Unlock instant, AI-driven research and patent intelligence for your innovation.

Iron-based catalyst for preparing high-carbon hydrocarbon through carbon dioxide hydrogenation as well as preparation and application of iron-based catalyst

A carbon dioxide and catalyst technology, which is applied in the field of preparation of carbon dioxide hydrogenation catalysts, can solve problems such as difficulties in aviation kerosene hydrocarbon products, and achieve the effects of easy scale-up, convenient operation, and simple process

Inactive Publication Date: 2021-06-08
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
View PDF4 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the limitation of the classic Anderson-Schulz-Flory (ASF) distribution law, it is usually very difficult to directly obtain the hydrocarbon products of aviation kerosene section from the C-C coupling process

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Iron-based catalyst for preparing high-carbon hydrocarbon through carbon dioxide hydrogenation as well as preparation and application of iron-based catalyst
  • Iron-based catalyst for preparing high-carbon hydrocarbon through carbon dioxide hydrogenation as well as preparation and application of iron-based catalyst
  • Iron-based catalyst for preparing high-carbon hydrocarbon through carbon dioxide hydrogenation as well as preparation and application of iron-based catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The iron-based catalyst preparation process is as follows:

[0024] Weigh 10 g of corn cob powder into a crucible, then transfer it to a muffle furnace and roast at 700°C for 3 hours, take it out after cooling to room temperature, and store it for future use. After the roasting treatment, the above-mentioned powder and commercial molten iron (black powder, specific surface area 10m 2 / g) was weighed according to the mass ratio of 5:95, then transferred to a mortar and ground for uniformity, and then pressed into tablets and sieved to obtain a 150-mesh iron-based catalyst.

[0025] The composition of the prepared iron-based catalyst is shown in Table 1. Effective promoters such as K, Ca, Mn, Mg, and Si all exist in the iron-based catalyst. The appearance of iron particles is as figure 2 As shown, the prepared catalyst is mainly composed of uniformly dispersed iron particles of about 20nm. From other chemical analysis, the active phase of iron is mainly composed of ir...

Embodiment 2

[0033] The iron-based catalyst preparation process is as follows:

[0034] Weigh 10 g of corncob powder into a crucible, then transfer it to a muffle furnace and roast at 600°C for 3 hours, take it out after cooling to room temperature, and store it for future use. After the roasting treatment, the above-mentioned powder and commercial molten iron (black powder, specific surface area 10m 2 / g) was weighed according to the mass ratio of 10:90, then transferred to a mortar and ground for uniformity, and then pressed into tablets and sieved to obtain a 200-mesh iron-based catalyst.

[0035] The composition of the prepared iron-based catalyst is shown in Table 1. Effective promoters such as K, Ca, Mn, Mg, and Si all exist in the iron-based catalyst, and the content of alkali metal promoter K is as high as 3.9%.

[0036] Table 3 The percentage content of each element relative to iron in the catalyst

[0037]

[0038]

[0039] Carbon dioxide hydrogenation reaction was carried...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle size (mesh)aaaaaaaaaa
Login to View More

Abstract

The invention relates to an iron-based catalyst for preparing high-carbon hydrocarbon through carbon dioxide hydrogenation as well as preparation and application of the iron-based catalyst, and aims to solve the problems of less high-carbon hydrocarbon products and lower added value of the products in the carbon dioxide hydrogenation process. According to the invention, a plurality of beneficial mineral elements, such as potassium, calcium and magnesium, are extracted from biomass as catalyst assistants, and are coupled with a cheap molten iron catalyst to prepare an efficient carbon dioxide hydrogenation catalyst. The preparation process of the catalyst is simple, green and cheap, hydrocarbon products of a C8 + fraction section can be generated in a high-selectivity mode in the carbon dioxide hydrogenation process, and the utilization value of the products obtained in the process is improved. The invention provides a brand new strategy for cyclic utilization of waste biomass resources and exploration of a new route for selective regulation and control of carbon dioxide hydrogenation products.

Description

technical field [0001] The present invention designs a kind of preparation method of carbon dioxide hydrogenation catalyst, specifically relates to a kind of carbon dioxide hydrogenation to produce C 8+ The high carbon distillate section is an iron-based catalyst with the main product. Background technique [0002] At present, the development of industry and agriculture in the world depends on the extensive use of fossil fuels. In recent years, with the acceleration of industrialization, the rapid development of petrochemical, chemical, building materials, steel, and other eight key industries has led to an increase in the emission of carbon dioxide, a major greenhouse gas, and the trend of global warming has become increasingly severe. Therefore, it is urgent to control the greenhouse effect and reduce the emission of carbon dioxide. At present, the main methods to reduce the content of carbon dioxide in the atmosphere are: carbon dioxide emission reduction, carbon captur...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/889B01J27/22C10G2/00
CPCB01J23/8892B01J27/22C10G2/332C10G2400/08
Inventor 孙剑葛庆杰纪学玮
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI