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Preparation method of hierarchical porous carbon fiber cloth capable of adsorbing and degrading formaldehyde

A carbon fiber cloth and multi-level hole technology, which is applied in the field of preparation of multi-level hole carbon fiber cloth, can solve the problems of secondary environmental pollution, human cell disease, potential danger, etc., and achieves lower use costs and lower volatile organic compounds. Effect

Inactive Publication Date: 2022-05-24
哈尔滨悟山青环保科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] From the above introduction, it can be seen that the photocatalyst TiO 2 The spraying of medicaments into the air achieves the purpose of removing formaldehyde, but the problem that is widely ignored is that there is no effect on the photocatalyst TiO 2 Recycling, it is easy to cause secondary pollution to the environment, nano-sized TiO 2 Contact with the human body will cause human cell lesions, and there is a potential danger

Method used

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  • Preparation method of hierarchical porous carbon fiber cloth capable of adsorbing and degrading formaldehyde
  • Preparation method of hierarchical porous carbon fiber cloth capable of adsorbing and degrading formaldehyde

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Embodiment approach 1

[0029] A preparation method of a hierarchical porous carbon fiber cloth that collects adsorption and degradation of formaldehyde, the method comprises the following steps:

[0030] S1: ultrasonically disperse the iron salt and dimethylformamide in a weight ratio of 1:10-20 to form a mixed solution A, the ambient temperature during the mixing process is 25°C-30°C, and the relative humidity of the environment is 25% -50%, the types of iron salts include one or several combinations of iron sulfate, iron nitrate, and iron chloride;

[0031] Preferably, the weight ratio of iron salt and dimethylformamide is 1:10-13;

[0032] S2: The polyacrylonitrile with a molecular weight of 150,000, polyvinylpyrrolidone with a molecular weight of 360,000 and dimethylformamide amine are stirred and dispersed at room temperature in a weight ratio of 3:0.1-1:4-10 to form a mixed solution B;

[0033] Preferably, polyacrylonitrile with a molecular weight of 150,000, polyvinylpyrrolidone with a mole...

Embodiment approach 2

[0040] A preparation method of a hierarchical porous carbon fiber cloth that collects adsorption and degradation of formaldehyde, the method comprises the following steps:

[0041] S1: ultrasonically disperse the iron salt and dimethylformamide in a weight ratio of 1:10-20 to form a mixed solution A, the ambient temperature during the mixing process is 25°C-30°C, and the relative humidity of the environment is 25% -50%, the types of iron salts include one or several combinations of iron sulfate, iron nitrate, and iron chloride;

[0042] Preferably, the weight ratio of iron salt and dimethylformamide is 1:10-13;

[0043] S2: The polyacrylonitrile with a molecular weight of 150,000, polyvinyl pyrrolidone with a molecular weight of 360,000 and dimethylformamide are stirred and dispersed at room temperature in a weight ratio of 3:0.1-1:4-10 to form a mixed solution B ;

[0044] Preferably, the weight ratio between polyacrylonitrile with a molecular weight of 150,000, polyvinylpy...

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Abstract

The invention relates to the field of preparation of carbon fiber cloth, in particular to a preparation method of hierarchical pore carbon fiber cloth integrating formaldehyde adsorption and degradation, which comprises the following steps: S1, mixing ferric salt and dimethylformamide to form a solution A; s2, mixing polyacrylonitrile with the molecular weight of 150000, polyvinylpyrrolidone with the molecular weight of 360000 and dimethylformamide to form a solution B; s3, mixing titanium tetrachloride, water and ethanol, and drying to form a substance C; s4, mixing the solution A, the solution B and a substance C to form a solution D, transferring the solution D into an injector for electrospinning to obtain a fiber membrane, and calcining the fiber membrane to form the hierarchical porous carbon fiber cloth; the hierarchical porous carbon fiber cloth has a formaldehyde adsorption function, nano TiO2 distributed on the hierarchical porous carbon fiber cloth can react with O2 and H2O in the air to generate. O2 <-> and. OH so as to achieve the purpose of oxygenolysis of formaldehyde, and the carbon fiber cloth can be recycled, does not cause secondary pollution to the environment, and reduces the use cost of a user.

Description

technical field [0001] The invention relates to the field of carbon fiber cloth preparation, in particular to a preparation method of a multi-level porous carbon fiber cloth which integrates adsorption and degradation of formaldehyde. Background technique [0002] The traditional formaldehyde removal is to spray the photocatalyst TiO in the air 2 Pharmacy, for TiO 2 For semiconductors, its photocatalytic mechanism is to use sunlight to irradiate TiO 2 On the catalyst, when the energy of the irradiated light is greater than that of TiO 2 , the light can be absorbed by the TiO 2 absorption, in TiO 2 The electrons in the valence band are activated to transition to the conduction band, thus, in TiO 2 There will be highly active photogenerated electrons (e - ) is generated, and a positively charged photogenerated hole (h) appears in its valence band. + ). Photogenerated electrons are reductive, photogenerated holes are strongly oxidative, and electron acceptors (such as O...

Claims

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Application Information

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IPC IPC(8): B01J20/20B01J20/28B01J20/30B01D53/02B01D53/86B01D53/72
CPCB01J20/205B01J20/28033B01J20/28078B01J20/28023B01J20/06B01D53/02B01D53/8668B01D2255/20707B01D2257/704Y02C20/30
Inventor 于振江迟木子赵天烁
Owner 哈尔滨悟山青环保科技有限公司
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