Procesxs for producing continuous silicon carbide fibre by skin and core double-composition fibre method
A bi-component fiber and continuous silicon carbide technology, applied in fiber chemical characteristics, fiber treatment, textiles and papermaking, etc., can solve problems such as excessive fiber diameter, broken filaments, poor weaving performance, etc., and achieve excellent tensile properties , the effect of reducing the diameter
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Embodiment 1
[0031] 1. Mix 100g PAN (average molecular weight M w =42000) was completely dissolved in 400 g of analytically pure DMF to make a 20% solution as skin fluid. The skin fluid was kept at 80°C with external heating.
[0032] 2. Dissolve 2g of dispersant NP-10 in 180g of DMF, then add 200g of β-SiC powder (average particle size 0.1μm, maximum particle size 0.25μm) and 0.6g amorphous boron powder (average particle size 0.6μm, maximum particle size 1.0 μm). The resulting mixture was ball milled for 1 h, and then 120 g of 20% PAN in DMF (M of PAN w =20000), continue ball milling for 3h (ball milling temperature 100°C) to obtain a uniform core liquid. The core fluid was kept at 80°C by means of external heating.
[0033] 3. The skin liquid and core liquid respectively pass through an independent spinning metering pump and a candle-shaped filter, and then enter the skin-core composite spinneret assembly. The filtration accuracy of the skin liquid filter is 2 μm, the filtration acc...
Embodiment 2
[0041] Same as Example 1, the difference is that the fibrils are prepared by dry spinning, that is, the difference is in Steps 4 and 5 of Example 1. The fibers coming out of the composite spinning assembly enter the heating chamber to volatilize the solvent to form fibers, and the heating temperature is 165°C. Simultaneous stretching during the heating process, the stretching ratio is 1000%, and the stretched fiber is wound to obtain a fibril.
[0042] Continuous SiC fibers were obtained after sintering with an average diameter of 29 μm and a relative density of 95.8%. The average grain size is 0.12μm, and there is no abnormal grain growth. XRD analysis shows that the fiber is single-phase SiC, and the content of α-SiC is greater than 90%. Chemical elemental analysis indicated that the fibers were essentially stoichiometric SiC.
Embodiment 3
[0044] Same as Example 1, the difference is that the skin liquid polymer is viscose, the falling ball viscosity of the viscose is 120s, the NaOH content is 5.5%, and the maturity is 7ml 10%NH 4 Cl, the temperature of the skin liquid during spinning is 30°C.
[0045] Same as Example 1, the difference is that in item 2 of Example 1, 2g of dispersant JA-281 is dissolved in 180g of distilled water, and then 200g of β-SiC powder (average particle size 0.1 μm, maximum particle size 0.25 μm) is added ) and 0.6 g of amorphous boron powder (average particle size 0.6 μm, maximum particle size 1.0 μm). The obtained mixed fluid was ball-milled for 1 hour, then 120 g of the same viscose solution as the skin solution was added, and the ball-milling was continued for 3 hours (ball-milling temperature 80° C.) to obtain a uniform core solution.
[0046] With embodiment 1, difference is that in the 4th item of embodiment 1, the composition of coagulation liquid is 220g / L Na 2 SO 4 , 13g / LZnS...
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