Compound taking benzospiroanthracene as core, and application thereof
A technology of benzospiroanthracene and compounds, applied in the application field of organic electroluminescent devices, can solve different problems, achieve the effects of improving luminous efficiency, improving current efficiency and life, and good application effect
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Embodiment 1
[0060] Synthesis of Example 1 Compound 1:
[0061]
[0062] Dissolve 0.01 mol of reactant A-1 and 0.012 mol of reactant B-1 in 150 mL of toluene, add 0.015 mol of potassium tert-butoxide, and react at 120 °C for 24 hours under a nitrogen atmosphere. , cooled and filtered, the filtrate was rotary evaporated to remove the solvent, and the crude product was passed through a silica gel column to obtain compound 1, the yield was 77.6%, and the HPLC purity was 99.49%; elemental analysis of the structure (C 58 H 39 N) Theoretical: C, 92.89; H, 5.24; N, 1.87; Tested: C, 92.87; H, 5.21; N, 1.88. MS(m / z)(M+): Theoretical value is 749.31, and the found value is 749.29.
Embodiment 18
[0063] Synthesis of Example 18 Compound 214:
[0064]
[0065] Dissolve 0.01 mol of reactant A-11 and 0.012 mol of reactant B-15 in 150 mL of toluene, add 0.015 mol of potassium tert-butoxide, and react at 120 °C for 24 hours under a nitrogen atmosphere. After the reaction was completed, it was cooled and filtered, the filtrate was rotary evaporated to remove the solvent, and the crude product was passed through a silica gel column to obtain compound 214; the yield was 88.3%, the HPLC purity was 99.14%, and the elemental analysis structure (molecular formula C 62 H 41 NO) Theoretical: C, 91.26; H, 5.06; N, 1.72; O, 1.96; Tested: C, 91.27; H, 5.05; N, 1.71; O, 1.97. MS(m / z)(M+): Theoretical value is 815.32, and the found value is 815.33.
Embodiment 16
[0066] The synthesis of compound A-15 in Example 16 is as follows:
[0067]
[0068] Dissolve 0.02mol of raw material C-1 with 60mL of dry THF, keep at -78°C for 30min, add 24mL of 1.2M n-butyllithium solution under a nitrogen atmosphere, stir for 1 to 2 hours, and under a nitrogen atmosphere Continue to add 0.02mol of raw material D-1, stir evenly, slowly raise to room temperature, continue stirring reaction at room temperature for 10-24 hours, add 20 mL of water to the reaction system, continue stirring for 1-2 hours, the product is precipitated from the reaction system, Filtration to obtain intermediate I-1 with HPLC purity of 91.89% and yield of 84.9%; 0.02 mol of intermediate I-1 was dissolved in a mixture of 50 mL of acetic acid and 5 mL of hydrochloric acid, stirred and heated to 110 °C, reacted for 10 h, and cooled naturally. After reaching room temperature, the product was precipitated, filtered and washed with water and methanol to obtain reactant A-15, HPLC purit...
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