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Flexible piezoelectric sensor and preparation method thereof

A flexible piezoelectric and sensor technology, applied in the manufacture/assembly of piezoelectric/electrostrictive devices, piezoelectric/electrostrictive/magnetostrictive devices, circuits, etc., can solve complex and diverse use environments, The film density is not high, the piezoelectric ceramics are brittle, etc., so as to avoid processing difficulties, simple structure and high piezoelectric constant.

Pending Publication Date: 2022-02-08
SUZHOU LEANSTAR ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional and most commonly used piezoelectric sensors mainly use piezoelectric ceramics as piezoelectric materials. Although this sensor has a long history and mature technology, piezoelectric ceramics have shortcomings such as high brittleness, high density, and poor flexibility, which cannot meet complex and diverse applications. The environment, especially in the fields of medical health, robotics, biomechanics, and smart wear, has higher requirements for the flexibility, thinness, and biocompatibility of piezoelectric materials.
[0003] Copolymer polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) piezoelectric material, as a new type of polymer piezoelectric functional material, has good flexibility, high mechanical strength, easy matching of acoustic impedance, wide frequency response range, and chemical resistance. And oily corrosion, can be processed into a large area and complex shape, etc., has been widely studied, it contains a high piezoelectric phase β phase, the film preparation process does not need to be uniaxially stretched, but the film prepared by the current process The density is not high, and there are many defects. During the polarization process, it is easy to cause high voltage breakdown and uneven polarization, resulting in low piezoelectric constant.

Method used

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  • Flexible piezoelectric sensor and preparation method thereof
  • Flexible piezoelectric sensor and preparation method thereof
  • Flexible piezoelectric sensor and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A flexible piezoelectric sensor, comprising a flexible substrate 1, a first electrode 2 is provided on the upper surface of the flexible substrate 1, a piezoelectric film layer 3 is provided on the upper surface of the first electrode 2, and a second electrode is provided on the upper surface of the piezoelectric film layer 3 4. A protective layer 5 is provided on the upper surface of the second electrode 4; the signal transmission sections of the first electrode 2 and the second electrode 4 are arranged separately and dislocated.

[0038] Wherein, piezoelectric thin film layer 3 adopts following preparation method to make:

[0039] S1. Weigh polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) powder with a content of 18%wt;

[0040] S2. Take N, N-dimethylformamide solvent and acetone solvent according to the ratio in Table 1 and mix them to prepare a mixed solvent;

[0041] S3. Dissolving polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) powder in a mixed solven...

Embodiment 2

[0054] The difference from Example 1 is that a method for preparing a flexible piezoelectric film comprises the following steps:

[0055] S1. Weigh polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) powder with a content of 15%wt;

[0056] S2, take triethyl phosphate solvent and acetone solvent and mix according to the ratio in table 2, make mixed solvent;

[0057] S3. Dissolving polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) powder in the mixed solvent, stirring continuously, and heating in a water bath for 1 hour, the temperature of the water bath is 70° C.;

[0058] S4, bonded to the substrate by coating, first baked at 80°C for 60 minutes, then baked at 110°C for 60 minutes, and finally annealed at 140°C for 4 hours to obtain a semi-finished flexible piezoelectric film;

[0059] S5. Polarizing the annealed semi-finished flexible piezoelectric film in air at room temperature with a polarization voltage of 35 MV / cm for 10 minutes to obtain a finished flexible piez...

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Abstract

The invention relates to a flexible piezoelectric sensor and a preparation method thereof. The flexible piezoelectric sensor is provided with a flexible substrate, a first electrode is arranged on the upper surface of the flexible substrate, a piezoelectric film layer is arranged on the upper surface of the first electrode, a second electrode is arranged on the upper surface of the piezoelectric film layer, and a protective layer is arranged on the upper surface of the second electrode; and the signal transmission sections of the first electrode and the second electrode are separately arranged in a staggered manner. According to the preparation method of the piezoelectric film layer, the mixed solvent with the high boiling point and the low boiling point is adopted for solution preparation, deformation caused by uneven tape casting of the edge part of the film in the forming process is avoided, and meanwhile machining difficulty caused by the fact that the solvent with the low boiling point is prone to volatilization is also avoided; and the piezoelectric sensor prepared by the invention has the advantages of simple structure, small volume, high sensitivity, good flexibility, high piezoelectric constant and good biocompatibility, is suitable for irregular object surfaces, and can be produced on a large scale.

Description

technical field [0001] The invention relates to the technical field of piezoelectric sensors, in particular to a flexible piezoelectric sensor and a preparation method thereof. Background technique [0002] As a sensing element, piezoelectric sensors have been used in a wide range of applications. Typical applications include medical, aerospace, consumer electronics, and nuclear instruments. The traditional and most commonly used piezoelectric sensors mainly use piezoelectric ceramics as piezoelectric materials. Although this sensor has a long history and mature technology, piezoelectric ceramics have shortcomings such as high brittleness, high density, and poor flexibility, which cannot meet complex and diverse applications. The environment, especially in the fields of medical health, robotics, biomechanics, and smart wear, has higher requirements for the flexibility, lightness, and biocompatibility of piezoelectric materials. [0003] Copolymer polyvinylidene fluoride-tri...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L41/047H01L41/113H01L41/45H01L41/317H01L41/257H10N30/87H10N30/045H10N30/077H10N30/098H10N30/30
CPCH10N30/87H10N30/302H10N30/045H10N30/077H10N30/098
Inventor 朱四美周震
Owner SUZHOU LEANSTAR ELECTRONICS TECH
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