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A gel particle plugging agent with self-healing properties and its preparation method and application

A gel particle, self-healing technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of complex formula of intelligent gel particles, complex preparation process, low temperature of pressure-bearing plugging, etc., to achieve Excellent healing plugging performance, simple preparation process, and the effect of improving plugging and pressure bearing capacity

Active Publication Date: 2021-12-07
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the above two materials are self-healing gel plugging materials prepared based on metal coordination bonds and hydrogen bonds, and their pressure-bearing plugging temperature is relatively low.
Chinese patent document CN105504158A provides a re-crosslinkable smart gel particle under formation conditions and its preparation method and application. The smart gel particle is composed of acrylamide, anionic monomer, cationic monomer, N,N -Vinylpyrrolidone, pH adjusting agent, initiator, crosslinking agent Ⅰ, crosslinking agent Ⅱ, stabilizer, nano particle material and water. After the gel particles enter the formation, under the formation conditions, the Re-cross-link between them to form a high-strength gel to achieve effective plugging. The above-mentioned method is to inject pre-cross-linked gel particles into the formation through the cross-linking agent I. Cross-linking forms an overall gel, but the formulation of the smart gel particles is complicated, and its preparation process is relatively complicated
[0005] The current research on self-healing gel plugging materials is still in its infancy, and it is necessary to develop new self-healing gel plugging materials based on different healing mechanisms

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  • A gel particle plugging agent with self-healing properties and its preparation method and application

Examples

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Effect test

Embodiment 1

[0069] A gel particle plugging agent with self-healing properties, comprising the following raw materials in parts by mass: 25 parts of comonomer, 10 parts of surfactant A, 0.01 part of initiator I, and 0.04 part of crosslinking agent , 2 parts of cationic latex particles.

[0070] The copolymerization monomer is a combination of octadecyl methacrylate, acrylic acid and acrylamide, and the mass ratio of octadecyl methacrylate, acrylic acid and acrylamide is 3:50:50.

[0071] Described surfactant A is sodium lauryl sulfate.

[0072] The initiator I is an oxidation-reduction initiator, the oxidizing agent is ammonium persulfate, the reducing agent is sodium bisulfite, and the mass ratio of the oxidizing agent to the reducing agent is 1:1.

[0073] The crosslinking agent is N, N-methylenebisacrylamide.

[0074] The preparation method of the above-mentioned gel particle plugging agent with self-healing properties comprises the following steps:

[0075] Disperse the comonomer, s...

Embodiment 2

[0094] A gel particle plugging agent with self-healing properties, comprising the following raw materials in parts by mass: 35 parts of comonomers, 10 parts of surfactant A, 0.05 parts of initiator I, and 0.02 parts of crosslinking agent , 2 parts of cationic latex particles.

[0095] The types of the comonomer, surfactant A, initiator I, and crosslinking agent are as described in Example 1.

[0096] The preparation method of the gel particle plugging agent with self-healing properties is as described in Example 1, except that the amount of deionized water is 112 parts.

[0097] The method for evaluating the healing and plugging performance of the above-mentioned self-healing gel plugging material is as described in Example 1, and its healing and plugging performance is shown in Table 1.

Embodiment 3

[0099] A gel particle plugging agent with self-healing properties, comprising the following raw materials in parts by mass: 15 parts of comonomer, 10 parts of surfactant A, 0.01 part of initiator I, and 0.02 parts of crosslinking agent 1 part of cationic latex particles.

[0100] The types of the comonomer, surfactant A, initiator I, and crosslinking agent are as described in Example 1.

[0101] The preparation method of the gel particle plugging agent with self-healing properties is as described in Example 1, except that 50 parts of deionized water is used.

[0102] The method for evaluating the healing and plugging performance of the above-mentioned self-healing gel plugging material is as described in Example 1, and its healing and plugging performance is shown in Table 1.

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Abstract

The invention provides a gel particle plugging agent with self-healing properties. The gel particle plugging agent comprises the following raw materials in parts by mass: 15-35 parts of copolymerization monomer, 0.1-35 parts of surfactant A 20 parts, 0.01-0.9 part of initiator I, 0.01-0.1 part of crosslinking agent, 0.5-5 part of cationic latex particles; the copolymerization monomer comprises hydrophilic monomer and hydrophobic monomer, and the hydrophilic monomer is A combination of acrylic acid and acrylamide monomers, the hydrophobic monomer is an acrylate monomer. The invention also provides a preparation method and a healing performance evaluation method of the gel particle plugging agent. The self-healing plugging material of the present invention has the characteristic of being recoverable after being damaged, and is injected into formation cracks in the form of particles, and can form an integral gel after healing, thereby achieving the purpose of effectively plugging cracks and pores.

Description

technical field [0001] The invention relates to a gel particle plugging agent with self-healing properties, a preparation method and application thereof, and belongs to the technical field of oil and gas drilling. Background technique [0002] Lost circulation is a common phenomenon in the process of oil drilling. According to statistics, the occurrence rate of lost circulation accounts for 20% to 25% of the total number of wells in the world. Lost circulation will not only cause huge economic losses to the drilling project, but also lead to a serious drop in well pressure, which will have a great impact on the stability of the inner wall of the oil well. In severe cases, it will lead to blowout accidents, which seriously threaten the safety of drilling operations. sex. Gel leak plugging technology is one of the commonly used and effective technologies for plugging leaky layers. The current gel plugging technology has achieved good results in field applications, but there a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/06C08F220/56C08F220/18C08F222/38C08F220/54C09K8/035C09K8/42
CPCC08F220/06C08F220/54C08F220/56C09K8/035C09K8/426C08F220/1818C08F222/385
Inventor 白英睿张启涛孙金声吕开河刘敬平黄贤斌王金堂金家锋
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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