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Chemical plating nickel conductive film on polymer thin film surface and method for preparing the same

A polymer film, chemical nickel plating technology, applied in the field of chemical plating, can solve problems such as difficulty in plating nickel, achieve the effects of lightweight shielding materials, reduce electromagnetic pollution, and reduce interference

Inactive Publication Date: 2004-11-17
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is quite difficult to plate nickel on non-metallic materials, especially for large-area thin-film polymer materials. Due to its unique surface inertia, it is difficult for nickel metal to adhere well on the surface of this type of thin film. Therefore, it has not been used before. see the report

Method used

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  • Chemical plating nickel conductive film on polymer thin film surface and method for preparing the same
  • Chemical plating nickel conductive film on polymer thin film surface and method for preparing the same
  • Chemical plating nickel conductive film on polymer thin film surface and method for preparing the same

Examples

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Effect test

Embodiment 1

[0028] Such as figure 1 The preparation method of the electroless nickel-plated conductive film on the surface of a polymer film shown, adopts 2 * 5cm 2 , a polyethylene terephthalate (PET) film with a thickness of 120m as the substrate, immersed in a 30g / L NaOH solution at 60°C for 30min, washed with water, immersed in a solution containing 10g / L stannous chloride, 0.5g / L Palladium chloride, in 20g / L 37% hydrochloric acid solution for 1min, washed with water, immersed in 20g / L hydrochloric acid solution for 1min, washed with water to complete pretreatment and pretreatment. Then immerse in the 80°C plating solution for 1min, the formulation of the plating solution is nickel chloride 25g / L, sodium hypophosphite 15g / L, sodium citrate 120g / L, ammonium chloride 40g / L, pH value 9. A nickel-plated PET conductive film is obtained, the thickness of the coating is about 1 μm, and the coating is dense under microscope observation.

Embodiment 2

[0030] Such as figure 1 The preparation method of the electroless nickel-plated conductive film on the surface of a polymer film shown, adopts 2 * 5cm 2 , a polyethylene terephthalate (PET) film with a thickness of 120 μm is the substrate, and the pretreatment and pretreatment are completed as in Example 1. Then immerse in a 45°C plating solution for 10 minutes. The difference is that the formulation of the plating solution is nickel sulfate 45g / L, sodium hypophosphite 30g / L, sodium pyrophosphate 50g / L, triethanolamine 15g / L, and pH 9.5. A nickel-plated PET conductive film was obtained, the thickness of the coating was about 5 μm, and the coating was dense under microscope observation.

Embodiment 3

[0032] Such as figure 1 The preparation method of the electroless nickel-plated conductive film on the surface of a polymer film shown, adopts 2 * 5cm 2 , a polyethylene terephthalate (PET) film with a thickness of 120 μm is the substrate, and the pretreatment and pretreatment are completed as in Example 1. Then immerse in the plating solution at 85°C for 1.5 minutes. The difference is that the formulation of the plating solution is nickel chloride 25g / L, sodium hypophosphite 15g / L, sodium glycolate 60g / L, lead nitrate 0.001g / L, twelve Sodium alkyl sulfate 0.02g / L, pH 5. A nickel-plated PET conductive film was obtained, the thickness of the coating was about 2 μm, and the coating was dense under microscope observation.

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Abstract

The invention discloses a chemical plating nickel conductive film on polymer thin film surface and method for preparing the same, wherein the conductive film is prepared through the steps of, (1) a pretreatment step of cleaning the surface of the polymer film, (2) carrying out activating and / or sensitization to the polymer film obtained in steps (1), water scrubbing for use later, throwing the polymer film obtained in step (2) into chemical plating liquid, water scrubbing for use later, (4) drying and heat treatment at 120-220 deg. C.

Description

technical field [0001] The invention relates to a conductive film obtained by attaching a layer of metal coating on the surface of a polymer film and a preparation process thereof, in particular to a conductive film obtained by plating nickel on the surface of a polymer and a preparation process thereof, and belongs to the technical field of chemical plating. Background technique [0002] With the widespread use of electronic and electrical products, while bringing convenience to people's lives, it also brings about the problem of electromagnetic pollution. These electromagnetic pollution often cause greater interference to other electronic equipment, and also affect people's health. . At the same time, in the military, the shielding of radar waves is an important part of military equipment stealth. Existing shielding materials often directly use metal sheets, metal mesh, etc., which have a problem of large specific weight, which limits the application in some areas that re...

Claims

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Application Information

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IPC IPC(8): C23C18/20C23C18/28C23C18/36
Inventor 张弢蒋正生章维益
Owner NANJING UNIV
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