The invention relates to a method for cleanly extracting
vanadium pentexide from a
vanadium containing material. The method is characterized in that: the
vanadium containing material is milled by the wet method, and then mixed with a certain weight amount of
sulfuric acid, vanadic acid, water,
sulfuric acid or
phosphoric acid salt having certain association; under conditions of set temperature and set time, performing three-stage
reflux leaching reaction of the mixture; adding
ammonia sulfate and reducing
iron powder to reaction leach solution in sequence to obtain
aluminum ammonium sulfate crystals and
ammonium ferrous sulfate crystals respectively; adding
sulfuric acid to the solution in which aluminum and iron are separated out, cooling the solution for
crystallization to obtain vanadium
sulfate acyl crystals, and returning the
mother liquor to extract vanadium ores; performing the
neutralization reaction of the vanadium sulfate acyl crystals and
ammonia water to obtain a precipitate of vanadium
hydroxide, and returning the solution of
ammonia sulfate to precipitate the aluminum and iron; and calcining the vanadium
hydroxide and
oxygen gas at a high temperature of over 300 DEG C to obtain the vanadium pentexide. The method has the advantages of short process flow, less
energy consumption, high vanadium yield, low production cost,
environmental protection, and comprehensive utilization of valuable metallic elements in ores.