High-sealing lithium ion battery cap and manufacturing method thereof
A lithium-ion battery, high-sealing technology, applied in the direction of battery cover/end cover, sealing material, battery pack components, etc., can solve problems such as liquid leakage, decreased sealing ability, and impact on battery output voltage
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[0024] Preferably, the preparation method of the allyltrimethoxysilane / N-(4-cyano-3-trifluoromethylphenyl)methacrylamide / isobornyl acrylate copolymer comprises: mixing allyl Trimethoxysilane, N-(4-cyano-3-trifluoromethylphenyl)methacrylamide, isobornyl acrylate, and initiator were added to a high-boiling solvent, in an inert gas atmosphere, 50-65 The reaction was stirred at ℃ for 3-5 hours, then precipitated in water, washed with ethanol for 2-6 times, and finally placed in a vacuum drying oven at 85-95 ℃ to dry to constant weight to obtain allyltrimethoxy Silane / N-(4-cyano-3-trifluoromethylphenyl)methacrylamide / isobornyl acrylate copolymer.
[0025] Preferably, the mass ratio of allyltrimethoxysilane, N-(4-cyano-3-trifluoromethylphenyl)methacrylamide, isobornyl acrylate, initiator and high boiling point solvent is (0.5-0.8):(3-5):(0.8-1.2):(0.05-0.07):(25-35).
[0026] Preferably, the initiator is azobisisobutyronitrile; the high boiling point solvent is dimethyl sulfoxide,...
Embodiment 1
[0037] Embodiment 1 provides a high-sealing lithium-ion battery cap, which is characterized in that it includes a top cover 1 and a base 2 arranged in sequence from top to bottom; the top cover 1 and the base 2 are connected by bolts 3; The base 2 is fixedly connected; an explosion-proof cavity 5 is formed between the top cover 1 and the base 2 ; the base 2 is machined with an annular explosion-proof notch 4 that ruptures under a specific pressure; A sealing ring 6 is provided; the sealing ring 6 and the outer wall of the explosion-proof cavity 5 are bonded by an adhesive; the sealing ring 6 is made of the following components by weight: 80 parts of nitrile rubber, olefin 15 parts of propyltrimethoxysilane / N-(4-cyano-3-trifluoromethylphenyl)methacrylamide / isobornyl acrylate copolymer, 2 parts of sodium polydithiodipropane sulfonate, five parts 0.5 part of phosphorus oxide, 0.1 part of polyphosphoric acid, 3 parts of vulcanizing agent, 2 parts of anti-aging agent, and 20 parts ...
Embodiment 2
[0045] Example 2 provides a high-sealing lithium-ion battery cap, which is basically the same as Example 1, except that the sealing ring 6 is made of the following components in parts by weight: nitrile rubber 85 parts, 17 parts of allyltrimethoxysilane / N-(4-cyano-3-trifluoromethylphenyl)methacrylamide / isobornyl acrylate copolymer, 2.3 parts of sodium polydithiodipropanesulfonate parts, 0.7 parts of phosphorus pentoxide, 0.2 parts of polyphosphoric acid, 4 parts of vulcanizing agent, 3 parts of anti-aging agent, and 23 parts of filler; the allyl trimethoxysilane, N-(4-cyano-3-trimethoxysilane) The mass ratio of fluoromethylphenyl) methacrylamide, isobornyl acrylate, initiator, and high boiling point solvent is 0.6:3.5:0.9:0.06:28.
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