A kind of circuit board filming method
A technology of high temperature resistant protective film and methacrylate, applied in the field of circuit boards, can solve the problems of complex coating process, and achieve the effects of easy peeling, improved high temperature resistance and chemical resistance, and excellent adhesion
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Embodiment 1
[0032] Preparation of modified methacrylate polymer:
[0033] (1) Add 1 / 2 of butanone and 1 / 2 of methacrylic acid, methyl methacrylate and butyl acrylate (methacrylic acid, methacrylic acid The mass ratio of methyl ester to butyl acrylate is 2.2:3.1:4.8) mixed monomers (the mass ratio of mixed monomers to butanone is 1:1.9), stirred and heated to 85°C, adding 1 / 3 initiator (AIBN ), react and reflux for 1h; within 2.5h, add the mixed solution of the remaining 1 / 2 of the mixed monomers, 1 / 4 of butanone and 1 / 3 of the initiator into the reactor, keep the temperature constant while maintaining reflux;
[0034](2) Then add the mixed solution of 1 / 3 initiator, 1 / 4 butanone and N-(3-butenyloxy)benzamide (mass ratio to mixed monomer is 0.12:1) into the reactor In the middle, keep reflux, keep warm for 4 hours, and stop the reaction to obtain viscous modified methacrylate polymer.
[0035] A high temperature resistant protective film composition, comprising: by weight, 96 parts of mo...
Embodiment 2
[0040] The difference between the preparation of the modified methacrylate polymer and Example 1 is that the mass ratio of the mixed monomer to butanone is 1:2.23; N-(3-butenyloxy)benzamide and the mixed monomer The mass ratio of the monomer is 0.10:1; wherein, the mass ratio of methacrylic acid, methyl methacrylate and butyl acrylate in the mixed monomer is 1.9:2.1:3.8.
[0041] A high temperature resistant protective film composition, comprising: by weight, 90 parts of modified methacrylate polymer, 4 parts of curing agent N75, and 3 parts of auxiliary agent. Among them, the auxiliary agent is hydroquinone.
[0042] A method for attaching film to a circuit board is the same as that in Embodiment 1.
Embodiment 3
[0044] The difference between the preparation of the modified methacrylate polymer and Example 1 is that the mass ratio of the mixed monomer to butanone is 1:1.76; N-(3-butenyloxy)benzamide and the mixed monomer The mass ratio of monomer is 0.14:1; among them, the mass ratio of methacrylic acid, methyl methacrylate and butyl acrylate in the mixed monomer is 2.9:3.4:5.1.
[0045] A high temperature resistant protective film composition, comprising: by weight, 76 parts of modified methacrylate polymer, 3 parts of curing agent N75, and 2 parts of auxiliary agent. Wherein the auxiliary agent is hydroquinone.
[0046] A method for attaching film to a circuit board is the same as that in Embodiment 1.
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Abstract
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