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Nickel-free white copper alloy strip foil and preparation method thereof

A copper alloy strip, white technology, applied in the field of metal material processing, can solve problems such as difficult industrialized production, and achieve the effects of high yield, avoiding heat treatment process, and short process flow

Inactive Publication Date: 2021-04-06
CNMC ALBETTER ALBRONZE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the shortage of nickel-free copper-nickel strip and foil materials in the prior art, and the difficulty in realizing industrialized production in the prior art, the present invention provides a nickel-nickel-nickel alloy strip and foil material and a preparation method thereof, and the alloy strip and foil prepared by the method The thickness of the material is only 0.04~0.1mm, and the production process is simple, the process is short, the yield is high, and the white chroma is good, which can meet the needs of white copper alloy strip and foil for building interior decoration, furniture and vehicle decoration, etc.

Method used

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  • Nickel-free white copper alloy strip foil and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] (1) The composition of the foil blank is (mass percentage): Zn: 14%, Mn: 10%, Al: 1.0%, Sn: 1.0%, Ti: 0.15%, Si: 0.1%, B: 0.3%, Ce: 0.08%, the balance is an alloy of Cu and unavoidable impurities;

[0029] (2) Melting

[0030] According to the designed white copper alloy composition ratio, pure zinc, pure manganese, pure aluminum, pure tin, copper-titanium master alloy, copper-silicon master alloy, copper-boron master alloy, copper-cerium master alloy and electrolytic copper Melt in an intermediate frequency induction furnace, remove slag, and cover with charcoal. When the temperature rises to 1240°C, take a sample from the furnace. Cover with charcoal and let stand for 30 minutes;

[0031] (3) Horizontal continuous casting

[0032]After confirming that the complete equipment of the horizontal continuous casting machine is in normal operation and the dummy device can rotate flexibly, start casting and drawing the billet. During the drawing process, it is required to ...

Embodiment 2

[0042] (1) The composition of the foil blank is (mass percentage): Zn: 11%, Mn: 14%, Al: 1.0%, Sn: 0.9%, Ti: 0.06%, Si: 0.3%, B: 0.02%, Ce: 0.3%, the balance is an alloy of Cu and unavoidable impurities;

[0043] (2) Melting

[0044] According to the designed white copper alloy composition ratio, pure zinc, pure manganese, pure aluminum, pure tin, copper-titanium master alloy, copper-silicon master alloy, copper-boron master alloy, copper-cerium master alloy and electrolytic copper Melt in the intermediate frequency induction furnace, add charcoal covering after slag removal, when the temperature rises to 1210 ° C, take the sample in the furnace, after the spectral analysis components meet the requirements, let the converter stand still, remove slag again and add charcoal covering, fully stand for 40 minutes;

[0045] (3) Horizontal continuous casting

[0046] After confirming that the complete set of equipment of the horizontal continuous casting machine is in normal operat...

Embodiment 3

[0056] (1) Foil blank composition (mass percentage): Zn: 12%, Mn: 12%, Al: 0.9%, Sn: 1.1%, Ti: 0.1%, Si: 0.2%, B: 0.05%, Ce: 0.1 %, the balance is an alloy of Cu and unavoidable impurities;

[0057] (2) Melting

[0058] According to the designed white copper alloy composition ratio, pure zinc, pure manganese, pure aluminum, pure tin, copper-titanium master alloy, copper-silicon master alloy, copper-boron master alloy, copper-cerium master alloy and electrolytic copper Melt in the intermediate frequency induction furnace, remove slag and cover with charcoal. When the temperature rises to 1230 ° C, take the sample in the furnace. After the spectral analysis components meet the requirements, leave the converter at rest, remove slag again and cover with charcoal, and let it stand for 25 minutes;

[0059] (3) Horizontal continuous casting

[0060] After confirming that the complete equipment of the horizontal continuous casting machine is in normal operation and the dummy device ...

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Abstract

The invention discloses a nickel-free white copper alloy strip foil and a preparation method thereof. The thickness of the nickel-free white copper alloy strip foil is 0.04-0.1 mm, the nickel-free white copper alloy strip foil is composed of, by weight, 5-15% of Zn, 10-14% of Mn, 0.5-1.5% of Al, 0.5-1.5% of Sn, 0.05-0.5% of Ti, 0.01-0.3% of Si, 0.01-0.3% of B, 0.01-0.3% of Ce and the balance Cu and inevitable impurities, wherein the impurity content is lower than 0.2%. According to the preparation method, the nickel-free white copper alloy strip foil is obtained through smelting, horizontal continuous casting, surface milling, rough rolling and cogging, multi-pass intermediate rolling and multi-pass finish rolling, the production process is simple, the process is short, the rate of finished products is high, the white chromaticity is good, environmental friendliness is achieved, and the requirements of building interior decoration, furniture and vehicle decoration and the like for the white copper alloy strip foil can be met.

Description

technical field [0001] The invention belongs to the technical field of metal material processing, and in particular relates to a nickel-free white copper alloy strip and foil material and a preparation method thereof. Background technique [0002] Traditional cupronickel alloy has beautiful and elegant silver-white luster and relatively cheap price. It is often used to make imitation silver and imitation platinum decoration materials. It is the most important kind of low-cost decoration materials. It is often used to make coins, Zippers, buttons, glasses frames, mobile phone cases and other daily necessities, as well as decoration materials for jewelry, gift box packaging, interior walls of buildings and indoor furniture, especially the facade and interior decoration of commercial institutions. The most common white copper alloy is copper-nickel-zinc alloy. However, with the development of modern medicine, it is found that nickel is a typical sensitizing element, which can n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/04C22C9/05C22C1/03C22F1/08B22D11/045
CPCB22D11/004B22D11/045C22C1/03C22C9/04C22C9/05C22F1/08
Inventor 刘娜蔡兰英姜业欣郑朋艳张县委贺玲慧田原晨苏花鲜田英明
Owner CNMC ALBETTER ALBRONZE
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