Modified polyimide binder, preparation method and application thereof
A technology of polyimide and binder, which is applied in the field of materials, can solve the problems of low electrical conductivity of polymers, and achieve the effects of improving flexibility, good mechanical stability, and reducing impedance
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Embodiment 1
[0071] This embodiment provides a lithium ion battery negative electrode binder, which is a modified polyimide polymer, and its structural formula is: Wherein, m:n=4:1.
[0072] The preparation method of the modified polyimide binder of the present embodiment is: with 8mmol and 2 mmol of Dissolve the diamine monomer in 40ml N-methylpyrrolidone, continuously feed nitrogen gas, stir at room temperature to fully dissolve it, then add 10.02mmol dianhydride monomer Stir at room temperature for 12 hours to obtain a polymer solution. After the reaction is completed, add 300ml of deionized water into the polymer solution to stir and precipitate. After washing and suction filtering, the obtained precipitate is vacuum-dried at 60°C for 12 hours to obtain a fibrous white and light yellow polyamic acid solid powder, the structural formula is
[0073] The above polyamic acid solid powder was dissolved in N-methylpyrrolidone, fully stirred at 15° C. to dissolve it completely, and ...
Embodiment 2
[0088] This embodiment provides a lithium ion battery negative electrode binder, which is a modified polyimide polymer, and its structural formula is: Wherein, m:n=3:1.
[0089] The preparation method of the modified polyimide binder of the present embodiment is: the and 2.5mmol of Dissolve the diamine monomer in 40ml N-methylpyrrolidone, continuously feed nitrogen gas, stir at room temperature to fully dissolve it, then add 10.02mmol dianhydride monomer Stir at room temperature for 12 hours to obtain a polymer solution. After the reaction is completed, add 300ml of deionized water into the polymer solution to stir and precipitate. After washing and suction filtration, the obtained precipitate is vacuum-dried at 60°C for 12 hours to obtain a fibrous white and light yellow polyamic acid polymer. solid powder.
[0090] The preparation method of the negative electrode sheet and the battery assembly process are the same as those in Example 1.
[0091] The negative pole pi...
Embodiment 3
[0095] This embodiment provides a lithium ion battery negative electrode binder, which is a modified polyimide polymer, and its structural formula is: Wherein, m:n=3:2.
[0096] The preparation method of the modified polyimide binder of the present embodiment is: the and 4mmol of Dissolve the diamine monomer in 40ml N-methylpyrrolidone, continuously feed nitrogen gas, stir at room temperature to fully dissolve it, and then add 10.02mmol dianhydride monomer Stir at room temperature for 12 hours to obtain a polymer solution. After the reaction is completed, add 300ml of deionized water into the polymer solution to stir and precipitate. After washing and suction filtration, the obtained precipitate is vacuum-dried at 60°C for 12 hours to obtain a fibrous white and light yellow polyamic acid polymer. solid powder.
[0097] The preparation method of the negative electrode sheet and the battery assembly process are the same as those in Example 1.
[0098] The negative pole p...
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