Soaking solution for removing rusty yellow spots of white cobblestones, preparation method thereof, and method for removing rusty yellow spots of white cobblestones

Abstract

The invention discloses a soaking solution for removing rusty yellow spots of white cobblestones, a preparation method thereof, and a method for removing the rusty yellow spots of the white cobblestones, and relates to the technical field of treatment of the white cobblestones. The soaking solution for removing the rust yellow spots of the white cobblestones comprises the following components: oxalic acid, chloride, hydroxylamine hydrochloride, citric acid, ascorbic acid, sulfosalicylic acid, an additive and water. Ascorbic acid and sulfosalicylic acid can achieve a synergistic effect, rapidly react with iron oxide in the cobblestones, and can permeate into the cobblestones to react with rust, so that the leaching speed of the iron oxide is increased; and hydroxylamine hydrochloride can quickly react with ferric ions to generate ferrous ions, so that the concentration of the ferric ions in the solution is reduced, and the reaction is promoted to move in the positive direction. The soaking solution for removing the rusty yellow spots of the white cobblestones is free of fluorine and pollution, cannot corrode and peel off the surface layers of the cobblestones, can quickly remove the rusty yellow spots of the cobblestones, and can be continuously used after corresponding components are supplemented according to conditions after being used.

Description

technical field

[0001] The invention relates to the technical field of white cobblestone treatment, in particular to a soaking solution for removing white cobblestone rust and yellow spots, a preparation method thereof, and a method for removing white cobblestone rust and yellow spots. Background technique

[0002] Stone reserves are very rich in our country and are widely used. The quality of stone determines the price of stone. Many stones are oxidized due to compounds containing iron to form endogenous rusty spots, especially white pebbles. Rust yellow spots seriously affect the The whiteness of the pebbles leads to the poor quality of the whole pebbles and affects its price. The main component of cobblestone is silicon dioxide. The conventional method of removing rust and yellow spots is to soak in strong acid or add fluorine-containing compounds. Strong acid will cause corrosion of equipment, and it is easy to form acid mist and pollute the environment. Adding fluorine...

Examples

preparation example Construction

[0046] see figure 1 , the present invention further proposes a method for preparing the soaking solution for removing white cobblestone rust and yellow spots as described above, comprising the following steps:

[0047] S10, dissolving oxalic acid, hydroxylamine hydrochloride, citric acid, ascorbic acid, sulfosalicylic acid, and additives in a part of water to form a solution A;

[0048] S20, dissolving the chloride in the remaining water to form a solution B;

[0049] S30, uniformly mixing the solution A and the solution B to obtain a soaking solution for removing rust and yellow spots of white pebbles.

[0050] The preparation method of the above-mentioned soaking solution for removing white cobblestone rust and yellow spots of the present invention is simple and easy to obtain, and has all the beneficial effects of the above-mentioned soaking solution for white cobblestone rust and yellow spots, and will not be repeated here.

[0051] The present invention further proposes...

Embodiment 1

[0059] (1) Weigh 2g of oxalic acid, 1.2g of hydroxylamine hydrochloride, 1.8g of citric acid, 1.5g of ascorbic acid, 0.5g of sulfosalicylic acid, 1g of hydroxyethylidene diphosphonic acid, 0.4g of low-foam penetrant SF, and dissolve them in 70g of Solution A was formed in water, and then 0.6g of ammonium chloride was weighed and dissolved in 21g of water to form solution B, solution B was slowly added to solution A, and stirred while adding, to obtain a soaking solution.

[0060] (2) Clean the rusty white pebbles with water, put them into the soaking solution, take them out after soaking for 5 days at a temperature of 25° C., rinse them with clean water, and complete the removal of the rusty yellow spots on the white pebbles.

[0061] figure 2 Be the picture of cobblestone before and after the rusty yellow spot is removed for the present embodiment, wherein, (a) is the picture of cobblestone before soaking, (b) is the picture of cobblestone after soaking 5 days with present e...

Embodiment 2

[0063] (1) Weigh 1g of oxalic acid, 1.8g of hydroxylamine hydrochloride, 2g of citric acid, 2g of ascorbic acid, 2g of sulfosalicylic acid, 2g of hydroxyethylidene diphosphonic acid, dissolve in 70g of water to form solution A, and then weigh 0.2g of chlorine Dissolve ammonium chloride and 0.1 g of sodium chloride in 18.9 g of water to form solution B, slowly add solution B into solution A, and stir while adding, to obtain a soaking solution.

[0064] (2) Clean the rusty white pebbles with water, put them into the soaking solution, take them out after soaking for 6 days at a temperature of 25° C., rinse them with clean water, and complete the removal of the rusty yellow spots on the white pebbles.

[0065] image 3 Be the picture of cobblestone before and after the removal of rusty macula for the present embodiment, wherein, (a) is the picture of cobblestone before immersion, (b) is the picture of cobblestone after soaking 6 days with present embodiment soaking liquid, as can ...

technical field

[0001] The invention relates to the technical field of white cobblestone treatment, in particular to a soaking solution for removing white cobblestone rust and yellow spots, a preparation method thereof, and a method for removing white cobblestone rust and yellow spots. Background technique

[0002] Stone reserves are very rich in our country and are widely used. The quality of stone determines the price of stone. Many stones are oxidized due to compounds containing iron to form endogenous rusty spots, especially white pebbles. Rust yellow spots seriously affect the The whiteness of the pebbles leads to the poor quality of the whole pebbles and affects its price. The main component of cobblestone is silicon dioxide. The conventional method of removing rust and yellow spots is to soak in strong acid or add fluorine-containing compounds. Strong acid will cause corrosion of equipment, and it is easy to form acid mist and pollute the environment. Adding fluorine...

Examples

preparation example Construction

[0046] see figure 1 , the present invention further proposes a method for preparing the soaking solution for removing white cobblestone rust and yellow spots as described above, comprising the following steps:

[0047] S10, dissolving oxalic acid, hydroxylamine hydrochloride, citric acid, ascorbic acid, sulfosalicylic acid, and additives in a part of water to form a solution A;

[0048] S20, dissolving the chloride in the remaining water to form a solution B;

[0049] S30, uniformly mixing the solution A and the solution B to obtain a soaking solution for removing rust and yellow spots of white pebbles.

[0050] The preparation method of the above-mentioned soaking solution for removing white cobblestone rust and yellow spots of the present invention is simple and easy to obtain, and has all the beneficial effects of the above-mentioned soaking solution for white cobblestone rust and yellow spots, and will not be repeated here.

[0051] The present invention further proposes...

Embodiment 1

[0059] (1) Weigh 2g of oxalic acid, 1.2g of hydroxylamine hydrochloride, 1.8g of citric acid, 1.5g of ascorbic acid, 0.5g of sulfosalicylic acid, 1g of hydroxyethylidene diphosphonic acid, 0.4g of low-foam penetrant SF, and dissolve them in 70g of Solution A was formed in water, and then 0.6g of ammonium chloride was weighed and dissolved in 21g of water to form solution B, solution B was slowly added to solution A, and stirred while adding, to obtain a soaking solution.

[0060] (2) Clean the rusty white pebbles with water, put them into the soaking solution, take them out after soaking for 5 days at a temperature of 25° C., rinse them with clean water, and complete the removal of the rusty yellow spots on the white pebbles.

[0061] figure 2 Be the picture of cobblestone before and after the rusty yellow spot is removed for the present embodiment, wherein, (a) is the picture of cobblestone before soaking, (b) is the picture of cobblestone after soaking 5 days with present e...

Embodiment 2

[0063] (1) Weigh 1g of oxalic acid, 1.8g of hydroxylamine hydrochloride, 2g of citric acid, 2g of ascorbic acid, 2g of sulfosalicylic acid, 2g of hydroxyethylidene diphosphonic acid, dissolve in 70g of water to form solution A, and then weigh 0.2g of chlorine Dissolve ammonium chloride and 0.1 g of sodium chloride in 18.9 g of water to form solution B, slowly add solution B into solution A, and stir while adding, to obtain a soaking solution.

[0064] (2) Clean the rusty white pebbles with water, put them into the soaking solution, take them out after soaking for 6 days at a temperature of 25° C., rinse them with clean water, and complete the removal of the rusty yellow spots on the white pebbles.

[0065] image 3 Be the picture of cobblestone before and after the removal of rusty macula for the present embodiment, wherein, (a) is the picture of cobblestone before immersion, (b) is the picture of cobblestone after soaking 6 days with present embodiment soaking liquid, as can ...

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