Iron and zinc-containing dust sludge solid waste treatment method based on whole-process iron and steel enterprise

A disposal method and a whole-process technology, applied in the direction of improving process efficiency, etc., can solve problems such as the degree of corrosion and ash accumulation in waste heat boilers, excessive heavy metals in drainage, and heavy metal enrichment, etc., to achieve resource utilization, reduce heat loss, and improve water washing efficiency effect

Pending Publication Date: 2022-02-01
CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The accumulation of iron-containing dust and sludge leads to the enrichment of heavy metals in areas such as steel plant sintering, which causes heavy metals in regional drainage to seriously exceed the standard
[0005] 3) Disposal in rotary hearth furnace: At present, iron-containing zinc-containing dust and sludge are mostly disposed of in a rotary hearth furnace, and the raw materials are mostly dust and sludge in ironmaking and steelmaking processes, and the disposal of dust and sludge in the sintering process is not considered
At the same time, the disposal process mostly adopts the direct treatment of raw materials, and the resource utilization of dust and sludge is not considered to the maximum; the raw materials contain a large amount of chlorine, potassium, sodium and other elements. During the operation of the rotary hearth furnace, chlorine, potassium, sodium and other elements are Gas enters the waste heat boiler, resulting in increased corrosion and dust accumulation of the waste heat boiler

Method used

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  • Iron and zinc-containing dust sludge solid waste treatment method based on whole-process iron and steel enterprise
  • Iron and zinc-containing dust sludge solid waste treatment method based on whole-process iron and steel enterprise

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] like figure 1 As shown, a method for solid waste disposal of iron-containing zinc-containing dust and sludge based on the whole process of iron and steel enterprises includes the following steps:

[0025] (1) washing the sintered ash produced by sintering and the gas ash of the blast furnace with water to reclaim the KCl and NaCl therein, and press-filtering the washed residue to obtain the filter residue;

[0026] (2) fully mixing the filter residue obtained in step (1) with the gravity ash of the blast furnace, the dedusting ash of the converter and the dedusting ash of the electric furnace, after adjusting the ratio of carbon, zinc and iron in the mixture, the mixture is subjected to reduction reaction;

[0027] (3) After the reduction reaction, the generated flue gas is sent to the waste heat boiler after being settled by gravity, and the steam generated by the waste heat boiler is used for heating; the flue gas after passing through the waste heat boiler is process...

Embodiment 2

[0033] A solid waste treatment method based on the whole process of iron and zinc-containing dust and sludge in iron and steel enterprises. After the gas ash produced in the blast furnace process of the iron and steel enterprise is fully stirred and leached, the leachate is sent to the sintered ash washing section produced in the sintering process, and the stirred slurry is passed through The solution rich in KCl and NaCl produced after graded filter press is sent to the multi-effect evaporation system to produce KCl and NaCl, and the filter residue produced after press filter is fully mixed with the gravity ash produced by the blast furnace, the dedusted ash produced by the converter, and the dedusted ash produced by the electric furnace , adjusting the water content of the mixture to 15%-25%, the carbon content to 15%-30%, the zinc content to 3%-15%, the iron content to 25%-50%, and the chlorine content to below 2%. After the iron-containing and zinc-containing raw materials ...

Embodiment 3

[0035] like figure 2 As shown, a iron and zinc-containing dust and sludge solid waste disposal system based on the whole process of iron and steel enterprises includes a water washing system 1, a zinc oxide recovery system 2 and a metallized product heat delivery system 3 connected in sequence, and the zinc oxide recovery system 2 It includes a reduction volatilization unit 21 and a flue gas treatment unit 22 connected in sequence.

[0036] The water washing system 1 includes a blast furnace gas ash water washing system 11 , a sintered ash water washing system 12 and an evaporation system 13 connected in sequence.

[0037] The blast furnace gas ash water washing system 11 includes a first pulping leaching unit 111 and a first graded filter press unit 112 connected in sequence, and the sintered ash water washing system 12 includes a second pulping leaching unit 121 and a second graded filter unit connected in sequence. Press filter unit 122, the effluent of the first graded f...

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Abstract

The invention relates to the technical field of iron-containing and zinc-containing dust sludge treatment in the iron and steel industry, in particular to an iron and zinc-containing dust sludge solid waste treatment method based on a whole-process iron and steel enterprise, which comprises the following steps that sintering ash generated by sintering and gas ash of a blast furnace are washed with water, KCl and NaCl in the sintering ash and the gas ash are recovered, and filter pressing is conducted on washing residues to obtain filter residues; the obtained filter residues arefully mixed with gravity ash of a blast furnace, fly ash of a converter and fly ash of an electric furnace, and the mixture is subjected to a high-temperature reduction reaction, steam generated after the generated flue gas sequentially passes through a gravity settling boiler and a waste heat boiler is used for supplying heat; the residual flue gas is subjected to air mixing, dust removal and wet treatment to realize ultralow emission, zinc oxide powder is collected and recycled in the dust removal process, gravity ash subjected to gravity settling serves as a return material to participate in raw material proportioning again, and a metallized product generated by high-temperature reduction reaction is subjected to heat preservation and transfer to be used for steelmaking production. Harmless treatment of solid waste and resource utilization of iron and zinc-containing dust sludge are really realized.

Description

technical field [0001] The invention relates to the technical field of iron and zinc-containing dust and sludge disposal in the iron and steel industry, in particular to a method for solid waste disposal of iron and zinc-containing dust and sludge in iron and steel enterprises based on the whole process. Background technique [0002] Iron and steel enterprises will inevitably produce a large amount of iron-containing dust and sludge during the production process. Taking a steel enterprise with a production capacity of 10 million tons as an example, the annual production of iron-containing and zinc-containing dust and sludge is 500,000-800,000 tons (dry basis). These dusts contain valuable elements such as iron and carbon, but also harmful elements such as zinc. For a long time, most of the iron-containing dust and sludge produced are directly returned to sintering for utilization, and some of them are stockpiled in the factory or disposed of in a rotary hearth furnace, etc. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B19/30C22B19/34C21B13/00C22B1/16
CPCC22B19/30C22B19/34C22B1/16C21B13/008Y02P10/20
Inventor 朱飞胡晓炜张浩浩赵晖何承泽聂海金陈珂冯建明
Owner CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY
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