Hydrophobic association typed thickening agent containing fluorocarbon radicals its synthesizing method and usage
A technology of hydrophobic association and synthesis method, which is applied in the field of hydrophobic association type thickeners containing fluorocarbon groups, and can solve the problems of high price of fluorocarbon monomers and the like
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[0039] Raw materials: acrylic acid (AA), redistilled. The hydrocarbon hydrophobic monomer n-octadecacrylate (abbreviated as SA, BASF company), has not been processed. Fluorocarbon hydrophobic monomer FX14 and initiator AIBN were recrystallized from methanol. Diethylene glycol diacrylate (abbreviated as DGDA, Aldrich Company), redistilled. Diethylene glycol dimethacrylate (abbreviated as DGDMA, Aldrich Company), was not processed. N, N-methylenebisacrylamide (China Reagent Corporation), untreated. The used hydrophilic monomer of thickener synthesis, the structural formula of hydrophobic monomer and cross-linking agent are as follows:
[0040]
[0041]
[0042] R = H, CH 3
[0043] Diethylene glycol di(meth)acrylate N,N-methylene-bisacrylamide.
[0044] Synthesis of polymers: in a machine equipped with condenser, stirrer, N 2 In the three-necked bottle with the interface, add AA, a mixed solvent of ethyl acetate and cyclohexane, a hydrophobic monomer, a crosslinking...
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