Methods To Detect Organic Contaminants In Pulp and Fiber

a technology of organic contaminants and pulp, applied in the field of pulp and fiber, can solve the problems of wet end breakage, high dirt count, wet end breakage,

Inactive Publication Date: 2009-04-02
BUCKMAN LAB INT INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0025]The present invention further relates to organic contaminants in pulp and fiber with at least one hydrophobic dye that stains organic contaminants present in the pulp and fiber without staining the pulp and fiber.

Problems solved by technology

Once caustic agents are used, some yellowing of the fibers occurs which results in a need to bleach the fibers.
Recycled paper fibers contain many components that when repulped in recycle fiber plants become stickies.
Stickies deposit on machine surfaces, fabrics, wires, felts, and rolls and lead to problems such as wet end breaks, pressroom breaks, dryer section breaks, holes, sheet defects, and high dirt counts.
These deposits and associated problems lead to a significant amount of downtime yearly.
Floating removes intermediate size stickies (50-300 microns), which are troublesome, because they're small enough to be accepted by screening and cleaning but too large to be removed by washing.
Measuring and controlling stickies in a recycled paper manufacturing process has always been a challenge.
Variations in recycled paper quality and the trend to increase the amount of waste paper incorporated into each ton of pulp produced are each contributing factors that make this challenge even more difficult to address.
These variations make predicting the amount of stickies that are entering a mill's system troublesome.
However, additional stresses on the screens and cleaner banks such as high furnish consistency, improper in-screen dilution, improper reject rates, and differential pressure control problems will facilitate the acceptance of formed macrostickies (Gallagher, 1997).
These materials remain tacky in the papermaking process, leading to the “stickies” label (Doshi, 1997).
Once the materials are incorporated into the fumish, they are difficult to remove, since they are deformable in nature and are often close to the specific gravity of water.
These physical characteristics present a different screening and cleaning challenge as these contaminants slip through screens and cleaners (Scholz, 1997) that are designed to allow water and fiber to be accepted.
Even if the cleaning and screening systems do perform properly and do remove most of the macrostickies, the remaining microstickies may cause problems.
The cost of stickies deposition is a significant one.
Preventing the agglomeration of microstickies is also an issue in addition to the microstickies problem.
However, most, if not all, of these tests are time-consuming, inaccurate, provide false-positive readings, are difficult to use in the mill, are not based on real time testing, and the like.

Method used

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  • Methods To Detect Organic Contaminants In Pulp and Fiber
  • Methods To Detect Organic Contaminants In Pulp and Fiber
  • Methods To Detect Organic Contaminants In Pulp and Fiber

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0062]A fresh 1% w / w solution of a D4 stain (Dupont #4 dye, from E.I. DuPont de Nemours & Co.) in tap water was prepared. To ensure the complete dissolution of the stain, the solution was heated to almost boiling. 0.1 g (0.1 ml) of stock sample was placed into a test tube. 5 mls of D4 solution was added and the tube was put in hot, not boiling, water for 20 minutes. The contents of the test tube were poured onto a watch glass. A very small quantity of fibre and liquor was transferred onto a microscope slide. The slide was examined at ×40, ×100, ×400 magnification.

[0063]The sample appeared as a collection of red and green fibres with coloured and colourless particles distributed around the fibres. Stickies appear as amorphous, slightly rounded not angular particles. They can be either in the water phase or attached to a fibre.

Color ReactionSUBSTANCECOLOR WITH D4 STAINHardwood FibreRedSoftwood FibreGreenSBRGolden / YellowPVADark Red / MaroonEVABright YellowPolyacrylateRed / Pink

[0064]As can...

example 2

[0065]A procedure for enumerating microstickies was experimentally studied in a field application (i.e., an actual paper producing facility). This paper producing facility uses recovered post consumer papers as a raw material to produce a commercial paper product. In the past, this particular location has experienced operational problems due to stickies deposition on the paper machine equipment. These operational “outbreaks” (i.e. off-quality sheet due to holes, defects / contamination, PM breaks, reduced production, downtime, etc.) are costly. Moreover, these stickies-related outbreaks were not predicted in the past.

[0066]Table 1 below lists the excitation and emission wavelengths for the fluorescent tag / microstickies compound of these experiments. The data was generated using a Perkin-Elmer 150 Fluorescence Spectrophotometer with a Xenon Power Supply.

TABLE 1Type of AdhesiveExcitation PeakEmission PeakCommentsFluorescent TAG466536(1% Solvent / TagMixture)Styrene Butadiene464532Polyviny...

example 3

[0098]Experimental evaluations were conducted on BULAB® 5453 bentonite (from Buckman Laboratories, Memphis Term.) to evaluate its performance in reducing the amount of suspend and colloidal material in the Krofta accepts, and specifically focusing on microstickies that were monitored and counted as part of the evaluation. The evaluation was run over a time period of four weeks, in which the BLLAB® 5453 Bentonite was substituted in production runs for an existing inorganic program used in the paper production facility, which was considered the “baseline” for purposes of these studies. The baseline material had been used and monitored in a prior four week production period. Microstickies were detected and enumerated in the manner described below.

[0099]The test results indicated that there was a 43% reduction in online turbidities when comparing the daily average turbidities for the baseline month when compared to the month long bentonite evaluation. In also conducting Krofta efficienc...

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Abstract

A method to detect organic contaminants in pulp and fiber is described which uses hydrophobic dyes, such as fluorescent dyes.

Description

[0001]This application claims the benefit under 35 U.S.C. §119(e) of prior U.S. Provisional Patent Application No. 60 / 930,414, filed May 16, 2007, which is incorporated in its entirety by reference herein.BACKGROUND OF THE INVENTION[0002]The present invention relates to pulp and fiber and more particularly relates to methods to detect and / or quantify organic contaminants, such as microstickies, present in pulp and fiber.[0003]Conventional recycling of old paper products such as old new print, old corrugated containers, and mixed office waste is an important aspect of papermills today due to environmental demands that many paper containing products have a portion of recycled fibers contained within the paper product. Thus, papermills are in a situation where the recycling of paper products is a necessity. However, the recycling of the paper products generally requires additional processing steps in order to lead to fibers which can be useable in paper products.[0004]Conventional recy...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): D21H21/30
CPCD21C5/02G01N33/343D21C9/08Y02W30/64
Inventor PERRY, CHRISTOPHER D.JOHNS, STUARTCOOPER, ROBERT A.
Owner BUCKMAN LAB INT INC
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