The invention relates to a method for cleanly extracting 
vanadium pentexide from a 
vanadium containing material. The method is characterized in that: the 
vanadium containing material is milled by the wet method, and then mixed with a certain weight amount of 
sulfuric acid, vanadic acid, water, 
sulfuric acid or 
phosphoric acid salt having certain association; under conditions of set temperature and set time, performing three-stage 
reflux leaching reaction of the mixture; adding 
ammonia sulfate and reducing 
iron powder to reaction leach solution in sequence to obtain 
aluminum ammonium sulfate crystals and 
ammonium ferrous sulfate crystals respectively; adding 
sulfuric acid to the solution in which aluminum and iron are separated out, cooling the solution for 
crystallization to obtain vanadium 
sulfate acyl crystals, and returning the 
mother liquor to extract vanadium ores; performing the 
neutralization reaction of the vanadium sulfate acyl crystals and 
ammonia water to obtain a precipitate of vanadium 
hydroxide, and returning the solution of 
ammonia sulfate to precipitate the aluminum and iron; and calcining the vanadium 
hydroxide and 
oxygen gas at a high temperature of over 300 DEG C to obtain the vanadium pentexide. The method has the advantages of short process flow, less 
energy consumption, high vanadium yield, low production cost, 
environmental protection, and comprehensive utilization of valuable metallic elements in ores.