Positive electrode material and preparation method thereof, positive plate and lithium ion battery
A technology of positive electrode material and positive electrode sheet, which is applied in the field of positive electrode sheet and lithium ion battery, positive electrode material and its preparation, can solve the problems of volume change, battery safety performance degradation, accelerated Co metal dissolution and O precipitation, etc., to expand the diffusion channel , stable structure and high energy density
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Embodiment 1
[0034] 1. Weigh the raw material Co according to the weight ratio of 688:317:2:1 3 O 4 , Li 2 CO 3 , Mg(OH) 2 and Y 2 O 3 ;
[0035] 2. Put the Co in step 1 3 O 4 , Li 2 CO 3 , Mg(OH) 2 and Y 2 O 3 Placed in a ball mill for ball milling and mixing for 10 hours at a speed of 500 r / min to obtain a Mg-Y co-doped lithium cobalt oxide precursor, that is, a pretreatment reactant;
[0036] 3. Put the Mg-Y co-doped lithium cobalt oxide precursor (pretreatment reactant) into a muffle furnace for 400 ℃ low temperature pre-sintering treatment for 10 hours, and then heat up to 850 ℃ for 8 hours for high temperature calcination treatment to obtain Mg -Ln co-doped lithium cobalt oxide crude sample;
[0037]4. The Mg-Y co-doped lithium cobalt oxide coarse sample is sieved and processed to finally obtain LiMg 0.008 Y x Co 1-x O 2 Cathode materials such as figure 1 and figure 2 As shown, the surface of the doped lithium cobalt oxide is rougher, and small particles appear o...
Embodiment 2
[0039] The difference from Example 1 is that the metal compound containing A-type elements is ZrO 2 .
[0040] The rest are the same as those in Embodiment 1, and are not repeated here.
Embodiment 3
[0042] The difference from Example 1 is that the metal compound containing A-type elements is Ln 2 O 3 .
[0043] The rest are the same as those in Embodiment 1, and are not repeated here.
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