Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for recycling positive electrode material of waste lithium ion battery as electrocatalyst

A lithium-ion battery and positive electrode material technology, which is applied in the field of recycling waste lithium-ion battery positive electrode materials as electrocatalysts, can solve environmental pollution, resource waste and other problems, and achieve the effects of reducing pollution, saving resources, and protecting the environment

Pending Publication Date: 2021-11-05
HARBIN INST OF TECH
View PDF8 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a method for reclaiming the positive electrode material of the waste lithium ion battery as an electrocatalyst in order to solve the environmental pollution and resource waste problems caused by the waste and old decommissioned lithium ion batteries;

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for recycling positive electrode material of waste lithium ion battery as electrocatalyst
  • Method for recycling positive electrode material of waste lithium ion battery as electrocatalyst
  • Method for recycling positive electrode material of waste lithium ion battery as electrocatalyst

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0030] The method for reclaiming waste and old lithium-ion battery cathode materials as electrocatalysts comprises the following steps:

[0031] Step 1. After the commercial lithium-ion battery is discharged, it is disassembled by a mechanical method to obtain the positive pole piece; the obtained positive pole piece is cleaned with an organic solvent I, and the side reaction products and lithium salt on the surface of the pole piece are cleaned. After cleaning, let it dry naturally for 2-12 hours;

[0032] Step 2. Obtain the active material from the positive electrode sheet by mechanical means, and perform calcination at 300-800°C for 30-120min in the air atmosphere to remove the conductive agent I, binder I and active material mixed with the active material in the electrode The interface film on the surface, and the calcined product is ground and sieved to obtain the transition metal oxide material with the required particle size;

[0033] Step 3: Mix transition metal oxide...

specific Embodiment approach 2

[0043] The method for reclaiming waste and old lithium-ion battery cathode materials as electrocatalysts comprises the following steps:

[0044] Step 1. After the commercial lithium-ion battery is discharged, it is disassembled by a mechanical method to obtain the positive pole piece; the obtained positive pole piece is cleaned with an organic solvent I, and the side reaction products and lithium salt on the surface of the pole piece are cleaned. After cleaning, let it dry naturally for 2-12 hours;

[0045] Step 2. Obtain the active material from the positive electrode sheet by mechanical means, and perform calcination at 300-800°C for 30-120min in the air atmosphere to remove the conductive agent I, binder I and active material mixed with the active material in the electrode The interface film on the surface, and the calcined product is ground and sieved to obtain the transition metal oxide material with the required particle size;

[0046] Step 3: Mix transition metal oxide...

specific Embodiment approach 3

[0056] The method for reclaiming waste and old lithium-ion battery cathode materials as electrocatalysts comprises the following steps:

[0057] Step 1. After the commercial lithium-ion battery is discharged, it is disassembled by a mechanical method to obtain the positive pole piece; the obtained positive pole piece is cleaned with an organic solvent I, and the side reaction products and lithium salt on the surface of the pole piece are cleaned. After cleaning, let it dry naturally for 2-12 hours;

[0058] Step 2. Obtain the active material from the positive electrode sheet by mechanical means, and perform calcination at 300-800°C for 30-120min in the air atmosphere to remove the conductive agent I, binder I and active material mixed with the active material in the electrode The interface film on the surface, and the calcined product is ground and sieved to obtain the transition metal oxide material with the required particle size;

[0059] Step 3: Mix transition metal oxide...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

A method for recovering the positive electrode material of a waste lithium ion battery as an electrocatalyst relates to the field of battery recovery, and specifically comprises the following steps of 1, disassembling the discharged lithium ion battery to obtain a positive electrode plate, cleaning the side reaction products and lithium salt on the surface of the electrode plate, and then airing; 2, obtaining an active substance from the positive electrode plate, calcining the active substance, and grinding and screening a product obtained by calcining to obtain a transition metal oxide material with a required particle size; 3, uniformly mixing the transition metal oxide material, a conductive agent and a binder to obtain a mixture, dispersing the mixture in an organic solvent to obtain a dispersion liquid, loading the dispersion liquid on a carbon paper, and airing to obtain a membrane electrode; and 4, arranging the membrane electrode between an exchange membrane and a cathode diffusion layer of a proton exchange membrane fuel cell, and applying the transition metal oxide in the membrane electrode as an oxygen reduction catalyst of the proton exchange membrane fuel cell, so that an electro-catalysis effect is better than that of an original material.

Description

technical field [0001] The invention relates to the technical field of battery recycling, in particular to a method for recycling waste lithium-ion battery anode materials as electrocatalysts. Background technique [0002] Due to the advantages of high specific capacity, small self-discharge, high working voltage, strong cycle stability, and long life, lithium-ion batteries have become important energy storage devices in today's society and are widely used in tablet computers, smart phones, and new energy vehicles. and power storage industries. However, after use, the discarded lithium-ion batteries are directly landfilled as ordinary garbage, which not only pollutes the environment, but also causes a waste of resources. [0003] The positive electrode of lithium-ion batteries is mainly composed of active materials, conductive agents, and binders, among which the commercial active materials include lithium cobalt oxide (LiCoO 2 ), ternary materials (LiNi 1-x-y co x mn y...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/88H01M4/90H01M10/54C22B1/02C22B7/00C22B23/02C22B47/00C25B1/04C25B11/073
CPCH01M4/8825H01M4/9016H01M10/54C25B11/073C25B1/04C22B23/02C22B47/00C22B7/001C22B1/02H01M2004/028Y02W30/84Y02E60/10Y02E60/36Y02E60/50Y02P10/20Y02P20/584
Inventor 娄帅锋孙业财王家钧全国策尹鸽平
Owner HARBIN INST OF TECH