Photocatalytic composite particle as well as preparation method and application thereof
A composite particle and photocatalysis technology, applied in the field of photocatalysis, can solve the problems of ineffective removal of polycyclic aromatic hydrocarbons, difficulty in material recycling and low treatment efficiency, etc., and achieve high degradation efficiency and photon utilization efficiency, excellent Chemical and thermal stability, small reaction area effect
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[0115] The preparation process of the photocatalytic film of the present invention is as follows figure 1 As shown, it specifically includes: using strontium titanate single crystal particles, electron donor salt and electron acceptor salt to carry out ultraviolet light-induced deposition reaction to prepare photocatalytic composite particles, and the photocatalytic composite particles, matrix and two-dimensional layered material The layer-by-layer self-assembly reaction was induced by ultraviolet light, and the photocatalytic film was prepared.
[0116] The invention provides a kind of photocatalytic composite particle, and described photocatalytic composite particle comprises the strontium titanate single crystal particle of octadecahedron, icosahedron or regular hexahedron and electron donor and electron donor supported on the surface of strontium titanate single crystal particle Electron acceptor; the molar ratio of strontium titanate single crystal particles, electron don...
Embodiment 1
[0128] This embodiment provides a photocatalytic composite particle, which includes octahedral strontium titanate single crystal particles, such as figure 2 As shown, and chromium oxide and manganese oxide supported on the surface of strontium titanate single crystal particles; the molar ratio of strontium titanate single crystal particles, chromium oxide and manganese oxide in the photocatalytic composite particles is 250:1:1.5.
[0129] This embodiment provides a preparation method of the photocatalytic composite particles, the preparation method comprising the following steps:
[0130] (1) Mix the octahedral strontium titanate single crystal particle dispersion liquid with a concentration of 0.25wt% and the potassium chromate solution of 0.005mol / L under 250W ultraviolet light irradiation, the stirring speed is 450r / min, and the stirring time is 70min, the intermediate product was obtained, the intermediate product was mixed with the manganese nitrate solution of 0.0075mol...
Embodiment 2
[0133] This embodiment provides a kind of photocatalytic composite particle, and described photocatalytic composite particle comprises the strontium titanate single crystal particle of icosahedron, such as image 3 As shown, and platinum and manganese oxide supported on the surface of strontium titanate single crystal particles; the molar ratio of strontium titanate single crystal particles, platinum and manganese oxide in the photocatalytic composite particles is 25:1:1.
[0134] This embodiment provides a preparation method of the photocatalytic composite particles, the preparation method comprising the following steps:
[0135] (1) Mix the icosahedral strontium titanate single crystal particle dispersion liquid with a concentration of 0.1wt% and 0.002mol / L chloroplatinic acid solution under 200W ultraviolet light irradiation, the stirring speed is 600r / min, and the stirring time The intermediate product was obtained for 20 min, and the intermediate product was mixed with 0....
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