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Coating as well as preparation method and application thereof

A coating and coating technology, used in polyurea/polyurethane coatings, coatings, semiconductor devices, etc., can solve the problems of low coating hardness and service life, low coating adhesion, and increased pollution, and achieve wear resistance. And outdoor self-cleaning effect, good wear resistance, long life effect

Active Publication Date: 2022-05-17
国家电投集团杭州新能源生产运营有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these coatings usually have low adhesion, which makes the coating hardness and service life low, and with the attachment of pollutants on the coating surface, its super-hydrophobic surface will gradually no longer be hydrophobic, and the attachment of water droplets will cause pollution. Intensified, loses effect in a short time

Method used

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  • Coating as well as preparation method and application thereof
  • Coating as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] This embodiment provides a kind of coating, and the raw material of described coating comprises 1.5 parts of polyurethane acrylates (Shandong Ruili PUA), 3 parts of vinyltriethoxysilanes, 1.5 parts of titanate coupling agents (iso Propyl tris (dioctyl pyrophosphate acyloxy) titanate, Jinan Rongguang Chemical Industry GR201), 0.5 parts of 2-hydroxy-2-methyl-1-phenyl ketone and 0.5 parts of nano titanium dioxide (Shanghai Chaowei Nanotechnology C25).

[0053] The present embodiment provides a kind of preparation method of described coating, and concrete steps comprise:

[0054] Premix vinyltriethoxysilane and titanate coupling agent in a mixed solution of water and methanol (the mass ratio of water and methanol is 4:3) for 12 hours according to the formula to obtain modified silane; The modified silane is mixed with urethane acrylate, 2-hydroxy-2-methyl-1-phenyl ketone and nano-titanium dioxide to obtain the coating; the solid content of the coating is 9.1%.

Embodiment 2

[0056] The present embodiment provides a kind of coating, and the raw material of described coating comprises 0.5 part of polyurethane acrylate (Shandong Ruili PUA), 1 part of vinyltriethoxysilane, 0.8 part of titanate coupling agent (Jinan Rongguang Chemical GR201), 0.01 part of 2-hydroxy-2-methyl-1-phenyl ketone and 0.1 part of nano strontium titanate (Beijing Gaoke, particle size 10nm).

[0057] The present embodiment provides a kind of preparation method of described coating, and concrete steps comprise:

[0058] According to the formula quantity, vinyltriethoxysilane and titanate coupling agent were premixed for 12 hours in a mixed solution of water and methanol (the mass ratio of water and methanol was 1:1) to obtain modified silane; The modified silane is mixed with polyurethane acrylate, 2-hydroxy-2-methyl-1-phenyl ketone and nano-strontium titanate to obtain the coating; the solid content of the coating is 5.7%.

Embodiment 3

[0060] The present embodiment provides a kind of coating, and the raw material of described coating comprises 2 parts of novolac epoxy acrylates (Jiangyin Getai Chemical Industry GT-3218), 5 parts of gamma-(methacryloyloxy)propyl trimethoxy in parts by weight. base silane, 1 part of titanate coupling agent (Jinan Rongguang Chemical GR201), 1 part of 2-hydroxy-2-methyl-1-phenyl ketone and 1 part of nano zinc sulfide (Zhejiang Yamei Nano Technology AM- ZnS, particle size 100nm).

[0061] The present embodiment provides a kind of preparation method of described coating, and concrete steps comprise:

[0062] Premix γ-(methacryloyloxy)propyltrimethoxysilane and titanate coupling agent in a mixed solution of water and methanol (the mass ratio of water and methanol is 6:5) for 12 hours according to the formula quantity , to obtain modified silane; the modified silane is mixed with novolac epoxy acrylate, 2-hydroxyl-2-methyl-1-phenyl ketone and nano-zinc sulfide to obtain the coating...

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Abstract

The invention provides a coating as well as a preparation method and application thereof. The coating is prepared from the following raw materials in parts by weight: 0.5 to 4 parts of light-cured resin, 1 to 5 parts of silane, 0.8 to 5 parts of ester coupling agent, 0.01 to 1 part of photoinitiator and 0.1 to 1 part of photocatalyst. According to the coating provided by the invention, the silane is treated by adopting the ester coupling agent, so that the silane forms a super-hydrophilic surface after cross-linking curing or condensation, and the coating has self-cleaning capability; the photoinitiator initiates crosslinking curing of the light-cured resin to form a three-dimensional network structure, the three-dimensional network structure is coated with the photocatalyst, and the photocatalyst is continuously released through the slow release effect, so that organic pollutants are decomposed, and the self-cleaning effect is further improved; meanwhile, the strength and the service life of the material are remarkably improved, and the material has an antireflection effect and is suitable for the field of photovoltaic modules.

Description

technical field [0001] The invention belongs to the technical field of self-cleaning materials, and in particular relates to a coating and its preparation method and application. Background technique [0002] During the use of photovoltaic modules, with the accumulation of dust, the power generation is gradually reduced. If there is no cleaning, operation and maintenance, the power generation will rapidly decay. However, photovoltaic operation and maintenance cleaning is usually not very simple and convenient. First of all, the installation of photovoltaic modules will be in various complex environments such as mountainous areas, water surfaces, seas, and the top floors of various buildings. The roads are not smooth, and many photovoltaic power stations do not have the water and electricity required for operation, maintenance and cleaning; secondly, There are many kinds of pollutants on photovoltaic modules, such as smog, industrial waste gas (welding, industrial dust, heat...

Claims

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Application Information

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IPC IPC(8): C09D175/14C09D133/04C09D183/04C09D7/61C09D7/63H01L31/0216H02S40/10
CPCC09D175/14C09D133/04C09D183/04C09D7/61C09D7/63H01L31/02168H02S40/10C08K2201/011C08K2003/2241C08K2003/2237C08K2003/3036C08K5/5425C08K5/0091C08K3/22C08K3/30Y02E10/50
Inventor 王文清许峰周琪权陈玲孙祥陈洪野吴小平郭伟栋王智琦
Owner 国家电投集团杭州新能源生产运营有限公司