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Composite plated part and manufacturing method thereof

A manufacturing method and composite plating technology, applied to contact parts, electrical components, coatings, etc., can solve problems such as inaccessible contacts or terminals with high life expectancy and high friction coefficient

Pending Publication Date: 2022-03-04
DOWA METALTECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the composite plated parts produced by the methods of Patent Documents 1 to 3 have the problem that the coefficient of friction is high and cannot cope with the increase in the life of contacts or terminals. Compared with plated parts, the content of carbon particles and the proportion of carbon particles on the surface are increased, and the composite plated parts are more excellent in wear resistance

Method used

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  • Composite plated part and manufacturing method thereof
  • Composite plated part and manufacturing method thereof
  • Composite plated part and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] As carbon particles, 6% by weight of flaky graphite particles having an average particle diameter of 5 μm was added to 3 L of pure water, and the mixed solution was heated up to 50° C. while stirring. Next, 1.2 L of a 0.1 mol / L potassium persulfate aqueous solution was slowly added dropwise to the mixed solution as an oxidizing agent, followed by stirring for 2 hours to carry out oxidation treatment, followed by filtration with filter paper and washing with water.

[0040] The carbon particles before and after the oxidation treatment were analyzed using a purge-and-trap gas chromatography-mass spectrometer (Japan Analytical Industry JHS-100) (GCMAS QP-5050A manufactured by Shimadzu Corporation) to analyze the gas generated by heating at 300°C. , lipophilic aliphatic hydrocarbons (such as nonane, decane, 3-methyl-2-heptene, etc.) and lipophilic aromatic hydrocarbons (such as xylene) adhering to the carbon particles have been removed by the above oxidation treatment.

[0...

Embodiment 2

[0050] A composite plated material was produced in the same manner as in Example 1 except that the ultrasonic cleaning time was 250 seconds.

[0051] For the obtained composite plated material, the area ratio (area ratio) occupied by the carbon particles on the surface of the composite plated film was calculated by the same method as in Example 1. As a result, the area ratio was 26 area%, the area ratio of the composite plated article before the treatment to remove part of the surface carbon was 64 area%, and the change in the area ratio based on the treatment of removing part of the surface carbon was 38 area% (=64 area%-26 area%), and the rate of change of the area ratio was 59 area% (=(64-26) area%×100 / 64 area%).

[0052] Moreover, arithmetic average roughness Ra was calculated by the same method as Example 1 about the obtained composite plated material, and it was 0.55 micrometers.

[0053] Moreover, the wear resistance was evaluated by the same method as Example 1 about ...

Embodiment 3

[0056]The same raw material as in Example 1 was used as the cathode, and the Ni electrode plate was used as the anode. In a nickel plating bath composed of 80g / L nickel sulfamate and 45g / L boric acid, the , current density 4A / dm 2 Electroplating (Ni plating) was performed for 30 seconds while stirring, and Ag strike plating was performed after forming a Ni plating film with a thickness of 0.3 μm on the raw material. A composite plated article was produced by the same method as in Example 1.

[0057] For the obtained composite plated material, the area ratio (area ratio) occupied by the carbon particles on the surface of the composite plated film was calculated by the same method as in Example 1. As a result, the area ratio was 32 area%, the area ratio of the composite plated article before the treatment to remove part of the carbon on the surface was 64 area%, and the change in the area ratio based on the treatment to remove part of the surface carbon was 32 area% (=64 area%-...

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Abstract

Provided are: a composite plated article in which a composite plating film comprising a composite material in which carbon particles are contained in a silver layer is formed on a raw material, wherein the carbon particles in the composite plating film do not fall off easily; and a method for producing the composite plated article. A composite plating film comprising a composite material in which carbon particles are contained in a silver layer is formed on a raw material (preferably comprising copper or a copper alloy) by electroplating using a silver plating solution to which carbon particles are added, and then a treatment for removing a portion of the carbon particles on the surface is performed.

Description

technical field [0001] The present invention relates to a composite plated article and a manufacturing method thereof, and particularly relates to a composite plated article used as a material for sliding contact parts such as switches and connectors, and a method for manufacturing the same. Background technique [0002] Conventionally, as materials for sliding contact parts such as switches and connectors, in order to prevent oxidation of conductive materials such as copper or copper alloys caused by heating during sliding, silver-plated materials that are plated with silver on conductive materials have been used. [0003] However, since silver plating is soft and easy to wear, and generally has a high coefficient of friction, there is a problem that it tends to peel off due to sliding. In order to solve this problem, it has been proposed to form a film of a composite material in which graphite particles are dispersed in a silver matrix by electroplating among carbon partic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D3/46C25D5/48C25D7/00C25D15/00
CPCC25D3/46C25D15/00C25D7/00C25D5/48C25D5/12H01H1/027C25D15/02H01R13/03H01H1/04H01H11/04H01H1/023Y10T428/12625
Inventor 小谷浩隆加藤有纪也土井龙大富谷隆夫成枝宏人
Owner DOWA METALTECH CO LTD