Antibacterial heterogeneous porous membrane and preparation method thereof
A porous membrane, heterogeneous technology, used in medical science, surgery, etc., can solve the problems of infection of new tissues, poor bacteriostatic properties, poor elasticity and mechanical properties, and achieve the effect of protecting space, good elasticity and mechanical properties
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[0039] The embodiment of the present invention also relates to the preparation method of the antibacterial heterogeneous porous membrane, the method comprising the following steps:
[0040] (1) Preparation of collagen slurry: mix type I collagen and elastin, add acidic solution, stir and mix to obtain collagen slurry. Divide the collagen slurry into 3 parts for preparing loose porous layer, antibacterial dense layer and bonding.
[0041] In one embodiment of the present invention, the mass ratio of type I collagen to elastin is (70-90):(10-30). Among them, the elastin organization structure can effectively improve the elasticity and mechanical properties of the porous membrane, such as tensile strength and elastic modulus.
[0042] In one embodiment of the present invention, the acidic solution is an aqueous solution of acetic acid or phosphoric acid, with a mass concentration of 0.02-0.10 wt%. The effect of adding acidic solution is to dissolve type I collagen and elastin t...
Embodiment 1
[0061] The antibacterial heterogeneous porous membrane is prepared by the following method:
[0062] (1) Preparation of collagen slurry: 1.6 g of 90% type I collagen and 10% elastin mixture were placed in 120 mL of 0.08 wt% acetic acid aqueous solution, mechanically stirred at 20°C and 800 rpm for 3 h , to obtain a collagen slurry. The collagen slurry prepared above is divided into three parts, which are used for preparing a loose porous layer, an antibacterial dense layer and bonding.
[0063] (2) Preparation of a loose porous layer: Add 0.0005 g of EDC / NHS (molar ratio 2:1) as a cross-linking agent to 150 mL of collagen slurry, and stir at 100 rpm at room temperature under the irradiation of ultraviolet light with a wavelength of 280 nm After reacting for 6 hours, pour the reacted mixed solution into a mold for freeze-drying. The depth of the mold is 0.5 mm to obtain a loose porous layer. The loose porous layer prepared above was washed 3 times with purified water, and pla...
Embodiment 2
[0069] In step (1), 1.6 g of protein mixture contains 80% type I collagen and 20% elastin, and other steps are the same as in Example 1.
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