Cold tolerant, shock resistant polyamide compoiste material in high intensity and its producing process
A technology of high-strength polyamide and composite materials, applied in the field of cold-resistant, impact-resistant and high-strength polyamide composite materials and their manufacturing, can solve the problems of cracking, impact and rigidity decline, and rigidity phase decline in products, and achieve Enhanced bond strength, improved toughness, and reduced manufacturing costs
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Embodiment 1
[0026] Antioxidant namely tetrakis [β-(3,5-di-tert-butyl-4'-hydroxyphenyl) propionic acid] pentaerythritol ester and compound coupling agent namely aminopropyltriethoxysilane and isopropyl The organic solution of triisostearoyl titanate dissolved in alcohol (the concentration is 10%, and the consumption is SiO 2 5% by weight) treated SiO 2 Composite material 3kg, add 10kg water, stir and disperse the water dispersion liquid obtained. Take 10kgε-caprolactam and add 1.6kg of water to heat up to 80°C to melt, and then SiO 2 The aqueous dispersion of the solution is put into the melted caprolactam melt to form SiO 2 - caprolactam monomer mother liquor, SiO 2 - Add caprolactam monomer mother liquor to 90kg caprolactam melt, stir evenly, press into the polymerization kettle and heat up to 210°C, heat preservation and pressure for 2 hours, depressurize for 4 hours, raise the temperature to 270°C and vacuum for 1 hour, pressurize (Nitrogen-filled) discharge, injection tape cutting...
Embodiment 2-6
[0029] Operation method and process control are the same as embodiment 1, change SiO 2 The amount of the toughening agent EPDM is unchanged, and the specific data are shown in Table 1.
[0030] The cold-resistant and impact-resistant high-strength polyamide composite material is injection-molded under the following conditions, and the test sample is prepared. The following test method is used for the test, and its technical indicators will reach those shown in Table 1.
[0031] Injection conditions:
[0032] Cylinder temperature: front section 240~285℃
[0033] Middle section 240~285℃
[0034] Back stage 240~275℃
[0035] Injection pressure: 6 ~ 9.0Mpa
[0036] Holding time ≥ 6 seconds
[0037] Cooling time ≥ 30 seconds
[0038] Test Methods:
[0039] Notched Impact Strength: GB 1043-1993 Hard Plastic Charpy Impact Test Method
[0040] Compressive Strength: GB 1041-1992 Test Method for Compressive Properties of Plastics...
example 7-9
[0045] Operation method and process control are the same as embodiment 1, SiO 2 The amount of the toughening agent EPDM is unchanged, and the amount of the toughening agent EPDM is changed. The specific data are shown in Table 2
[0046] Reality
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