Preparation method and application of flame-retardant PVC leather compound for traffic interior decoration

A compound and transportation technology, applied in the field of flame retardant materials, can solve the problems of low LOI test value, and achieve the effects of poor wear resistance, poor ductility, and poor low temperature resistance

Active Publication Date: 2020-11-10
HANGZHOU XIANGJUN TEXTILE FLAME RETARDANT TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The horizontal combustion method has been used as the evaluation standard in domestic and foreign industries for a long time, and LOI is not a mandatory index, so the actual test value of LOI of ordinary PVC leather compound products is relatively low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A vehicle interior leather retardant PVC composite, comprising a PVC leather layer, a functional layer and an elastic layer flame retardant in parts by weight of the functional layer comprising 100 parts of PVC paste resin, 50 parts of diphenyl isooctyl acrylate, the BDP 5 parts, 5 parts of the APP, zinchydroxystannate 3 parts, 5 parts of zirconium phosphate, 1 part of tetrakis [β- (3,5- di-tert-butyl-4-hydroxyphenyl) propionate], tris [ 2,4-di-tert-butylphenyl] phosphite, 1 part of a heat stabilizer, 1 part of 1 part of calcium carbonate, 1 part of a black syrup, 1 part of a foaming agent. The above raw materials were added sequentially dispersion mixer, stirring speed 600-800rmp / min, mixing time 30min, flame retardant functional layer paint prepared. The functional layer is flame-retardant coating, applied to the back surface of the leather weight PVC, flame-retardant layer by a doctor blade way function is 10% PVC leather layer, drying temperature 120 ℃ after molding, ...

Embodiment 2

[0030] A vehicle interior leather retardant PVC composite, comprising a PVC leather layer, a functional layer and an elastic layer flame retardant in parts by weight of the functional layer comprising 100 parts of PVC paste resin, 100 parts of diphenyl isooctyl acrylate, 5 parts of the BDP, APP 20 parts, 5 parts zinchydroxystannate, 5 parts of zirconium phosphate, 1 part of tetrakis [β- (3,5- di-tert-butyl-4-hydroxyphenyl) propionate], tris [ 2.4-di-tert-butylphenyl] phosphite, 1 part of a heat stabilizer, 1 part of 1 part of calcium carbonate, 1 part of a black syrup, 1 part of a foaming agent. The above raw materials were added sequentially dispersion mixer, stirring speed 1800-2000rmp / min, mixing time 60min, flame retardant functional layer paint prepared. The functional layer is flame-retardant coating, applied to the back surface of the leather weight PVC, flame-retardant layer by a doctor blade way function is 20% PVC leather layer, drying temperature 120 ℃ after molding, ...

Embodiment 3

[0032] A vehicle interior leather retardant PVC composite, comprising a PVC leather layer, a functional layer and an elastic layer flame retardant in parts by weight of the functional layer comprising 100 parts of PVC paste resin, diphenyl isooctyl acrylate 80 parts, RDP 20 parts, APP 20 parts, 10 parts of zinc borate, 5 parts of zirconium phosphate, 1 part of tetrakis [β- (3,5- di-tert-butyl-4-hydroxyphenyl) propionate], tris [2.4 di-tert-butylphenyl] phosphite, 1 part of a heat stabilizer, 1 part of 1 part of calcium carbonate, 1 part of a black syrup, 1 part of a foaming agent. The above raw materials were added sequentially dispersion mixer, stirring speed 600-800rmp / min, mixing time 60min, flame retardant functional layer paint prepared. The functional layer is flame-retardant coating, applied to the back surface of the leather weight PVC, flame-retardant layer by a doctor blade way function is 25% PVC leather layer after molding temperature of 130 ℃ drying, to give flame s...

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PUM

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Abstract

The invention discloses a flame-retardant PVC leather compound for traffic interior decoration as well as a preparation method and application thereof. The PVC leather compound comprises a PVC leatherlayer, a flame-retardant functional layer and an elastic layer, wherein the flame-retardant functional layer is prepared from 100 parts of PVC paste resin, 50-120 parts of a flame-retardant plasticizer, 5-20 parts of a phosphorus-containing liquid flame retardant, 5-20 parts of a powder flame retardant, 3-10 parts of a flame-retardant synergist, 1-10 parts of zirconium phosphate, 1-5 parts of anantioxidant, 1-5 parts of a heat stabilizer, 1-10 parts of a filler, 0-5 parts of color paste and 1-10 parts of a foaming agent; the elastic layer is polyurethane sponge. The flame-retardant functional layer is combined with the PVC leather layer to form a flame-retardant PVC leather layer, and then the flame-retardant PVC leather layer is tightly combined with the elastic layer through flame compounding, flame-retardant glue compounding or flame-retardant hot melt adhesive compounding. The flame-retardant PVC leather compound has the characteristics of excellent flame retardancy, low smoke, low toxicity, low VOC, low atomization value, no peculiar smell, soft hand feeling, high peel strength, good resilience and the like, and can be widely applied to seats, safety seats, door plates, handrails and the like of cars, passenger cars, trucks, high-speed rails, bullet trains, urban railways, low-speed trains and the like.

Description

Technical field [0001] The present invention relates to the field of flame-retardant materials, particularly relates to a preparation method and application A vehicle interior composite flame-retardant PVC leather. Background technique [0002] In recent years, motor vehicle combustion accidents, the relevant state ministries issued a document that the vehicle interior materials fire test standard is an important factor in ensuring the safety of the vehicle. States for the vehicle interior fabric flammability has clear regulations, my country has proposed a new standard in fire-retardant performance requirements of the school bus, buses and trains with interior fabric, horizontal burn test indicators from the original burning speed ≤100mm / min decreased to ≤70mm / min. Flame retardant passenger interior materials only with reference to the level of national mandatory GB8410-2006 burning rate control, is not sufficient to effectively prevent fire retard the spread of fire. Theref...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/30B32B27/08B32B27/40B32B5/18B32B7/12B32B7/08B32B7/027B32B7/022B32B7/02B32B33/00B32B37/12B32B37/06B32B37/24C09D5/18C09D127/06C09D7/61C09D7/63C08J7/05C08L27/06
CPCB32B27/304B32B27/065B32B7/12B32B7/08B32B7/027B32B7/022B32B7/02B32B33/00B32B37/06B32B37/1284B32B37/24C09D5/18C09D127/06C09D7/61C09D7/63C08J7/05C08J7/0427C08K2201/014C08K2003/323C08K2003/328C08K2003/265C08J2327/06C08J2427/06B32B2037/243B32B2255/10B32B2255/26B32B2266/0278B32B2307/3065B32B2307/554B32B2307/50B32B2307/51B32B2307/70B32B2307/7145C08K13/02C08K5/523C08K3/32C08K5/1345C08K5/526C08K3/26C08K5/524C08K3/346
Inventor 蒋小云唐俊毅刘清华陈忠刚宋习兵
Owner HANGZHOU XIANGJUN TEXTILE FLAME RETARDANT TECH
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