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A kind of preparation method of oxide ceramic particle reinforced Cu-based composite material

A technology of oxide ceramics and composite materials, applied in the field of metals and their composite materials, can solve the problems of high Cu content, difficult to form W skeleton, difficult to implement Cu-W alloy with high copper content, etc., and achieves simple process and comprehensive performance. good indicators

Active Publication Date: 2021-11-09
HENAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these two preparation methods are difficult to implement in the preparation of high copper content Cu-W alloys
The reason is that, first, it is difficult to form a W skeleton because of the low W content, and second, due to the high Cu content, once a liquid phase sample is formed, it will collapse

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The preparation method of a kind of oxide ceramic particle reinforced Cu-based composite material according to the present invention adopts the technical scheme, and the specific method is:

[0033] Step 1. Select copper nitrate powder, ammonium metatungstate powder and aluminum nitrate (or zirconium nitrate) powder with a purity greater than 99.99% as raw materials, and calculate according to the weight ratio of Cu:W:Al2O3 (or ZrO2) controlled at 77:5:0.05 Get the required copper nitrate powder, ammonium metatungstate powder and aluminum nitrate (or zirconium nitrate) powder, and use a high-precision balance to weigh and set aside;

[0034] Step 2. Slowly add the aluminum nitrate (or zirconium nitrate), copper nitrate and ammonium metatungstate powders taken in step 1 into 3 beakers pre-added with deionized water, and the concentration is controlled at 1mol / L. Then put the beaker into the ultrasonic oscillator for ultrasonic vibration, and start the electric stirrer at...

Embodiment 2

[0042] The preparation method of a kind of oxide ceramic particle reinforced Cu-based composite material according to the present invention adopts the technical scheme, and the specific method is:

[0043] Step 1. Select copper nitrate powder, ammonium metatungstate powder and aluminum nitrate (or zirconium nitrate) powder with a purity greater than 99.99% as raw materials, and calculate by controlling the weight ratio of Cu:W:Al2O3 (or ZrO2) at 94.95:20:3 Get the required copper nitrate powder, ammonium metatungstate powder and aluminum nitrate (or zirconium nitrate) powder, and use a high-precision balance to weigh and set aside;

[0044] Step 2. Slowly add the aluminum nitrate (or zirconium nitrate), copper nitrate and ammonium metatungstate powders weighed in step 1 into three beakers pre-added with deionized water, and the concentration is controlled at 1.5mol / L , then put the beaker into an ultrasonic oscillator for ultrasonic vibration, and start the electric stirrer at...

Embodiment 3

[0052] The preparation method of a kind of oxide ceramic particles reinforced Cu-based composite material according to the present invention adopts the technical scheme, and the specific method is:

[0053] Step 1. Select copper nitrate powder, ammonium metatungstate powder and aluminum nitrate (or zirconium nitrate) powder with a purity greater than 99.99% as raw materials, and calculate according to the weight ratio of Cu:W:Al2O3 (or ZrO2) controlled at 85:15:1.5 Get the required copper nitrate powder, ammonium metatungstate powder and aluminum nitrate (or zirconium nitrate) powder, and use a high-precision balance to weigh and set aside;

[0054] Step 2. Slowly add the aluminum nitrate (or zirconium nitrate), copper nitrate and ammonium metatungstate powders weighed in step 1 into three beakers pre-added with deionized water, and the concentration is controlled at 1.25mol / L , then put the beaker into an ultrasonic oscillator for ultrasonic vibration, and simultaneously star...

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Abstract

The invention relates to an oxide ceramic particle reinforced Cu-based composite material and a preparation method thereof. The invention belongs to the field of composite materials. Aluminum nitrate (or zirconium nitrate), copper nitrate and ammonium metatungstate are used as raw materials, respectively prepared into solutions with a certain concentration and mixed evenly, and a composite powder precursor is prepared by a cyclone spray drying method, and roasted get Al 2 o 3 -WO 3 ‑CuO mixed powder; then Al 2 o 3 -WO 3 ‑CuO is reduced to Al by high-purity hydrogen 2 o 3 Doped with copper-tungsten composite powder, the composite powder is directly sintered by vacuum hot pressing to prepare Al 2 o 3 Ceramic particles reinforced Cu-based composites, in which ZrO can also be used 2 -WO 3 ‑CuO mixed powder to get ZrO 2 , its effect is similar to that of Al 2 o 3 The effect is the same. The process of the present invention is simple, and the prepared Al 2 o 3 The ceramic particle-reinforced Cu-based composite material has uniform composition, fine and uniform grains, extremely low impurity content, and good comprehensive performance indicators. It can be used in harsh working conditions where electricity, high temperature, wear and corrosion interact, and is suitable for large-scale industrial production. It has broad industrial application prospects.

Description

technical field [0001] The invention belongs to the field of metals and composite materials thereof, and in particular relates to a preparation method of oxide ceramic particles reinforced Cu-based composite materials. Background technique [0002] Metal copper (Cu) is one of the earliest metals used by humans. It has outstanding characteristics such as high thermal conductivity and electrical conductivity, good ductility, good corrosion resistance, and excellent formability, so it is widely used in cables and electrical and electronic components. , military armor-piercing weapons, electromagnetic gun tracks and other fields. However, with the rapid development of science and technology, the use of metal copper is becoming wider and wider, and the requirements for its use are getting higher and higher. A single metal copper has been difficult to meet the development needs of human beings. Under this background, various copper alloys or copper-based composite materials have ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/05C22C1/10C22C9/00B22F3/14B22F9/22
CPCB22F3/14B22F9/22C22C1/05C22C9/00
Inventor 李秀青魏世忠杨晴霞徐流杰周玉成张敏杰张国赏毛丰陈冲张程熊美潘昆明
Owner HENAN UNIV OF SCI & TECH