Iron-based catalyst for preparing high-carbon hydrocarbon through carbon dioxide hydrogenation as well as preparation and application of iron-based catalyst
A carbon dioxide and catalyst technology, which is applied in the field of preparation of carbon dioxide hydrogenation catalysts, can solve problems such as difficulties in aviation kerosene hydrocarbon products, and achieve the effects of easy scale-up, convenient operation, and simple process
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Embodiment 1
[0023] The iron-based catalyst preparation process is as follows:
[0024] Weigh 10 g of corn cob powder into a crucible, then transfer it to a muffle furnace and roast at 700°C for 3 hours, take it out after cooling to room temperature, and store it for future use. After the roasting treatment, the above-mentioned powder and commercial molten iron (black powder, specific surface area 10m 2 / g) was weighed according to the mass ratio of 5:95, then transferred to a mortar and ground for uniformity, and then pressed into tablets and sieved to obtain a 150-mesh iron-based catalyst.
[0025] The composition of the prepared iron-based catalyst is shown in Table 1. Effective promoters such as K, Ca, Mn, Mg, and Si all exist in the iron-based catalyst. The appearance of iron particles is as figure 2 As shown, the prepared catalyst is mainly composed of uniformly dispersed iron particles of about 20nm. From other chemical analysis, the active phase of iron is mainly composed of ir...
Embodiment 2
[0033] The iron-based catalyst preparation process is as follows:
[0034] Weigh 10 g of corncob powder into a crucible, then transfer it to a muffle furnace and roast at 600°C for 3 hours, take it out after cooling to room temperature, and store it for future use. After the roasting treatment, the above-mentioned powder and commercial molten iron (black powder, specific surface area 10m 2 / g) was weighed according to the mass ratio of 10:90, then transferred to a mortar and ground for uniformity, and then pressed into tablets and sieved to obtain a 200-mesh iron-based catalyst.
[0035] The composition of the prepared iron-based catalyst is shown in Table 1. Effective promoters such as K, Ca, Mn, Mg, and Si all exist in the iron-based catalyst, and the content of alkali metal promoter K is as high as 3.9%.
[0036] Table 3 The percentage content of each element relative to iron in the catalyst
[0037]
[0038]
[0039] Carbon dioxide hydrogenation reaction was carried...
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