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Main grid silver paste used in cooperation with front aluminum paste of N-type TOPCon battery and preparation method of main grid silver paste

A battery and aluminum paste technology, which is applied in the field of solar cells, can solve the problems of grid line falling off at overlapping joints, less P+ layer formation, and inability to achieve the effects of good printing and line width, reduced fine grid resistance, and excellent welding tension

Pending Publication Date: 2022-03-22
JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Defects and insufficiencies of the existing technology: currently on the market, the positive silver-aluminum paste mainly provides a good contact effect after sintering, and cannot or rarely forms a P+ layer, and has almost no gain to Voc
On the other hand, because this project is supporting the use of aluminum paste, there is a co-firing of silver and aluminum. The co-firing of silver and aluminum will cause various failures caused by the violent reaction of silver and aluminum, including the grid wire falling off at the overlap, and EL blackening and other common exceptions

Method used

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  • Main grid silver paste used in cooperation with front aluminum paste of N-type TOPCon battery and preparation method of main grid silver paste

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A busbar silver paste used in conjunction with the front aluminum paste of an N-type TOPCon battery is prepared from the following components according to the mass percentage:

[0025] Highly dispersed and highly active spherical silver powder 75%: spherical, particle size 0.3μm, D100<2μm, specific table 1.8-2.0, tap density 4.5g / ml, burning loss 0.5-0.55%, silver powder surface coating agent must be at 270℃ can be decomposed within;

[0026] Nano-silver powder 10%: the particle size is about 80nm, and can be sintered at a low temperature within 200°C;

[0027] Low-melting ultra-fine glass powder 1%: average particle size 0.5μm; softening point 310°C, composition is 65% lead fluoride, 20% calcium fluoride, 2% silicon oxide, 6% boron oxide, 1% aluminum oxide, Zinc oxide 6%;

[0028] Organic vehicle 11%: The main components are resin and solvent, which are mixed, heated, stirred, and boiled at a temperature of 80°C.

[0029] The resin accounts for 5% of the weight of t...

Embodiment 2

[0036] A busbar silver paste used in conjunction with the front aluminum paste of an N-type TOPCon battery is prepared from the following components according to the mass percentage:

[0037] Highly dispersed and highly active spherical silver powder 85%: spherical, particle size 0.5μm, D100<2μm, specific table 1.0-1.2, tap density 5.5g / ml, burning loss 0.4%, silver powder surface coating agent must be decomposed at 280°C Finish;

[0038] Nano-silver powder 1%: particle size 50nm, and low-temperature sintering can be completed at 200°C;

[0039] Low-melting ultra-fine glass powder 3%: average particle size 1μm; softening point 340°C, components are 90% lead oxide, 6% boron oxide, and 4% zinc oxide;

[0040] Organic carrier 8.5%: The main components are resin and solvent, which are mixed, heated, stirred, and boiled at 60°C;

[0041] The resin accounts for 15% of the weight of the carrier, containing 5% ethyl cellulose and 10% PVB resin;

[0042] The solvent is 85% of the we...

Embodiment 3

[0048] A busbar silver paste used in conjunction with the front aluminum paste of an N-type TOPCon battery is prepared from the following components according to the mass percentage:

[0049] Highly dispersed and highly active spherical silver powder 78%: spherical, particle size 0.4μm, D100<2μm, specific table 1.4-1.6, tap density 5g / ml, burning loss 0.5%, and silver powder surface coating agent can be decomposed within 270℃ Finish;

[0050] Nano silver powder 3%: particle size 30nm, and low temperature sintering can be completed at 200°C;

[0051] Low-melting ultra-fine glass powder 2%: average particle size 0.7μm; softening point 330°C, composition is lead fluoride 50%, bismuth oxide 20%, silicon oxide 6%, boron oxide 10%, aluminum oxide 2%, oxide Zinc 12%;

[0052] Organic carrier 12%: the main components are resin and solvent, mix, heat and stir the two, and boil at 70°C;

[0053] The resin accounts for 25% of the weight of the carrier, containing 5% ethyl cellulose, 1...

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Abstract

The invention provides main grid silver paste matched with front aluminum paste of an N-type TOPCon battery for use, which is prepared from the following components in percentage by mass: 75-85% of high-dispersion and high-activity spherical silver powder, 1-10% of nano silver powder, 1-3% of low-melting superfine glass powder, 7-15% of an organic carrier, 0.5-2% of a dispersing agent, 0-2% of a thixotropic agent and 0-2% of a slipping agent. According to the invention, the diffusion of silver and aluminum and the damage of high temperature to the battery can be avoided, better welding tension can be provided during low-temperature sintering, the resistance of the fine grid can be obviously reduced, and the conversion efficiency can be improved by more than 0.05% on year-on-year basis.

Description

technical field [0001] The invention relates to the technical field of solar cells, in particular to a busbar silver paste used in conjunction with the front aluminum paste of an N-type TOPCon battery and a preparation method thereof. Background technique [0002] The development of solar technology is changing with each passing day, and new cell technologies and processes are constantly emerging. The current PERC process will eventually be replaced by HJT or Topcon (Tunnel Oxide Passivating Contacts) tunnel oxide passivating contact cells. Compared with HJT, Topcon technology has the advantages of low cost of ownership and good inheritance with PERC technology. It is still the mainstream of solar cell technology in the past 3-5 years. At present, the conductive paste used for front metallization of Topcon batteries is mainly silver-aluminum paste. [0003] Defects and insufficiencies of the existing technology: At present, the positive silver-aluminum paste on the market m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/16H01B1/22H01B13/00H01L31/0224
CPCH01B1/16H01B1/22H01B13/00H01L31/0224
Inventor 冷青松刘瑞鸿丰昭耿心彤许飞赵军
Owner JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD