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Method for cascade neutralization and cascade flotation of multi-metal acid wastewater

A technology for acidic wastewater and polymetallics, applied in chemical instruments and methods, wet separation, process efficiency improvement, etc., can solve the problems of resource waste, environmental pollution, etc., and achieve effective separation, efficient recovery and safe treatment.

Pending Publication Date: 2021-11-30
SHANDONG GUODA GOLD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the production process of gold mines, because the cyanide method has the advantages of high recovery rate, mature process, and low cost, most of them adopt the cyanide gold extraction process technology. The cyanide gold extraction process includes direct cyanide gold extraction and roasting cyanide gold extraction. However, after gold extraction, a large amount of cyanide tailings will be produced. For a long time, due to technical and production cost reasons, a large amount of cyanide tailings have been discarded and piled up like mountains, which not only seriously pollutes the environment, but also causes huge waste of resources

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific example 1

[0038] The concentration of cyanide pyrite tailings produced by the process of 10wt% sulfuric acid in a stirred tank at the waste matter according to the solid-liquid mass ratio of 1: 1 ratio with stirring, the temperature stirred for 50 ℃, stirring speed 50r / min, air charge 50m 3 / H, stirring time 4h, the reaction was stirred into the thickener, flow through filter bottom dehydrated decyanation tailings, multi-metal overflow drainage, the concentration of sulfuric acid waste water resulting multimetal of 2wt%, gold 0.3 mg / L, silver 0.3mg / L, copper 500mg / L, zinc 500mg / L, iron 3000mg / L, arsenic 100mg / L.

[0039] A plurality of metal to acid waste water transport tank and stirring, adding lime powder containing 75wt% calcium oxide was stirred, and the temperature 40 ℃, stirring speed of 100r / min, and the time of 4h, the reaction end point pH of 1.5, into the reaction the precipitate was concentrated thickener, flow through the bottom filter was washed horizontal fil...

specific example 2

[0046] The cyanide degenesis and the sulfur-containing gold concentrate calcined have a waste of 20% by weight of the waste sulfate in the stirring tank in the stirring tank mixed stirring, stirring the temperature of 65 ° C, stirring the speed 125R / min, pneumatic volume of 100M 3 / h, stirring time is 5 h, after stirring, enter the concentrator, the bottom fluid is dehydrated to give the deodoxide, overflow is a poly metallic acid wastewater, the obtained multi-metal acid wastewater concentration is 6% by weight, containing gold 0.65 Mg / L, silver 0.65mg / L, copper 1000mg / L, zinc 1000mg / L, iron 8000mg / L, arsenic 300 mg / L.

[0047] The multi-metal acid wastewater is delivered to a neutralizing tank, adding 80% by weight of lime powder stirring, neutralizing temperature 50 ° C, stirring the rotation speed 200R / min, neutralization time, and the reaction endpoint pH is 2.0, and after entering The concentrated concentration is concentrated, and the bottom flow is filtere...

specific example 3

[0054] The concentration of the cyanide degenesis and the yellow iron mine process was 30% by weight of the waste sulfate in the stirring tank was mixed in a ratio of solid liquid mass than 1: 5, stirring the temperature of 80 ° C, stirring the rotation speed of 200R / min, pumping 150M 3 / h, stirring time is 6 h, after stirring reaction, enter the concentrator, the bottom flow filter machine is dehydrated to give the deodoxide residue, the overflow is a poly metallic acid wastewater, the obtained poly metallic acid wastewater concentration is 10% by weight, and the gold 1.0 Mg / L, silver 1.0mg / L, copper 1500mg / L, zinc 1500mg / L, iron 13000mg / L, arsenic 500mg / L.

[0055] The multi-metal acid wastewater is delivered to the medium and stirring tank, and the lime powder containing 85 wt% calcium oxide is added, the neutralizing temperature is 60 ° C, stirred at the temperature of 300 r / min, the neutralization time is 2.5, the reaction endpoint is 2.5, and after entering ...

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Abstract

The invention relates to a method for cascade neutralization and cascade flotation of multi-metal acid wastewater. The method comprises the following steps: 1) producing of the multi-metal acid wastewater; 2) first-stage neutralization deacidification; (3) second-stage gold and silver replacement; (4) third-stage neutralization copper deposition; (5) four-stage flotation of copper; (6) fifth-stage neutralization zinc deposition; and (7) sixth-stage zinc flotation. According to the method, firstly, waste sulfuric acid in the acid making process is used for decyanation treatment of cyanidation tailings, the acid wastewater containing multiple metals is produced in the process, and effective separation of multiple metal ions in the acid wastewater is achieved; the gold, silver, copper and zinc in the acid wastewater are comprehensively recycled and utilized through a first-stage neutralization deacidification treatment technology, a second-stage gold and silver replacement treatment technology, a third-stage neutralization copper deposition treatment technology, a fourth-stage copper flotation technology, a fifth-stage neutralization zinc deposition treatment technology and a sixth-stage zinc flotation technology; and therefore, efficient recovery and safe treatment of valuable elements in the multi-metal acid wastewater are realized.

Description

Technical field [0001] The present invention is in the smelting of gold, and in particular relates to a method for multi-metal step and acidic waste water in the flotation step. Background technique [0002] Gold mines in the production process, since the method has high recovery cyanide, mature technology, low cost, etc., often using cyanidation technology, cyanide gold direct cyanidation process comprises roasting and Cyanide Leaching gold process, but after gold extraction will produce large amounts of cyanide tailings, long time, because technology and production cost reasons, a large number of cyanide tailings have been discarded unused, piling up, not only seriously pollute the environment, but also huge waste of resources. [0003] Currently, technical processing mainly cyanide tailings flotation, supplemented autoclaved method, chlorination roasting process, molten calcination, reduction roasting method, oxidation method, a curing method, the preparation of Portland cemen...

Claims

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Application Information

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IPC IPC(8): B03B9/00B03B7/00C22B7/00
CPCB03B9/00B03B7/00C22B7/006Y02P10/20
Inventor 郭建东朱德兵
Owner SHANDONG GUODA GOLD