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High-voltage low-loss ceramic capacitor dielectric and preparation method thereof

A ceramic capacitor and high-voltage technology, applied in the direction of fixed capacitor dielectric, capacitor, fixed capacitor, etc., can solve the problems of high dielectric loss, harm to human body and environment, small dielectric constant, etc., and achieve small dielectric loss, no pollution to the environment, and dielectric The effect of high electric constant

Pending Publication Date: 2022-06-07
汕头市瑞升电子有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the medium used to produce high-voltage ceramic capacitors usually contains a certain amount of bismuth, lead, and cadmium, which will cause harm to the human body and the environment, and are gradually eliminated
Although some ceramic capacitor dielectrics are bismuth-free, lead-free, and cadmium-free dielectric materials, they have small dielectric constants, high dielectric losses, and low withstand voltages, which are not conducive to the miniaturization of ceramic capacitors, and their pressure resistance is poor, which is also not conducive to expansion. Application range of ceramic capacitors and improvement of safety

Method used

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  • High-voltage low-loss ceramic capacitor dielectric and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] First, BaTiO was synthesized by the solid-phase method 3 , BaZrO 3 .

[0024] BaTiO 3 Prepared by the following process: Equipped with BaCO in a molar ratio of 1:1 3 and TiO 2 , then for BaCO 3 and TiO 2 Grind and mix well (BaCO 3 and TiO 2 The mixed material is ball-milled, and the weight ratio of the ball-milled mixed material, the ball used, and the water used is: mixed material: ball: water=1:5:1.5, and the ball milling process lasts 4 hours; after the ball milling is completed, the mixed material is dried and passed through an 80-mesh sieve), and then the BaCO 3 and TiO 2 The mixed material was put into an alumina crucible, and kept at 1260 ° C for 180 minutes to obtain BaTiO 3 .

[0025] BaZrO 3 Prepared by the following process: Equipped with BaCO in a molar ratio of 1:1 3 and ZrO 2 , then for BaCO 3 and ZrO 2 Grind and mix well (BaCO 3 and ZrO2 The mixed material is ball-milled, and the weight ratio of the ball-milled mixed material, the ball us...

Embodiment 2

[0038] First, BaTiO was synthesized by the solid-phase method 3 , BaZrO 3 .

[0039] BaTiO in this example 3 , BaZrO 3 The preparation process is the same as in Example 1.

[0040] Then, prepare the high voltage low loss ceramic capacitor dielectric as follows:

[0041] (1) Equipped with BaTiO in proportion 3 , BaZrO 3 , CeO 2 , ZnO, MnCO 3 , La 2 O 3 and W 2 O 3 ;

[0042] The weight percentages of various raw materials prepared in this example are as follows: BaTiO 3 89%, BaZrO 3 6%, CeO 2 0.6%, ZnO 1%, MnCO 3 0.4%, La 2 O 3 2%, W 2 O 3 1%;

[0043] (2) Put the BaTiO prepared in step (1) 3 , BaZrO 3 , CeO 2 , ZnO, MnCO 3 , La 2 O 3 and W 2 O 3 Mix and use a ball mill for ball milling, and then transfer the slurry obtained by ball milling to a sand mill for sand milling;

[0044] In this step (2), a planetary ball mill is used to ball mill the prepared raw materials, and the weight ratio of the ball milled raw materials, the balls used, and ...

Embodiment 3

[0052] First, BaTiO was synthesized by the solid-phase method 3 , BaZrO 3 .

[0053] BaTiO in this example 3 , BaZrO 3 The preparation process is the same as in Example 1.

[0054] Then, prepare the high voltage low loss ceramic capacitor dielectric as follows:

[0055] (1) Equipped with BaTiO in proportion 3 , BaZrO 3 , CeO 2 , ZnO, MnCO 3 , La 2 O 3 and W 2 O 3 ;

[0056] The weight percentages of various raw materials prepared in this example are as follows: BaTiO 3 88.2%, BaZrO 3 7%, CeO 2 0.5%, ZnO 1.2%, MnCO 3 0.5%, La 2 O 3 1.8%, W 2 O 3 0.8%;

[0057] (2) Put the BaTiO prepared in step (1) 3 , BaZrO 3 , CeO 2 , ZnO, MnCO 3 , La 2 O 3 and W 2 O 3 Mix and use a ball mill for ball milling, and then transfer the slurry obtained by ball milling to a sand mill for sand milling;

[0058] In this step (2), a planetary ball mill is used to ball mill the prepared raw materials. The weight ratio of the ball milled raw materials, the balls used, a...

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PUM

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Abstract

The invention relates to a high-voltage low-loss ceramic capacitor dielectric, which is characterized by being prepared from the following raw materials in percentage by weight: 35 to 7 percent of BaZrO, 0.5 to 0.7 percent of CeO2, 0.8 to 1.2 percent of ZnO, 0.3 to 0.5 percent of MnCO3, 1.5 to 2.5 percent of La2O3, 0.8 to 1.2 percent of W2O3 and the balance of BaTiO3. The invention also provides a preparation method of the high-voltage low-loss ceramic capacitor medium. Compared with the prior art, the ceramic capacitor dielectric has the following advantages that the dielectric constant of the ceramic capacitor dielectric is high (the dielectric constant is more than 3400), the withstand voltage is high (the direct-current withstand voltage can reach more than 7kV / mm, and the alternating-current withstand voltage can reach more than 5kV / mm), and the dielectric loss is small (the dielectric loss is less than 0.8%). The ceramic capacitor dielectric disclosed by the invention is suitable for manufacturing a ceramic capacitor meeting the Y5P characteristic requirement. Moreover, the ceramic capacitor dielectric does not contain bismuth, lead and cadmium, and has no pollution to the environment in the preparation and use processes.

Description

technical field [0001] The invention relates to the technical field of inorganic non-metallic materials, in particular to a high-voltage and low-loss ceramic capacitor medium and a preparation method of the high-voltage and low-loss ceramic capacitor medium. Background technique [0002] Color TV, computer, communication, aerospace, missile, navigation and other fields urgently need ceramic capacitors with high breakdown voltage, stable temperature characteristics, high reliability, miniaturization and large capacity. At present, the medium used to produce high-voltage ceramic capacitors usually contains a certain amount of bismuth, lead and cadmium, which will cause harm to the human body and the environment and are gradually eliminated. Although some ceramic capacitor dielectrics are bismuth-free, lead-free, and cadmium-free dielectric materials, they have small dielectric constant, high dielectric loss, and low withstand voltage, which are not conducive to the miniaturiza...

Claims

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Application Information

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IPC IPC(8): C04B35/468C04B35/622C04B35/626C04B41/88H01G4/12
CPCC04B35/468C04B35/622C04B35/62675C04B41/009C04B41/5116C04B41/88H01G4/1227C04B2235/3248C04B2235/3229C04B2235/3284C04B2235/3262C04B2235/3227C04B2235/3258C04B2235/5436C04B2235/602C04B2235/656C04B2235/6567
Inventor 彭道华陈映义牛继恩陈甲天姜学文
Owner 汕头市瑞升电子有限公司
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