Filament Bundle Type Nano Fiber and Manufacturing Method Thereof
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preparation example 1
First Preparation of Spinning Solution
[0055]A polymer copolymer, which consists of 30 mol % of polyamide-based polymer with an average molecular weight and 70 mol % of polyimide-based polymer with an average molecular weight, was added to a N-methyl-2-pyrrolidine solvent, and sufficiently dissolved at room temperature for 20-30 min using a ultrasonic device. In this regard, a spinning solution contains 25 wt % of polyamide-polyimide copolymer with a number average molecular weight of 1000 based on the solvent.
preparation example 2
Second Preparation of Spinning Solution
[0056]Polyethylene terephthalate having an intrinsic viscosity of 0.64 was mixed with a polyester copolymer, which contains 30 mol % of isophthalic acid and 15 mol % of diethylene glycol and which has an intrinsic viscosity of 0.60, in a weight ratio of 75:25, and then dissolved in a mixed solvent (50:50) of trifluoroacetic acid and methylene glycol to produce a spinning solution containing 15 wt % of solids.
preparation example 3
Preparation of Spinning Melt
[0057]A mixed composition, which consists of 30 mol % of polyamide-based polymer with an average molecular weight and 70 mol % of polyimide-based polymer with an average molecular weight, was melted in an electric furnace at 350° C. to produce a spinning melt.
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