Self-polishing antifouling paint and preparation method thereof

A technology of self-polishing and antifouling paint, which is applied in the direction of antifouling/underwater paint, paint containing biocide, coating, etc. It can solve the problems of not being able to meet environmental protection requirements and high content, and achieve improved hydrophobicity and controllable hydrolysis Sex, good hydrophobicity and lubricity, and the effect of increasing solid content

Active Publication Date: 2016-04-13
CHINA NAT OFFSHORE OIL CORP +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The Intersmooth365 product of the International Coatings Company belonging to the same category as the above is prepared from copper acrylate self-polishing resin, cuprous oxide, and zinc zinc. Its volume solid content is 40%, and its VOC (volatile organic compound) content is high. Current Environmental Requirements

Method used

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  • Self-polishing antifouling paint and preparation method thereof
  • Self-polishing antifouling paint and preparation method thereof
  • Self-polishing antifouling paint and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0028] Embodiment 1 prepares self-polishing antifouling paint 1 and 2

[0029] In 100 parts by mass of the self-polishing antifouling paint of the present invention, there are 18 to 24 parts of resin in solids, 50 to 55 parts of antifouling agent, 0.5 to 1.5 parts of graphene microflakes, 3 to 6 parts of pigments and fillers, and 1 to 5 parts of dispersant. 2 parts, 1-2 parts of organic bentonite, and the balance is organic solvent;

[0030] The 18-24 parts of solid-based resin is composed of 4 parts of solid-based hydroxyl acrylic resin, 4-6 parts of solid-based zinc acrylate resin, and the balance is rosin, wherein the zinc content of solid-based zinc acrylate resin is 12-15wt %, the hydroxyl content of the hydroxy acrylic resin in solids is 4 to 5wt%;

[0031] The 50-55 parts of antifouling agent is composed of 3 parts of copper pyrithione, 3 parts of 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one, 30-35 parts of cuprous oxide , the balance is composed of zinc oxide;

[003...

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Abstract

The invention relates to a self-polishing antifouling paint and a preparation method thereof. Every 100 parts by mass of the antifouling paint is composed of 18-24 parts of solid-based resin, 50-55 parts of antifouling compound, 0.5-1.5 parts of graphene microchip, 3-6 parts of pigment and filler, 1-2 parts of dispersing agent, 1-2 parts of organobentonite and the balance of organic solvent. The resin is composed of a hydroxy acrylic resin, a zinc acrylate resin and rosin. The antifouling compound is composed of zinc pyrithione, 4,5-dichloro-2-n-octyl-4-isothiazolinyl-3-one, cuprous oxide and zinc oxide. The preparation method comprises the following steps: respectively preparing the graphene microchip-zinc oxide-hydroxy acrylic resin slurry and cuprous oxide-rosin-zinc acrylate slurry, and mixing to obtain the self-polishing antifouling paint. The obtained self-polishing antifouling paint product has the advantages of stable quality, long antifouling period, favorable polishing effect, high strength, cracking resistance and low VOC (volatile organic compound).

Description

technical field [0001] The invention relates to a self-polishing antifouling paint and a preparation method thereof, which is especially suitable for ship bottom antifouling. Background technique [0002] The attachment and fouling of marine organisms to the bottom of the ship increases the roughness of the outer surface of the bottom of the ship, increases the navigation resistance, reduces the speed of the ship, and increases the fuel consumption. In addition, the adhesion and fouling of marine organisms to the hull also accelerates the corrosion of the hull, shortens the service life of the ship, and poses a hazard to navigation safety. According to incomplete estimates, the economic loss caused by marine biofouling in the world exceeds 1 billion US dollars every year. Therefore, preventing the attachment and fouling of marine organisms has always been an important task in naval defense construction, marine transportation and marine engineering development. In order to ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D193/04C09D5/16C09D7/12
CPCC08L2205/03C09D5/1618C09D5/1625C09D7/61C09D193/04C08L33/02C08K13/02C08K5/378C08K5/47C08K2003/2248C08K2003/2296C08K3/04
Inventor 马胜军王秀娟李敏方健君张伟丽徐科靳美亮狄志刚
Owner CHINA NAT OFFSHORE OIL CORP
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