Preparation method of silicon and silicon germanium quantum point array
A technology of quantum dots and silicon germanium, which is applied in the field of nanomaterial preparation and application, can solve the problems of low periodicity and order of quantum dots, complex equipment, high production costs, etc., and achieve good application prospects and simple conditions.
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Embodiment 1
[0021] According to the surface area of the substrate, drop the solution of polystyrene beads with a concentration of 0.01% onto the surface of the cleaned silicon wafer, dry it and keep it warm at 90°C for 6 minutes. Then on the surface of the silicon wafer with the PS ball array arranged, a 25nm (± 3nm) thick Ag film is evaporated with a vacuum evaporation device, and then the sample deposited with the silver film is immersed in a closed container containing a mixed solution of hydrofluoric acid and ferric nitrate After 10 minutes of treatment in a kettle (the concentrations of hydrofluoric acid and ferric nitrate are 1.15 mol / L and 0.0675 mol / L, respectively), silicon quantum dot arrays arranged in a large area can be obtained in an orderly manner.
Embodiment 2
[0023] According to the surface area of the substrate, drop the solution of polystyrene beads with a concentration of 0.01% onto the surface of the cleaned silicon wafer, dry it and keep it warm at 90°C for 6 minutes. Then on the surface of the silicon wafer with the PS ball array arranged, a 50nm (± 5nm) thick Ag film is evaporated with a vacuum evaporation device, and then the sample deposited with the silver film is immersed in a closed container containing a mixed solution of hydrofluoric acid and ferric nitrate After 6 minutes of treatment in the kettle (the concentrations of hydrofluoric acid and ferric nitrate are 2.3 mol / L and 0.0675 mol / L, respectively), silicon quantum dot arrays arranged in a large area can be obtained in an orderly manner.
Embodiment 3
[0025]According to the surface area of the substrate, drop the solution of polystyrene beads with a concentration of 0.1% onto the surface of the cleaned silicon wafer, dry it and keep it warm at 100°C for 5 minutes. Then on the surface of the silicon wafer with the PS ball array arranged, a 100nm (± 10nm) thick Ag film is evaporated with a vacuum evaporation device, and then the sample deposited with the silver film is immersed in a closed container containing a mixed solution of hydrofluoric acid and ferric nitrate After 3 minutes of treatment in a kettle (the concentrations of hydrofluoric acid and ferric nitrate are 4.6 mol / L and 0.135 mol / L, respectively), silicon quantum dot arrays arranged in a large area can be obtained in an orderly manner.
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