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Preparation method of hard mutual dissolve alloy and its special device

An alloy and uniform mixing technology, applied in the field of preparation of immiscible alloys, can solve the problems of macrosegregation, recrystallization and grain growth, difficult methods, etc., achieve uniform phase distribution, small microstructure, and meet environmental protection requirements. Effect

Inactive Publication Date: 2005-05-25
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Refractory alloys are alloys that have significant differences in melting point and density, limited miscibility between components in the liquid state and immiscibility in the solid state, so the metals of this system will be stratified and separated in specific gravity in the liquid state during the smelting process , using conventional smelting methods, it is difficult to obtain ideal organizational structure
In recent decades, researchers have tried various non-equilibrium methods, such as: rapid solidification, mechanical alloying and powder metallurgy, but these methods have great difficulties
If the rapid solidification method is to obtain high-speed quenched powder or thin strip (thickness of tens of microns), it will quickly lose its physical-mechanical performance level, and the method of spray deposition is difficult to ensure sufficient cooling rate and good combination with the matrix
The method of mechanical alloying can obtain well-dispersed alloy powder, but the low-temperature recrystallization of the ultra-dispersed system hinders this approach to maintain the original dispersed system and obtain the corresponding physical-mechanical properties. In addition, when the powder metallurgy method forms bulk materials , there are also problems of recrystallization, grain growth and macrosegregation during sintering
It can be said that the existing technical methods have not been able to solve the problem of preparation of immiscible alloys well.

Method used

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  • Preparation method of hard mutual dissolve alloy and its special device
  • Preparation method of hard mutual dissolve alloy and its special device
  • Preparation method of hard mutual dissolve alloy and its special device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Such as figure 1 The special device for the preparation method of the immiscible alloy shown has a high-pressure gas source connected to the air inlet pipe, a heater 3, a powder feeder 2, and a supersonic nozzle 4, and the air inlet pipe 1 connected to the high-pressure air source passes through the powder feeder 2 respectively. The heater 3 is connected with the supersonic nozzle 4, the part of the inlet pipe 1 placed in the heater 3 is a spiral structure, the substrate 5 is opposite to the outlet of the supersonic nozzle, and the high-pressure gas enters the powder feeder 2 and the Heater 3, part of the gas carrying powder entering the powder feeder 2 is mixed with the preheated gas passing through the heater 3 at the entrance of the supersonic nozzle to form a gas-solid two-phase flow, and the gas-solid two-phase flow in the supersonic nozzle After the acceleration process, it reaches the supersonic state. The metal particles in the two-phase flow have high kinetic ...

Embodiment 2

[0034] The difference from Example 1 is:

[0035] The immiscible alloy prepared in this example is an electrical material, Fe is used as a matrix, and chromium powder is used as an alloying element. The particle size is ~50 microns. As a result, an electrical material of a hard miscible alloy was obtained. The Fe and Cr phases were observed by scanning electron microscopy, and the two phases were evenly distributed and the structure was compact.

Embodiment 3

[0037] The difference from Example 1 is:

[0038]The immiscible alloy prepared in this embodiment is a high damping material Fe-Cu alloy, a mixed powder of pure iron and pure copper, and the base material is ceramics. The parameters of the spraying process are as follows: spraying distance 5mm, gas pressure 2.5MPa, gas temperature 600°C, air flow rate 30g / s, powder particle size ~ 5 microns. As a result, the Fe-Cu alloy and the coating were obtained. Observation by scanning electron microscope showed that the two phases of iron and copper were evenly distributed without obvious segregation phenomenon.

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Abstract

A process for preparing the alloy of the components difficult to dissolve mutually by pneumatic spray technique includes mixing the superfine particles of its components, mixing the granular mixture with the compressed air in the supersonic nozzle to obtain dual-phase airflow, and spraying it onto surface of workpiece for depositing the particles on the plastically deformed surface of workpiece to form an alloy layer. Its apparatus is composed of high-pressure air source, heater, power feeder, and supersonic nozzle.

Description

technical field [0001] The invention relates to the preparation technology of the incompatible alloy, in particular to a preparation method of the incompatible alloy and a special device thereof. Background technique [0002] Refractory alloys are alloys that have significant differences in melting point and density, limited miscibility between components in the liquid state and immiscibility in the solid state, so the metals of this system will be stratified and separated in specific gravity in the liquid state during the smelting process , using conventional smelting methods, it is difficult to obtain the ideal structure. In recent decades, researchers have tried various non-equilibrium methods, such as: rapid solidification, mechanical alloying and powder metallurgy, but these methods have great difficulties. The rapid solidification method needs to obtain high-speed quenching powder or thin strip (thickness of tens of microns), which will quickly lose its physical-mecha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F3/115C22C1/04
Inventor 熊天英吴杰金花子吴敏杰吕家舜李铁藩梁慎国
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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