Sodium-based oxygen production molecular sieve and production process thereof

A production process and technology of molecular sieves, applied in the field of molecular sieves, can solve the problems affecting the purity of oxygen, the surface of molecular sieves is not smooth enough, the molecular sieves are deactivated, etc., and achieve the effect of good polishing effect, convenient polishing treatment and better performance

Inactive Publication Date: 2022-04-22
南京永成分子筛有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the molecular sieve prepared by this method is easy to absorb water molecules in the air in the pore structure during use, which not only easily affects the purity of the obtained oxygen, but also easily leads to the inactivation of the molecular sieve; If the surface is not smooth enough, it is easy to make the oxygen production effect of the molecular sieve poor

Method used

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  • Sodium-based oxygen production molecular sieve and production process thereof
  • Sodium-based oxygen production molecular sieve and production process thereof
  • Sodium-based oxygen production molecular sieve and production process thereof

Examples

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preparation example Construction

[0042] The preparation method of this molecular sieve comprises the following steps:

[0043] Dry mixing: first mix and stir the molecular sieve powder and clay, then add solid amine and silane coupling agent to continue mixing and stirring to obtain a mixture;

[0044] Granulation: granulate the mixed material to obtain spherical particles;

[0045] Polishing: polishing the spherical particles to obtain crude products;

[0046] Dehumidification and activation: Dehumidification and activation are performed on the crude product in sequence to obtain a finished molecular sieve.

[0047] The mass parts of each component of the molecular sieve in this embodiment is more preferably 90-110 parts of molecular sieve powder, 40-50 parts of clay, 7-9 parts of solid amine, and 9-11 parts of silane coupling agent.

[0048] The molecular sieve powder in this embodiment is the hydrate of crystalline sodium aluminosilicate;

[0049] The clay in this embodiment includes at least one of kao...

Embodiment 1

[0059] A sodium-based oxygen-producing molecular sieve, comprising the following components in parts by mass: 100 kg of molecular sieve raw powder, 45 kg of clay, 8 kg of solid amine, and 10 kg of silane coupling agent.

[0060] Wherein the molecular sieve raw powder is the hydrate of crystalline sodium aluminosilicate;

[0061] The clay is bentonite;

[0062] The solid amine is a mixture of tetraethylenepentamine, pentaethylenehexamine and polyethyleneimine in a mass ratio of 1:1:4;

[0063] The silane coupling agent is KH-560;

[0064] The ratio of the average particle size of the molecular sieve raw powder to the average particle size of the clay is 9:1.

[0065] The preparation method of this molecular sieve comprises the following steps:

[0066] S1 dry mixing: first mix and stir the molecular sieve powder and clay, control the stirring speed to 1000rpm, adjust the stirring speed to 600rpm after stirring for 1h, add solid amine and silane coupling agent, and continue s...

Embodiment 6

[0082] The difference between this example and Example 1 is that the ratio of the molecular sieve raw powder to the average particle size of the clay is 7:1.

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Abstract

The invention relates to the technical field of molecular sieves, and particularly discloses a sodium-based oxygen production molecular sieve and a production process thereof. The oxygen production molecular sieve comprises the following raw materials: molecular sieve raw powder, clay, solid amine and a silane coupling agent. The production process of the oxygen production molecular sieve comprises the following steps: firstly, mixing and stirring molecular sieve raw powder and clay, then adding solid amine and a silane coupling agent, and continuously stirring to prepare a mixed material; granulating and forming the mixed material to obtain spherical particles; polishing the spherical particles by using a polishing device to obtain a crude product; and finally, dehumidifying and activating the crude product in sequence to prepare the finished molecular sieve. The molecular sieve prepared by the invention has a good barrier effect on water molecules in air, so that the molecular sieve can keep relatively high activity; meanwhile, the molecular sieve has good carbon dioxide adsorption performance, so that the purity of oxygen prepared from the molecular sieve is relatively high. Meanwhile, the surface of the molecular sieve is smooth, so that the oxygen production effect of the molecular sieve is better.

Description

technical field [0001] The application relates to the technical field of molecular sieves, more specifically, it relates to a sodium-based oxygen-producing molecular sieve and its production process. Background technique [0002] Molecular sieve is an aluminosilicate compound with a cubic lattice, and molecular sieve has a uniform microporous structure, which can adsorb molecules smaller than its diameter into the interior of the cavity, and has a preference for polar molecules and unsaturated molecules. Adsorption capacity, so it can separate molecules with different polarity, saturation, molecular size and boiling point, that is, it has the function of "sieving" molecules, so it is called molecular sieve. [0003] Due to the unique adsorption capacity of molecular sieves, molecular sieves have a good application in the field of oxygen production. That is, oxygen is prepared from air. Since the air is rich in nitrogen and oxygen, and the quadrupole moment of nitrogen is st...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/26B01J20/28B01J20/30C01B13/02B24B31/033B24B31/12B24B47/00
CPCB01J20/12B01J20/183B01J20/22B01J20/261B01J20/28019B01J20/3028C01B13/0274B24B31/033B24B31/12B24B47/00C01B2210/0062C01B2210/0028
Inventor 王成王勇
Owner 南京永成分子筛有限公司
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