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Water-based copper ion battery suitable for large-scale energy storage application

A copper ion, large-scale technology, applied in the field of electrochemical energy storage, can solve the problems of unrealized water-based copper-based secondary battery battery energy storage, no matching positive electrode materials, etc., and achieve stable rate performance cycle and good electrochemical performance , the effect of high ion mobility

Active Publication Date: 2021-06-08
YANSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Cu 2+ The carrier redox potential is high (0.153V vs. standard hydrogen electrode), and the hydrogen evolution reaction is not easy to occur in the aqueous electrolyte, but at the same time, it also faces the problem that there is no matching positive electrode material, and the aqueous copper-based secondary battery has not yet been realized. battery energy storage technology

Method used

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  • Water-based copper ion battery suitable for large-scale energy storage application
  • Water-based copper ion battery suitable for large-scale energy storage application
  • Water-based copper ion battery suitable for large-scale energy storage application

Examples

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Effect test

Embodiment 1

[0040] This embodiment is a water-based copper ion battery suitable for large-scale energy storage applications, including a positive electrode, a negative electrode, a separator for separating the positive and negative electrodes, and a water-based aqueous solution containing copper ions.

[0041] 1. The positive electrode is made of active material activated carbon (the specific surface area is 950m 2 / g of activated carbon), conductive agent (acetylene black) and binder (polytetrafluoroethylene), its preparation method is prepared according to the following method:

[0042] The active material activated carbon, the conductive agent acetylene black and the binder polytetrafluoroethylene are placed in the organic solvent N-methylpyrrolidone in a mass ratio of 70:20:10, mixed and dispersed to form a slurry; then the slurry The material is rolled and pressed into a self-supporting film (film thickness 0.02-1mm), and the film is dried in an oven at 80°C for 12 hours. After drying...

Embodiment 2

[0048] This embodiment is a water-based copper ion battery suitable for large-scale energy storage applications, including a positive electrode, a negative electrode, a separator for separating the positive and negative electrodes, and a water-based aqueous solution containing copper ions.

[0049] 1. The positive electrode is made of active material activated carbon (the specific surface area is 950m 2 / g of activated carbon), conductive agent (Ketjen black) and binder (polytetrafluoroethylene), its preparation method is prepared according to the following method:

[0050] The active material activated carbon, the conductive agent Ketjen black and the binder polytetrafluoroethylene are placed in the organic solvent N,N-dimethylformamide in a mass ratio of 80:10:10, mixed and dispersed to form a slurry Then roll the slurry into a self-supporting film (thickness 0.02-1mm), put the film in an oven and dry it at 80°C for 12 hours, and cut the membrane electrode into a circular po...

Embodiment 3

[0056] This embodiment is a water-based copper ion battery suitable for large-scale energy storage applications, including a positive electrode, a negative electrode, a separator for separating the positive and negative electrodes, and a water-based aqueous solution containing copper ions.

[0057] 1. The positive electrode is made of active material activated carbon (the specific surface area is 950m 2 / g of activated carbon), conductive agent (Super-P carbon black) and binder (polyvinylidene fluoride), its preparation method is prepared according to the following method:

[0058] The active material activated carbon, the conductive agent Super-P carbon black and the binder polyvinylidene fluoride are placed in the organic solvent N,N-dimethylacetamide in a mass ratio of 90:5:5, Mix and disperse to form a slurry, and then coat the slurry on the titanium net collector fluid (coated film thickness is 0.02-1mm), place the titanium net collector fluid in an oven and dry at 80°C f...

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Abstract

The invention discloses a water-based copper ion battery suitable for large-scale energy storage application, which is characterized in that an aqueous solution consisting of choline chloride and copper chloride is used as an electrolyte, activated carbon is used as a positive electrode, a metal copper foil is used as a negative electrode, and the positive electrode and the negative electrode are separated by a diaphragm to form the battery. The positive electrode material, the negative electrode material and the electrolyte of the battery respectively adopt the low-cost carbon material, the metal copper foil and the cheap metal chlorate containing the copper ions, the preparation process is simple, the preparation price is extremely low, the period is short, the ion mobility is high in the charging and discharging process, only the redox reaction of the carrier metal copper ions is involved, the dynamic problem caused by the charge shielding effect in the process of embedding and removing metal ions in the material is avoided, and the battery has the characteristics of high capacity, high energy density, good rate capability, stable circulation and environment friendliness, and has good electrochemical performance. The scheme is suitable for preparing the water-based copper ion battery.

Description

technical field [0001] The invention belongs to the technical field of electrochemical energy storage, and relates to an aqueous copper ion battery suitable for large-scale energy storage applications. Background technique [0002] As the international community pays more and more attention to issues such as ensuring energy security and addressing climate change, the development of renewable energy has become a common consensus and concerted action by all countries in the world. However, renewable energy has the characteristics of volatility, randomness, and intermittent nature. Large-scale grid connection will pose severe challenges to the safe and stable operation of the grid, and the development of large-scale energy storage technology is an effective solution. Battery energy storage technology is one of the key technologies supporting large-scale energy storage systems, and plays an important role in the development of power systems and energy transformation. However, d...

Claims

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Application Information

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IPC IPC(8): H01M10/36H01M10/38H01M4/583
CPCH01M10/36H01M10/38H01M4/583H01M2220/10H01M2300/0091H01M2300/0002H01M2004/021Y02P70/50Y02E60/10
Inventor 张璐段泽昂韩树民王文凤王雨
Owner YANSHAN UNIV