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Two-dimensional material transfer method based on water phase change

A technology of two-dimensional materials and transfer methods, applied in the field of two-dimensional material transfer, can solve the problems of polymer pollution, transfer, and shortage, and achieve the effects of simple operation, good continuity and low cost.

Pending Publication Date: 2021-04-09
XI AN JIAOTONG UNIV
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

However, the existing large-scale and low-cost production of graphene, especially the method of single-layer graphene film is chemical vapor deposition method, the limitation of this method is that it can only grow with copper foil as the growth substrate of graphene, graphite The application of graphene films necessarily involves the transfer of graphene films from copper substrates to target substrates.
[0003] The existing transfer methods of two-dimensional materials such as graphene mainly include dry transfer, wet transfer, and liquid bridge-assisted transfer, etc., but there are various problems, and it is difficult to realize the transfer of copper-based graphene film to any other substrate. High-quality transfer, mainly: problems related to polymer contamination, high-temperature annealing and insufficient transfer power
Electronic devices prepared by these methods are difficult to truly play the ideal properties of two-dimensional materials such as graphene

Method used

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  • Two-dimensional material transfer method based on water phase change
  • Two-dimensional material transfer method based on water phase change
  • Two-dimensional material transfer method based on water phase change

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Embodiment Construction

[0026] The present invention will be described in detail below in conjunction with the accompanying drawings and embodiments.

[0027] A two-dimensional material transfer method based on water phase change. In this embodiment, the two-dimensional material is graphene, and the transfer of graphene from a copper substrate to a gold substrate, a PDMS substrate, a silicon substrate, a Teflon substrate, etc. is completed. The operation is completed in a clean room with a temperature of 20-25°C and a humidity of 40%-60%, including the following steps:

[0028] The first step: the copper-based single-layer graphene film grown by chemical vapor deposition is used as the two-dimensional material 3 (single-layer graphene film) to be transferred, and the original substrate 4 (copper foil) with the two-dimensional material 3 is pasted Combined on the auxiliary substrate 5 (glass slide), such as figure 1 shown;

[0029] The second step: In this embodiment, a semiconductor refrigeration p...

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Abstract

A two-dimensional material transfer method based on water phase change comprises the following steps: preparing a to-be-transferred sample, namely fixing a two-dimensional material with an original substrate on an auxiliary substrate, then placing a mold with the same cross section size on the two-dimensional material, injecting distilled water into the mold, freezing the distilled water into an ice pillar, after the distilled water is completely frozen into the ice pillar, separating the ice pillar attached with the two-dimensional material from the upper surface of the original substrate through mechanical force, then quickly placing the ice pillar with the two-dimensional material on a target substrate, and completely transferring the two-dimensional material to the target substrate after the ice pillar is removed. According to the invention, large-scale, pollution-free and high-quality transfer of the two-dimensional material to any substrate can be realized.

Description

technical field [0001] The invention relates to the technical field of two-dimensional material transfer, in particular to a two-dimensional material transfer method based on water phase transition. Background technique [0002] As a new type of two-dimensional material, graphene has high strength-to-mass ratio, creep resistance, tensile strength and high toughness compared with traditional materials; it is flexible, wearable, and attachable; and has high light transmittance. , electrical conductivity, thermal conductivity and other characteristics, therefore, graphene has broad application prospects in the fields of medical health, aerospace, microelectronics, energy storage, sensing and communication. However, the existing large-scale and low-cost production of graphene, especially the method of single-layer graphene film is chemical vapor deposition method, the limitation of this method is that it can only grow with copper foil as the growth substrate of graphene, graphit...

Claims

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Application Information

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IPC IPC(8): C01B32/194C01B32/186
CPCC01B32/194C01B32/186C01B2204/02
Inventor 陈小明马河川李浩邵金友李祥明田洪淼韩宇飞张洁
Owner XI AN JIAOTONG UNIV
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