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43results about How to "Facilitates insertion and extraction" patented technology

Sodium ion pre-embedded MoO3 nanobelt as well as preparation method and application of sodium ion pre-embedded MoO3 nanobelt

The invention relates to a sodium ion pre-embedded MoO3 nanobelt as well as a preparation method and application of the sodium ion pre-embedded MoO3 nanobelt. The sodium ion pre-embedded MoO3 nanobelt can be used as a positive electrode active material of a lithium ion battery. The preparation method comprises the following steps: (1) adding MoO3 nanobelt, PEG4000 and NaCl into deionized water, and stirring; (2) transferring the solution into a reaction kettle, carrying out hydrothermal reaction, taking out the solution, and cooling to the room temperature; and (3) after carrying out centrifugal separation on the obtained product, repeatedly washing the product with deionized water and ethanol, and finally drying the product in a drying box, so as to obtain the sodium ion pre-embedded MoO3 nanobelt. The preparation method has the beneficial effects that sodium ions are pre-embedded among layers, so that the substantial attenuation of the capacity in a primary cycle period is avoided, the electrochemical property of MoO3 is improved, the conductivity of the material is improved, furthermore, the cycling stability of the electrode material is effectively improved, and the electrode material can be used as a potential application material of the lithium ion battery, can meet the requirements of green chemistry and is beneficial to market promotion.
Owner:WUHAN UNIV OF TECH

Fibrous hollow hard carbon material capable of being used for sodium-ion battery negative electrode and preparation method thereof

The invention discloses a fibrous hollow hard carbon material. The amorphous fibrous hollow hard carbon material with the d002 value within the range of 0.36-0.42 nm and the ID/IG within the range of1.5-2.0 is prepared by taking a fibrous biomass material as a raw material through a direct pyrolysis method. A preparation method thereof comprises the following steps of 1) carrying out pretreatmenton the raw material; and 2) carrying out high-temperature pyrolysis. According to the fibrous hollow hard carbon material, as a negative electrode active material in a sodium-ion secondary battery, the specific capacity of the fibrous hollow hard carbon material is 150-350 mAh/g, the fibrous hollow hard carbon material under 2 C can keep the capacity of 60% or above at 0.1C, and the capacity retention ratio can be kept within the range of 90-100% after 100 weeks of circulation. The fibrous hollow hard carbon material and the preparation method thereof have the advantages that 1, through a stable micron-scale fiber structure, the cycle life is prolonged; 2, a natural tubular hollow structure is utilized, so that the wettability of an electrolyte is improved, the ion transmission distance is shortened, and the dynamics performance of the battery is improved; and 3, the preparation method is simple, and the processing cost for preparing the special morphology is lowered. The fibrous hollow hard carbon material is a very potential negative electrode material of the sodium-ion battery and can be applied to the fields of intelligent power grids, secondary clean energy power generation and other large-scale energy storage systems or power batteries.
Owner:SHANGHAI UNIV

Anthraquinone-2-copper carboxylate/graphene nano-composite as well as preparation and application thereof

The invention belongs to the field of lithium ion battery materials, and discloses an anthraquinone-2-copper carboxylate / graphene nano-composite as well as preparation and application thereof. The preparation method comprises the following steps: adding anthraquinone-2-carboxylic acid into a solvent, uniformly stirring and dissolving, dropwise adding a copper nitrate solution, and stirring for reflux reaction to obtain CuAQC; grinding the CuAQC, dispersing CuAQC and graphene into a solvent, and sequentially carrying out ball milling and ultrasonic treatment to obtain a uniform mixed dispersionliquid; and finally, carrying out forced air drying and coprecipitation to obtain the anthraquinone-2-copper carboxylate / graphene nano-composite. According to the method disclosed by the invention, the anthraquinone-2-carboxylic acid copper salt complex and the graphene are compounded by adopting simple ball milling and forced air drying coprecipitation, and the obtained compound has a characteristic structure of coating the rod-like anthraquinone-2-carboxylic acid copper salt complex with the graphene. The composite has excellent electrochemical performance as a lithium ion battery positiveelectrode material.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Bismuth phosphorus sulfur/carbon composite nanofiber negative electrode material for sodium-ion battery, preparation method of bismuth phosphorus sulfur/carbon composite nanofiber negative electrode material and sodium-ion battery

The invention relates to a bismuth phosphorus sulfur / carbon composite nanofiber negative electrode material for a sodium-ion battery, a preparation method of the bismuth phosphorus sulfur / carbon composite nanofiber negative electrode material and the sodium-ion battery, and belongs to the technical field of sodium-ion batteries. The preparation method of the bismuth phosphorus sulfur / carbon composite nanofiber negative electrode material for the sodium-ion battery comprises the following steps of mixing polyacrylonitrile, bismuth salt and an organic solvent to prepare a mixed solution, and then performing electrostatic spinning to prepare spinning fibers; preserving the heat of the prepared spinning fibers at 250-300 DEG C for 1-3 hours for pre-oxidation, and then preserving the heat in aninert atmosphere at 700-900 DEG C for 1-3 hours to prepare a precursor; and uniformly mixing the prepared precursor with phosphorus and sulfur, and carrying out calcining at 500-700 DEG C for 4-7 days to obtain the bismuth phosphorus sulfur / carbon composite nanofiber negative electrode material. The material prepared by the preparation method of the bismuth phosphorus sulfur / carbon composite nanofiber negative electrode material for the sodium-ion battery is of a one-dimensional nanowire structure and stable in structure in the charging and discharging process, and has relatively high specific discharge capacity and good cycling stability.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Preparation method of novel tin-based nanocrystalline alloy flexible film electrode

ActiveCN108574084AImprove bindingSolve the problem of easy falling off from the current collectorSecondary cellsElectrode collector coatingElectroplatingCopper salt
The invention discloses a novel tin-based nanocrystalline alloy flexible film electrode and a preparation method thereof, and belongs to the technical field of preparation of tin-based alloy film electrodes. The preparation method is characterized by comprising the following steps of: preparing electroplating solution main salt soluble copper salt and soluble tin salt and a electroplating complexing agent into an electroplating solution A; adding additives to the electroplating solution A to obtain an electroplating solution B; continuing to add the electroplating solution main salt soluble copper salt and the soluble tin salt to the electroplating solution B to obtain an electroplating solution C; conducting surface-treatment on a current collector for electroplating; placing the electroplating solution C and the surface-treated current collector in a plating bath for electroplating to obtain the tin-based nanocrystalline alloy flexible film electrode; and rinsing and drying the tin-based nanocrystalline alloy flexible film electrode to obtain a copper-tin nanocrystalline alloy flexible film electrode. The novel tin-based nanocrystalline alloy flexible film electrode and the preparation method thereof effectively solve a problem that a tin-based active material is easily detached from the current collector during a charging and discharging process, and a preparation process issimple, operation is convenient, cost is low, and production efficiency is high.
Owner:河南电池研究院有限公司 +1

Preparation and application of high-performance sodium-ion battery energy storage material based on regulation and control of hard carbon structure through ion catalysis

The invention relates to the field of sodium ion secondary batteries, and provides a method for regulating and controlling a hard carbon structure based on transition metal manganese, which is used for a sodium ion battery negative electrode material. Cheap and easily available biomass is used as a carbon source, and manganese is ensured to be uniformly dispersed in a precursor polymer through coordination of manganese ions (Mn < 2 + >) and one-dimensional cellulose nanofibers and a coordination effect; according to the present invention, the graphene sheets are introduced into the graphene sheets, such that the conversion between the SP3 carbon and the SP2 carbon is effectively catalyzed so as to freely rearrange the graphene sheets, such that the expanded nano-graphite and the carbon micro-pores are formed, and the controllable adjustment of the carbon interlayer spacing and the micro-pores is achieved by adjusting the concentration; and finally, 92.05% of ultrahigh first efficiency and excellent circulating performance are obtained (the capacity retention ratio of 200 cycles is 95.80% under the current density of 20mA g <-1 >). The problems of low sodium ion first efficiency and poor cycling stability are solved through ion catalysis regulation and control, the first efficiency can be improved to 90% or above, the performance is improved by 30% or above, the energy density of the battery is greatly improved, and the total battery with sodium vanadium phosphate as the positive electrode has excellent electrochemical performance, has a good industrialization prospect and is suitable for industrial production. The method is very suitable for large-scale energy storage systems.
Owner:温州大学碳中和技术创新研究院

Preparation method of nickel-cobalt-aluminum ternary positive electrode material precursor

The invention relates to a preparation method of a nickel-cobalt-aluminum ternary positive electrode material precursor. The preparation method comprises the following steps: respectively preparing a nickel-cobalt binary solution, a sodium metaaluminate solution, a liquid alkali solution and a complexing agent solution, wherein the complexing agent is one or more of ammonium sulfite, ammonium bisulfite, ammonium sulfate, ammonium bisulfate, ammonium sulfide, ammonium hydrosulfide, diamine pentasulfide and ammonium thiosulfate; adding the base solution into the reaction kettle, introducing nitrogen, and controlling the temperature and the stirring rotating speed; adding the nickel-cobalt binary solution, the sodium metaaluminate solution, the liquid caustic soda solution and the complexing agent solution into a reaction kettle in a parallel flow manner for reaction; when the particle D50 generated by the reaction reaches 3.0-18.0 [mu]m, stopping feeding; performing aging, washing and impurity removal, dehydration, drying, batch mixing, screening and iron removal on the obtained material, and performing packaging to obtain a finished product. In the process of synthesizing the nickel-cobalt-aluminum ternary precursor, the variety and the adding amount of the added complexing agent are adjusted, and the problems that pores in the precursor are few and are irregularly distributed are solved.
Owner:JINGMEN GEM NEW MATERIAL

MNO, a negative electrode material for sodium ion batteries x preparation method

A preparation method of a sodium ion battery negative electrode material MnOx comprises the steps of respectively preparing a manganese acetate solution and an ammonium persulfate solution from manganese acetate and ammonium persulfate; dispersing lauryl sodium sulfate in the manganese acetate solution to obtain a mixed solution; dropwise adding ammonium persulfate into the mixed solution, and continuously stirring until a system is uniform; moving the uniformly-dissolved system to an ultrasonic generation device for ultrasonic processing until a black precipitant is generated; and washing, filtering and drying the black precipitant, thereby obtaining the sodium ion battery negative electrode material MnOx. According to the preparation method, the acetate solution and the ammonium persulfate are used as raw materials, and the MnOx is prepared with ultrasound. Compared with the prior art, the preparation process is simple, the raw material is simple and available, the flower-shaped morphology comprising the MnOx is prepared with ultrasound, so that the active specific area of the negative electrode material is greatly improved, intercalation and de-intercalation of sodium ions are facilitated, and the capacity is improved.
Owner:SHAANXI UNIV OF SCI & TECH

Preparation method of porous sheet-shaped sodium ion battery negative electrode material

According to the preparation method, graphene oxide is taken as a template, organic or inorganic titanium is taken as a titanium source, under the action of an alkali catalyst, the titanium source and functional groups on the surface of the graphene oxide form chemical bonds, and the chemical bonds are deposited on the surface of the graphene oxide; the titanium dioxide / graphene oxide / titanium dioxide sandwich framework is obtained. After filtering, drying and calcining, the template is completely removed, and the amorphous titanium dioxide is converted into the mesoporous anatase-phase porous titanium dioxide nanosheet. The particle calcining device can effectively prevent the pore structure from being blocked due to insufficient gasification of the graphene oxide template in the calcining process, so that the prepared mesoporous material has relatively large pore volume and pore diameter, and the porous structure can improve the liquid retention capacity, is beneficial to intercalation and deintercalation of sodium ions, reduces the internal stress of the material, avoids de-molding and sodium separation of a pole piece, and improves the production efficiency. The material is suitable for high-voltage density design and high-rate charge and discharge, and can improve the energy density and rate capability of the battery cell.
Owner:WUHU ETC BATTERY LTD
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