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Apparatus and method for processing a substrate

a substrate surface and apparatus technology, applied in the direction of non-linear optics, cleaning using liquids, instruments, etc., can solve the problems of inability to produce active oxygen in the vicinity of the substrate surface, and inability to decompose ultraviolet light rays. , to achieve the effect of reducing the capacity of activating organic substances on the substrate surface, reducing the capacity of substrate surface activation, and reducing the capacity of substrate surfa

Inactive Publication Date: 2004-03-11
HITACHI ELECTRONICS ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012] It is another object of the present invention to provide a method and an apparatus for producing an oxidative active member and a reducing active member by irradiating substrate surfaces with ultraviolet light rays in a mixed atmosphere of an inert gas and, thereby ensuring reactions with decomposition products of organic substances to proceed efficiently in an assured manner.
[0018] According to a more specific form of the present invention, the method for treating substrate surfaces comprises the steps of: horizontally transferring a substrate into a mixed atmosphere of an inert gas and water vapor under irradiation of ultraviolet light from a dielectric barrier discharge lamp, thereby decomposing organic substances deposited on a surface of the substrate and at the same time splitting water vapor into a reducing active member [H.] and an oxidative active member [.OH]; dry-washing and minimizing contact angle of a surface of the substrate by subjecting the reducing and oxidative active members [H.] and [.OH] to reactions with decomposition products of the organic substances; wet-washing the substrate by supplying a wash liquid thereto; and drying the substrate.

Problems solved by technology

Therefore, of various organic compounds which have deposited on substrate surfaces, the ultraviolet light may not be able to decompose those compounds which have chemical bonds of strong energy like double bonds.
However, since ultraviolet light is consumed for cracking oxygen in the air, an air layer between the discharge lamp and a substrate is increased in thickness to cause an exponential attenuation to the amount of ultraviolet light rays which can reach a substrate surface.
Consequently, there occur conspicuous degradations in the capacities of activating organic substances on substrate surfaces and producing active oxygen in the vicinity of substrate surfaces, that is, in the capacity of removing contaminant organic substances by ultraviolet light.
Therefore, depending upon the kinds of organic substances which have deposited on substrate surfaces, it is often found difficult to remove deposited organic contaminants from substrate surfaces simply by oxidative reactions.

Method used

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  • Apparatus and method for processing a substrate

Examples

Experimental program
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Effect test

first embodiment

[0046] In the case of the first embodiment described above, the lamp house is connected to the lower chamber. However, for the sake of simplification in construction, it may be arranged, for example, as shown in FIG. 5. In the embodiment of FIG. 5, a lamp house 112 is arranged to completely cover or enshroud discharge lamps 1. In this case, on the side which faces a substrate 10, the lamp house 112 is provided is with a window 112a which is fitted with a pane of glass which is highly transmissive of ultraviolet light, such as synthetic quartz glass or the like. With the lamp house 112 of this construction, the inert gas is sealed in the lamp house 112 and not allowed to escape to the outside. Accordingly, in this case, there is no necessity for constantly feeding an inert gas to the lamp house 112 as long as a predetermined amount of inert gas is sealed therein.

[0047] Shown in FIG. 6 are results of wettability improving experiments using the apparatus of FIG. 5 and changing the natu...

fourth embodiment

[0057] Illustrated in FIG. 8 is the present invention. In this embodiment, a boundary is provided across an opening at the lower end of the lamp house 212 which is projected into the chamber 214, drawing a border between a dry nitrogen gas atmosphere in the lamp house 212 and a moistened inert gas atmosphere in the chamber 214. The boundary is formed by the use of a partition plate 202 of a predetermined thickness. The partition plate 202 is constituted, for example, by a plate of honeycomb or grid-like structure which contains a multitude of fine passages across its thickness and in its entire surface areas. Further, the partition plate is coated with a reflecting film, including inner surfaces of fine passages.

[0058] In this case, the dry nitrogen gas in the lamp house 212 is maintained at a pressure level slightly higher than a gas pressure within the chamber 214. Therefore, a border is defined between the dry nitrogen gas atmosphere in the lamp house 212 and the moistened inert ...

fifth embodiment

[0059] Furthermore, in place of the above-described partition plate, a window pane 202 of an ultraviolet light transmitting material such as quartz glass or the like may be fitted in the lower opening of the lamp house as in the invention shown in FIG. 9. In this case, although dry nitrogen gas is supplied to the lamp house 212 through a nitrogen gas feed pipe 213, there is no necessity for keeping the supply of dry nitrogen gas because the lamp house 212 is substantially in a closed state.

[0060] Any way, in the foregoing second to fifth embodiments, pressure chambers may be provided on the outer side of the entrance and exit openings 214a and 214b of the chamber 214 in the same manner as in the first embodiment. The exhaust pipe 218 is not required in case such pressure chambers are maintained at a negative pressure level.

[0061] Shown in FIG. 10 is a sixth embodiment of the present invention. In this embodiment, the processing apparatus is arranged to generate moistened inert gas w...

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Abstract

A lamp house is located face to face with a substrate which is transferred by a conveyer means. A dielectric barrier discharge lamp is provided in the lamp house to irradiate the substrate with ultraviolet light, while a moistened inert gas, consisting of an inert gas and water vapor, is supplied to a space between the substrate and the dielectric barrier discharge lamp from a moistened inert gas generating means. Under irradiation of ultraviolet light from the dielectric barrier discharge lamp, water vapor in the moistened inert gas is split into a reducing active member [H.] and an oxidative active member [.OH].

Description

[0001] 1. Field of the Art[0002] This invention relates to a method and an apparatus for treating surfaces of substrates such as of LCD panels, semiconductor wafers, magnetic storage disks and optical storage disks which are formed of glass, semiconductor, synthetic resin, ceramics, metals or a composite material of these materials, and more particularly to a method and an apparatus for treating substrate surfaces by irradiation of ultraviolet light in a washing or etching stage of a fabrication process.[0003] 2. Prior Art[0004] For instance, a circuit pattern including transparent electrodes is formed on a TFT substrate which constitutes a transparent substrate of an LCD panel by the use of a film-forming means. In suc a substrate fabrication process, surfaces of substrates are processed by washing and etching treatments. In a processing of this sort, it has been the general practice to employ a wet process in which treating liquids are applied or injected on substrate surfaces. Ho...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B08B7/00C03C23/00G11B23/50H01L21/00
CPCB08B7/00B08B7/0057C03C23/0075Y10S134/902G11B23/505H01L21/67028H01L21/67115G02F2001/1316G02F1/1316
Inventor KINOSHITA, KAZUTOGOMMORI, KAZUHIKOWADA, KENYA
Owner HITACHI ELECTRONICS ENG CO LTD
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