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108results about How to "Good oxygen barrier effect" patented technology

Halogen-free flame retardant containing linear phenolic aldehyde and polymer material containing halogen-free flame retardant

The invention relates to a halogen-free flame retardant containing linear phenolic aldehyde and a polymer material containing the halogen-free flame retardant. A small quantity of metal hydroxides can be added simultaneously for serving as synergistic flame retardants. Phosphorus pentoxide generated by the combustion of red phosphorus reacts with a phenolic hydroxyl group in the linear phenolic aldehyde, and phosphonic acid or metaphosphoric acid and the like are generated simultaneously; and the acids of the type are further used for catalyzing dehydration and char formation of phenolic resin, and are esterified with the phenolic hydroxyl group, so that an organic-inorganic hybrid barrier layer is formed. The barrier layer is used for blocking heat conduction, diffusion and permeation of oxygen and overflow of combustible matter and slowing material degradation and the like, so that combustion is stopped finally, and flame is extinguished. A flame retarding effect can be further improved by using a small quantity of hydroxides and inorganic flame retardants containing crystal water. A halogen-free flame retardant composition can be used for retarding combustion of polymers and polymer compositions. A halogen-free flame retardant system disclosed by the invention has the advantages of low cost, low toxicity, wide application and the like, and contributes to environmental protection.
Owner:SOUTH CHINA UNIV OF TECH

Production technology for polycrystalline silicon

The invention discloses a production technology for polycrystalline silicon. The production technology includes the following steps: 1, a first coating, a second coating and a third coating are sequentially arranged on the surface of a crucible from inside to outside, and a crystalline silicone leftover material layer is laid; 2, a small quantity of raw polycrystalline silicon materials in the melted state is contained in the crucible, and the temperature of the crucible is controlled to be lower than the melting point of the crystalline silicone leftover material layer to enable the small quantity of melted raw polycrystalline silicon materials to form a crystallization protection layer; 3, in the vacuum environment, to-be-processed raw polycrystalline silicon materials are contained in the crucible, placed in a melting furnace with an electron beam generating device and processed through laser irradiation; 4, high-frequency induction heating is carried out in the vacuum environment, a slag forming constituent is added, plasma heating is carried out, steam-and-hydrogen-mixed argon is introduced, and directional solidification is carried out to obtain the polycrystalline silicon serving as the target product. By means of the production technology, the boron content, the phosphorous content and the metal impurity content can be effectively reduced, the complete polycrystalline silicon is prepared, long crystal dislocation is less, grain boundaries are proper, and the conversion rate of a polycrystalline silicon battery is increased.
Owner:THE SIXTH CONSTR CO LTD OF CHINA NAT CHEM ENG

Polyvinyl alcohol foam oxygen insulation material and preparation method and application thereof

ActiveCN102336994AGood oxygen barrier effectSmall oxygen permeability coefficientDust removalFire preventionFoaming agentAlcohol
The invention discloses a polyvinyl alcohol foam oxygen insulation material, which comprises a component (A) and a component (B), wherein the component (A) comprises a solvent, and 3-8 percent by weight of polyvinyl alcohol, 0.5-1.5 percent by weight of linear hydrocarbon organic alcohol or ester and 0.04-0.10 percent by weight of foaming agent based on the total amount of the solvents contained in the component (A) and the component (B); the component (B) comprises 0.1-0.3 percent by weight of borate based on the total amount of solvents contained in the component (A) and the component (B); and the mass ratio of the solvent contained in the component (A) to the solvent contained in the component (B) is (5-9):1. A method for preparing the polyvinyl alcohol foam oxygen insulation material comprises the following steps of: dissolving polyvinyl alcohol into the solvent at constant temperature 70-95 DEG C, performing return flow agitation for 30-60 minutes, cooling to room temperature, and adding the linear hydrocarbon organic alcohol or ester and the foaming agent to obtain the component (A); adding borate into the solvent to obtain the component (B); and foaming the component (A), spraying onto a coal surface and spraying the component (B) to form a foam gel oxygen insulation material layer which plays a good role in sealing and insulating oxygen on the coal surface.
Owner:CHINA SHENHUA ENERGY CO LTD +1

Economic and environment-friendly gel foam for preventing and curing coal spontaneous combustion

The invention relates to the technical application field of coal mine fire preventing and extinguishing, and provides economic and environment-friendly gel foam for preventing and curing coal spontaneous combustion. The economic and environment-friendly gel foam is prepared from the components in percentage by weight: 4% to 35% of water glass, 0.4% to 3% of a foaming agent, 0.1% to 3% of a foam stabilizing agent, 1% to 5% of a coagulant, and the balance of water; and the foaming agent is formed by compounding two or more anionic-type foaming agents. According to the economic and environment-friendly gel foam for preventing and curing coal spontaneous combustion, the adopted foaming agent is formed by compounding two or more anionic-type foaming agents, an adopted gelatinizing system is composed of the water glass and the coagulant, the cost is low, economy and environmental protection are realized, and the gel foam is non-poisonous and harmless during using and has good economic benefits. The obtained gel foam maintains the advantages of high fluidity and good aggregation of water-based foam before gelatinizing, and after gelatinizing, the advantages of the outstanding cooling effect and the good leak sealing effect of water glass gel are maintained; and the gel foam is good in inhibition and fire extinguishing effect, the fire source temperature, thermal radiation and CO output can be significantly reduced, fire extinguishing is stable, and the reignition phenomenon does not occur.
Owner:SHANDONG UNIV OF SCI & TECH

Preparation method and application of inorganic hybrid smoke-suppression flame retardant

The invention discloses a preparation method of an inorganic hybrid smoke-suppression flame retardant, which comprises the following steps: a) preparing a 0.4-0.6 mg / ml graphene oxide suspension; b) adding a soluble zinc salt into the graphene oxide suspension until the concentration of the soluble zinc salt is 2.5-9 mmol / L, stirring for 15-20 minutes, and adding a soluble stannate with the same mole number as the soluble zinc salt; stirring for 30-40 minutes to obtain a precursor solution; c) carrying out hydrothermal reaction on the precursor solution at 120-160 DEG C for 6-12 hours; and after the reaction finishes, cooling, filtering, washing with water and drying to obtain the inorganic hybrid smoke-suppression flame retardant. The invention also discloses application of the flame retardant in epoxy resins. The method is simple to operate, has the advantage of mild and controllable reaction conditions, and can easily implement large-scale production. The prepared flame retardant has favorable flame retardancy, overcomes the defects of low flame-retardant efficiency, high aggregation tendency, high addition amount and the like in the single graphene flame retardant. The flame-retardant material prepared by adding into the epoxy resin has flame-retardant and smoke-suppression functions.
Owner:HEBEI UNIVERSITY

A kind of topcoat for building curtain wall aluminum veneer and preparation method thereof

The invention relates to a finish for a building curtain wall aluminum veneer, and a preparation method thereof. The finish comprises 60 to 70% of FEVE fluorocarbon resin, 5 to 10% of an organic silicon resin, 0.05 to 0.1% of an acrylic acid levelling agent, 0.1 to 0.3% of an organosilicon levelling agent, 0.3 to 0.8% of benzotriazole ultraviolet absorbent, 0.3 to 0.8% of hindered amine light stabilizer, 0.1 to 0.3% of an organotin catalyst, 10 to 15% of butyl acetate, 10 to 15% of dimethylbenzene and 9 to 13% of an aliphatic isocyanate curing agent, wherein the aliphatic isocyanate curing agent needs to be individually packaged and stored and is added into a formula prior to construction for use. The FEVE fluorocarbon resin and the organic silicon resin are utilized as film-forming substances of the finish and the finish can be cured at normal temperature, and thus energy and labor are saved. Through a fluorine-silicon interpenetrating network structure, film surface tension is reduced and a water contact angle is reduced, and thus film anti-contamination properties are improved greatly. Through introduction of silicon atoms, film toughness is improved, and thus a film surface isnot easy to craze and temperature tolerance and endurance are further improved. In addition, the finish has the advantages of simple preparation method and low cost.
Owner:苏州金近幕墙有限公司

Biodegradable flame-retardant plastic film and preparation method thereof

The invention discloses a biodegradable flame-retardant plastic film, which is prepared from the following raw materials in parts by weight: 85 parts of polyethylene, 20-30 parts of polylactic acid, 65-80 parts of a PBM degradable material, 10-15 parts of packing, 5-10 parts of pullulan, 2-4 parts of an antioxidant, 1-1.5 parts of an ultraviolet light absorber and 25-30 parts of nano flame-retardant composites. The oxygen-isolating biodegradable plastic film disclosed by the invention is prepared by blending extrusion and film blowing of mature modified starch biodegradable plastic master batches PBM and pullulan and film-grade LDPE in the market at present in the preparation method; good mechanical property of the film is ensured by using the characteristics of the LDPE; the environment friendliness of the film material is achieved by using the biodegradability of the PBM and the pullulan; the oxygen isolating property of the film material is improved by using high oxygen isolating property of the pullulan; the overall compatibility of the plastic film material is improved by using the structure similarity of the starch and the pullulan as carbohydrates; and regulation and control of the oxygen isolating property, the biodegradability and the like can be achieved by controlling the blending ratio of the LDPE/PBM/Pullulan system.
Owner:TIANJIN KAIXUAN PLASTIC PROD

Bacillus amyloliquefaciens and preparation method of exopolysaccharides thereof

The invention provides bacillus amyloliquefaciens EZ99. The bacillus amyloliquefaciens is gram positive bacteria, exists in plant rhizosphere soil, has no pathogenicity for people and plants, is collected from an orchard county, in the west of a Qilihe district in the Lanzhou city of the Gansu province, and has been identified, registered and preserved in the China common microorganism strain preservation center, and the preservation number is CGMCC No.13267. Component analysis is performed on bacterial colonies formed by the bacillus amyloliquefaciens on a PMA and MS culture medium, and it is found that the bacillus amyloliquefaciens has the characteristic of synthesizing and secreting exopolysaccharides. Optimal culture medium formulas and fermentation optimal conditions based on fermentation production of the exopolysaccharides of the strains are built, a fermentation solution is subjected to centrifuging, alcohol precipitation, dialysis and chromatographic separation, four purification polysaccharide components are obtained, and four-polysaccharide-component monosaccharide composition and monomer molecular weight are determined. The exopolysaccharides obtained through the strain and the method have the various applications of medicines, cosmetics, food additives, biological film raw materials and the like.
Owner:甘肃尚农生物科技有限公司

High-temperature self-transformation amorphous/nanocrystalline high-entropy oxide film, preparation method and application

The invention provides a high-temperature self-transformation amorphous/nanocrystalline high-entropy oxide thin film, a preparation method and application. The preparation method comprises the following steps that (1) a zirconium-based multi-element target material is cut and combined into a sputtering target material A, an Al-based multi-element target material is cut and combined into a sputtering target material B, the sputtering target material A is connected with a direct-current power source, the sputtering target material B is connected with a radio-frequency power source, and a high-entropy metal glass film is deposited by adopting a co-sputtering method after pre-sputtering; and (2) the obtained high-entropy metal glass film is placed in a muffle furnace, and calcining is carried out to obtain the amorphous/nanocrystalline high-entropy oxide film. The high-entropy thin film prepared through the method gradually achieves in-situ transformation at the high temperature, uniform and compact high-entropy oxide is formed, and cracks and coating failure are avoided. The high mixing entropy enhances the intersolubility among the elements and inhibits the formation of a single compound. Meanwhile, due to high interface energy and dynamic obstacles (slow kinetics) of atomic diffusion in the crystallization process, an amorphous/nanocrystalline system can stably exist.
Owner:ZHENGZHOU UNIV

Preparation method of nano-cellulose-based oxygen isolation composite film

PendingCN112210225AExcellent oxygen barrier performanceGood water resistance and mechanical propertiesBio-packagingPolymer chemistryPolyvinyl alcohol
The invention provides a preparation method of a nanocellulose-based oxygen-isolating composite film. The method comprises the following steps: removing lignin from larch pulp powder to obtain lignocellulose, dissolving NaBr and tetramethylpiperidine oxide in a Na2CO3-NaHCO3 buffer solution, adding lignocellulose, dropwisely adding a NaClO solution, regulating the pH value, carrying out oxidationreaction, rinsing with deionized water, carrying out mechanical treatment, and obtaining carboxylated lignocellulose; adding deionized water and carboxylated lignocellulose into polyvinyl alcohol, mixing, and carrying out vacuum drying treatment to obtain a nanocellulose-based oxygen-isolating composite film, the mass ratio of polyvinyl alcohol to carboxylated lignocellulose being 3:7. The nano-cellulose-based oxygen isolation composite film prepared by the method has excellent oxygen isolation performance, and also has excellent water resistance and mechanical properties.
Owner:INNER MONGOLIA AGRICULTURAL UNIVERSITY

Biodegradable flame-retardant plastic film

The invention discloses a biodegradable flame-retardant plastic film, which is prepared from the following raw materials in parts by weight: 85 parts of polyethylene, 20-30 parts of polylactic acid, 65-80 parts of a PBM degradable material, 10-15 parts of packing, 5-10 parts of pullulan, 2-4 parts of an antioxidant, 1-1.5 parts of an ultraviolet light absorber and 25-30 parts of nano flame-retardant composites. The oxygen-isolating biodegradable plastic film disclosed by the invention is prepared by blending extrusion and film blowing of mature modified starch biodegradable plastic master batches PBM and pullulan and film-grade LDPE in the market at present in the preparation method; good mechanical property of the film is ensured by using the characteristics of the LDPE; the environment friendliness of the film material is achieved by using the biodegradability of the PBM and the pullulan; the oxygen isolating property of the film material is improved by using high oxygen isolating property of the pullulan; the overall compatibility of the plastic film material is improved by using the structure similarity of starch and the pullulan as carbohydrates; and regulation and control of the oxygen isolating property, the biodegradability and the like can be achieved by controlling the blending ratio of the LDPE / PBM / Pullulan system.
Owner:TIANJIN KAIXUAN PLASTIC PROD

Method for preventing browning in production of konjak powder

The invention discloses a method for preventing browning in production of konjak powder. The method particularly includes following steps: mixing konjak flying powder with papain and spraying the konjak flying powder and the papain on fresh cut konjak pieces for enabling the powder fully covers surfaces of the fresh cut konjak pieces. Glucomannan has a quite strong water-absorbing property and can absorb moisture on the surfaces of the fresh cut konjak piece to form a hydration film so that an oxygen-insulation effect is achieved. In addition, by means of color protection of the papain, a quite good color-protective effect is achieved. By means of the color-protective method combined with a conventional production technology of the konjak powder, an object of producing high-quality konjak powder is achieved.
Owner:HUBEI JIANSHI NONGTAI IND CO LTD

Biodegradable plastic film

The invention discloses a biodegradable plastic film which respectively comprises the following raw material components in parts by weight: 80 parts of polyethylene, 20-40 parts of polylactic acid, 60-80 parts of a PBM degradable material, 10-15 parts of a filling material, 5-8 parts of Pullulan, 2-4 parts of an antioxidant and 1-1.5 parts of an ultraviolet light absorber. The oxygen-isolating and biodegradable plastic film provided by the invention has the advantages that the mature modified starch biodegradable plastic master batch PBM, the Pullulan and film-level LDPE in the market are selected to be subjected to blending extrusion and film blowing in the preparation method at present, the characteristics of LDPE are utilized, and good mechanical property of the film is guaranteed; by utilizing the biodegradability of PBM and Pullulan, the environment friendliness of the film material is realized; by utilizing high oxygen isolating property of the Pullulan, the oxygen isolation property of the film material is improved; by utilizing the structural similarity of the starch and Pullulan serving as saccharides, the overall compatibility of the plastic film material is improved; and moreover, the blending ratio of the LDPE/PBM/Pullulan system is controlled, so that the oxygen isolation property, the biodegradability and the like can be regulated.
Owner:TIANJIN KAIXUAN PLASTIC PROD

Agricultural insect killing and oxygen isolating environment-friendly degradable plastic film

The invention provides an agricultural insect killing and oxygen isolating environment-friendly degradable plastic film. The agricultural insect killing and oxygen isolating environment-friendly degradable plastic film is prepared by coating both sides of a plastic film with an insecticide and comprises the following components in parts by weight: 40-60 parts of corn starch, 100 parts of low density polyethylene (LDPE), 20-40 parts of pulullan, 10-20 parts of polycarbonate, 2-4 parts of antioxidant, 0.5-1 part of ultraviolet absorber, 4.5-6.5 parts of cedar oil, 5-10 parts of polyethylene wax and 6-8 parts of composite filler. The film per m<2> is coated with 4-6g of insecticide slurry. The oxygen isolating degradable plastic film provided by the invention has the advantages and beneficial effects that the plastic film can be automatically decomposed under the actions of rich oxygen and microorganisms; the waste films can be completely decomposed and digested by microorganisms in the natural world to finally generate carbon dioxide and water; the oxygen isolating property of the plastic film can be improved by 40% compared with the oxygen isolating properties of LDPE films in the same thickness; a preparation method of the plastic film is simple in process and high in production efficiency, is easy to implement industrially and can be used for producing the plastic film by using a common plastic film blowing machine.
Owner:TIANJIN KAIXUAN PLASTIC PROD
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