Water-based paint and article coated with same
A water-based paint, water-based medium technology, applied in anti-fouling/underwater paint, polyurea/polyurethane paint, coatings, etc., can solve the problem of low safety of paint
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[0055] As a preparation method of the water-based paint of the present invention, for example, the above-mentioned visible light-responsive photocatalyst (A) and pigments can be added to the water-based resin composition obtained by dispersing the above-mentioned resin (R) in the above-mentioned water-based medium (W), and use Sand mill, disperser and other mixing machines for preparation. If necessary, by further mixing a curing agent, a two-component type paint can be prepared.
[0056] As the coating method of the water-based paint of the present invention, for example, a gravure coater, a roll coater, a comma coater, a knife coater, an air knife coater, a curtain coater, a kiss coater, etc. Cloth machine, spray coater, wheel coater, spin coater, dipping, screen printing, spraying, applicator, rod coater, brushing and other methods.
[0057] The water-based paint of the present invention can provide a cured coating film excellent in virus resistance to the surface of vario...
preparation example 1
[0063] (Preparation Example 1: Preparation of Visible Light Responsive Photocatalyst (A-1))
[0065] a) Crystalline rutile titanium oxide
[0066] b) Preparation method: liquid phase method (sulfuric acid method)
[0067] c) Physical property value
[0068] · BET specific surface area: 9.0m 2 / g
[0069] · Rutile rate: 95.4%
[0070] ·Primary particle size: 0.18μm
[0071] (2) Manufacturing process
[0072] a) Mixing process (reaction process)
[0073] 600 parts by mass of the aforementioned titanium oxide, 8 parts by mass of copper chloride (ii) dihydrate, and 900 parts by mass of water were mixed in a stainless steel container. Next, the mixture was stirred with a stirrer ("ROBO MICS" manufactured by Tokuku Kikka Kogyo Co., Ltd.), and a 1 mol / L sodium hydroxide aqueous solution was added dropwise until the pH of the mixed solution became 10.
[0074] b) Dehydration process
[0075] Filtration under reduced pressure was carried out using ...
Embodiment 1
[0078] (Example 1: manufacture of water-based paint (1))
[0079] 11.2 parts by mass of the visible light-responsive photocatalyst (A-1) obtained above, titanium oxide pigment (manufactured by Chemours "Ti-Pure R-706") 33.7 parts by mass and 19.9 parts by mass of ion-exchanged water were kneaded for 30 minutes with a sand mill to obtain a pigment dispersion. 29.3 parts by mass of a polyisocyanate resin ("Burnock DNW-5500" manufactured by DIC Corporation) was added as a curing agent to the obtained pigment dispersion, and stirred for 5 minutes with a disperser to obtain an aqueous paint (1).
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