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A water-soluble power lithium-ion battery

A lithium-ion battery, water-soluble technology, applied in the direction of battery electrodes, secondary batteries, active material electrodes, etc., can solve the problems of reducing energy density, cracking and powder loss, and difficulty in dispersing slurry, so as to improve dispersion and stability Effect

Active Publication Date: 2022-04-19
江西安驰新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (1) Deionized water is used as the solvent, the dispersion of the positive electrode is difficult, the slurry is difficult to disperse, and the stability is poor;
[0005] (2) When coating, on the one hand, the slurry dries quickly, causing scratches and leakage of foil; on the other hand, cracking and powder dropping can be slightly improved by increasing the amount of binder and reducing the density of the coating surface, but Reduced energy density;
[0006] (3) The pole piece is brittle when rolling, although the flexibility of the pole piece can be slightly improved by reducing the compaction density, but the energy density is also reduced;
[0007] (4) The lamination process is adopted, and the production efficiency is low

Method used

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  • A water-soluble power lithium-ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] (1) Positive electrode

[0034] The positive electrode sheet includes a positive electrode current collector and a positive electrode slurry, the positive electrode slurry includes a positive electrode active material, a conductive agent, an aqueous binder, a dispersing aid, a solvent additive and deionized water, and the positive electrode current collector is an oily carbon coating aluminum foil;

[0035] The weight ratio of the positive electrode active material: conductive agent: aqueous binder: dispersing aid is 94.5:1.25:3.0:0.03; the positive electrode active material is nano-lithium iron phosphate;

[0036] The conductive agent includes water-based conductive paste and carbon black, the water-based conductive paste is carbon nanotube paste, the carbon black is superconducting carbon black, and the weight ratio of the water-based conductive paste: carbon black is 0.5 :1;

[0037] The water-based binder includes water-based binder A, water-based binder B and bin...

Embodiment 2

[0050] (1) Positive electrode

[0051] The positive electrode sheet includes a positive electrode current collector and a positive electrode slurry, the positive electrode slurry includes a positive electrode active material, a conductive agent, an aqueous binder, a dispersing aid, a solvent additive and deionized water, and the positive electrode current collector is an oily carbon coating aluminum foil;

[0052]The weight ratio of the positive electrode active material: conductive agent: aqueous binder: dispersing aid is 96:1:3.5:0.01; the positive electrode active material is nano-lithium iron phosphate; the conductive agent includes aqueous conductive paste and Carbon black, the water-based conductive paste is graphene conductive paste, the carbon black is Ketjen Black ECP600JD, and the water-based conductive paste: the weight ratio of carbon black is 0.5:1;

[0053] The water-based binder includes water-based binder A, water-based binder B and binder C, the water-based b...

Embodiment 3

[0059] (1) Positive electrode

[0060] The positive electrode sheet includes a positive electrode current collector and a positive electrode slurry, the positive electrode slurry includes a positive electrode active material, a conductive agent, an aqueous binder, a dispersing aid, a solvent additive and deionized water, and the positive electrode current collector is an oily carbon coating aluminum foil;

[0061] The weight ratio of the positive electrode active material: conductive agent: aqueous binder: dispersing aid is 93:1.5:2.5:0.05; the positive electrode active material is nano-lithium iron phosphate; the conductive agent includes water-based conductive paste and Carbon black, the water-based conductive slurry is carbon nanotube slurry, the carbon black is SP, and the weight ratio of the water-based conductive slurry:carbon black is 0.5:1;

[0062] The water-based binder includes water-based binder A, water-based binder B and binder C, the water-based binder A is mod...

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Abstract

The invention belongs to the technical field of lithium-ion batteries, and specifically relates to a water-soluble power lithium-ion battery, which includes a positive electrode sheet, and the positive electrode sheet includes a positive electrode current collector and a positive electrode slurry, and the positive electrode slurry includes a conductive agent, a water-based binder and a Ionized water, the positive current collector is oily carbon-coated aluminum foil; the conductive agent includes water-based conductive paste and carbon black, and the water-based binder includes water-based binder A, water-based binder B and binder C. The invention improves the dispersibility and stability of the positive electrode slurry, improves the bonding performance of the positive electrode sheet and the flexibility of the positive electrode sheet, and increases the compaction density to increase the energy density, and the better flexibility of the electrode sheet can improve the roll pressure. , laser cutting, winding and hot pressing yield and production efficiency; solves the problem of scratches, leaking foil and pole piece cracking caused by rapid slurry drying, and the oily carbon-coated aluminum foil reduces the internal resistance of the battery.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a water-soluble power lithium ion battery. Background technique [0002] Compared with lead-acid batteries, nickel-metal hydride batteries, and nickel-cadmium batteries, lithium-ion batteries have the advantages of higher energy density, low self-discharge, and long cycle life. They have been widely used in consumer electronics and power batteries. Currently, fluorine-containing polymers such as polyvinylidene fluoride are generally used as a binder and NMP (N-methylpyrrolidone) as a solvent for the positive electrode slurry of lithium ion batteries. Since organic solvents are easy to cause environmental pollution and harm the health of operators, it is necessary to increase the cost to recover the organic solvents during the coating and drying process. At the same time, the cost of NMP is high, which increases the production cost of batteries. Therefor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/58H01M4/62H01M4/66H01M10/0525H01M10/42
CPCH01M4/5825H01M4/621H01M4/625H01M4/667H01M10/0525H01M10/4235H01M2004/028Y02E60/10
Inventor 郭娜娜毛振强何涛斌张小溪白科陈富源
Owner 江西安驰新能源科技有限公司