Plugging agent for drilling fluid and preparation method thereof
The technology of a plugging agent and drilling fluid, which is applied in the field of oil drilling plugging, can solve the problems of high product hardness, low plugging strength, weak scour ability, etc. High temperature resistance effect
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Embodiment 1
[0044] Add 48g of m-xylylenediamine and 31.5g of phenol into the reactor, stir and heat up to dissolve, slowly add 35.7g of 37wt% formaldehyde aqueous solution dropwise at 80°C, drop it over 60min, then react at 90°C for 3.0h, and raise the temperature To 175°C, vacuum dehydration to obtain the accelerator.
[0045] Dissolve 25g of polymethyl methacrylate in dichloromethane, add 73.6g of WE-8325 water-based epoxy curing agent and 16.4g of the accelerator prepared above, and divide evenly for 20min with a homogenizer to form a dispersed phase. Add 1.0% sodium lauryl sulfate aqueous solution into the three-necked flask as the continuous phase. At room temperature, add the dispersed phase drop by drop to the continuous phase while stirring, and emulsify with high-speed stirring at a stirring speed of 2500r / min; then place the three-necked flask in a constant temperature water bath at 40°C, reduce the stirring speed to 550r / min, The reaction time is 3.5 h until the dichloromethan...
Embodiment 2
[0048] Add 64.2g of ethylenediamine and 37.5g of phenol into the reactor, stir and heat up to dissolve, slowly add 49.2g of 37wt% formaldehyde aqueous solution dropwise at 55°C, drop it in 70min, then react at 85°C for 2.5h, and heat up to 170°C, vacuum dehydration to obtain accelerator.
[0049] Dissolve 28g of polymethyl methacrylate in dichloromethane, add 100g of WE-8300 water-based epoxy curing agent and 31.3g of the accelerator prepared above, and divide evenly for 25min with a homogenizer to form a dispersed phase. Add 1.0% sodium lauryl sulfate aqueous solution into the three-necked flask as the continuous phase. At room temperature, add the dispersed phase drop by drop to the continuous phase while stirring, and emulsify with high-speed stirring at a stirring speed of 2200r / min; then place the three-necked flask in a constant temperature water bath at 45°C, reduce the stirring speed to 650r / min, The reaction time is 5 hours until the dichloromethane is completely vol...
Embodiment 3
[0052] Add 47.6g m-xylylenediamine and 24.2g phenol into the reactor, stir and raise the temperature to dissolve, slowly add 35.7g aqueous solution containing 35wt% formaldehyde dropwise at 75°C, drop it in 45min, then react at 100°C for 3.5h, Raise the temperature to 180°C, vacuumize and dehydrate to obtain the accelerator.
[0053] Dissolve 35g of polymethyl methacrylate in dichloromethane, add 87.2g of WE-8309 water-based epoxy curing agent and 24.8g of the accelerator prepared above, and divide evenly for 30min with a homogenizer to form a dispersed phase. Add 1.0% sodium lauryl sulfate aqueous solution into the three-necked flask as the continuous phase. At room temperature, add the dispersed phase drop by drop to the continuous phase while stirring, and emulsify with high-speed stirring at a stirring speed of 2600r / min; then place the three-necked flask in a constant temperature water bath at 40°C, reduce the stirring speed to 700r / min, The reaction time is 4.5 h until ...
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