Electrode and preparation method thereof
A technology of electrode and negative charge, which is applied in the field of electrode and its preparation, can solve the problems of low safety and reliability, and achieve the effects of improving safety and reliability, prolonging cycle life, and avoiding metal burrs
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Embodiment 1
[0042] This embodiment provides an electrode, including: a porous current collector, the material of which is MXene material; and an active material, the active material is supported in the pores of the porous current collector. In the above electrodes, the material of the current collector is MXene material with excellent electrical conductivity, which avoids the generation of metal burrs during the electrode preparation process, thereby reducing the risk of short circuit in the lithium battery and improving the safety and reliability of the lithium battery; at the same time, The current collector prepared by using the MXene material has a porous structure, and the porous current collector can relieve the volume expansion of the active material during the charging and discharging process of the lithium battery, which is beneficial to prolong the cycle life of the battery. In addition, the active material is loaded in the pores of the porous current collector, which improves th...
Embodiment 2
[0052] This embodiment provides an electrode, the preparation method of which includes the following steps:
[0053] Preparation of negatively charged MXene materials: the ceramic phase precursor MAX is sequentially etched and washed with water, and the etchant used in the etching step includes hydrofluoric acid; the chemical formula of the negatively charged MXene material is M n+1 X n T x , where M is a transition metal element, X is a carbon or nitrogen element, and T is a surface functional group OH - , O - and F - At least one of n=1, 2 or 3.
[0054] Preparation of the second suspension: add the active substance to absolute ethanol, ultrasonically treat it at 100W for 5 min, and then stir at 100 rpm for 3 min to fully infiltrate the active substance in the absolute ethanol; add 18 to the absolute ethanol Alkyltrimethylammonium chloride obtains a dispersion, and the mass ratio of the cationic surfactant to the active material in the dispersion is 0.005; the dispersio...
Embodiment 3
[0058] This embodiment provides an electrode, the preparation method of which includes the following steps:
[0059] Preparation of negatively charged MXene materials: the ceramic phase precursor MAX is sequentially etched and washed with water, and the etchant used in the etching step includes hydrofluoric acid; the chemical formula of the negatively charged MXene material is M n+1 X n T x , where M is a transition metal element, X is a carbon or nitrogen element, and T is a surface functional group OH - , O - and F - At least one of n=1, 2 or 3.
[0060] Preparation of the second suspension: add the active substance to absolute ethanol, ultrasonically treat it at 50W for 10 min, and then stir at 750 rpm for 1 min to fully infiltrate the active substance in absolute ethanol; add twelve Alkyl dimethyl benzyl ammonium chloride to obtain a dispersion, the mass ratio of cationic surfactant and active material in the dispersion is 0.0001; the dispersion is stirred at 180rpm f...
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Abstract
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