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Hydroprocessing light cycle oil in liquid-full reactors

a technology of hydroprocessing and light cycle oil, which is applied in the treatment of hydrocarbon oils, hydrocarbon oil treatment, and treatment with plural serial cracking stages. it can solve the problems of large quantities of hydrogen, large naphtha and lighter hydrocarbons, and the inability to directly blend oil into today's diesel fuels. achieve the effect of high yield and/or quality

Active Publication Date: 2014-05-08
REFINING TECH SOLUTIONS LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The process described in this patent makes it possible to create a high-quality diesel fuel from LCO. This process results in a high yield of diesel, without losing too much of the useful hydrocarbon to lower value naphtha. This diesel fuel is ideal for use in applications that require specific physical properties, such as transportation fuels.

Problems solved by technology

However, such oils cannot be directly blended into today's diesel fuels because of their high sulfur content, high nitrogen content, high aromatics content (particularly high polyaromatics), high density, and low cetane value.
However, high nitrogen content can poison a zeolitic hydrocracking catalyst, and hydrocracking conditions which are too severe can cause the formation of significant amounts of naphtha and lighter hydrocarbons which are considered lower value products.
These units are expensive, require large quantities of hydrogen, much of which must be recycled through expensive hydrogen compressors, and result in significant coke formation on the catalyst surface and catalyst deactivation.

Method used

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  • Hydroprocessing light cycle oil in liquid-full reactors

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0064]This example demonstrated the first stage of the present invention. Reactors 1-3 were equipped with a hydrotreating catalyst to accomplish hydrodenitrogenation (HDN), hydrodesulfurization (HDS) and hydrodearomatization (HDA). The catalyst, KF-860 (NiMo on γ-Al2O3 support) from Albemarle Corp., Baton Rouge, La., was in the form of extrudates of a quadralobe about 1.3 mm diameter and 10 mm long. About 22 mL, 62 mL, and 96 mL of catalyst (180 mL total) were loaded into the first, second, and third reactor, respectively. Reactor 1 was packed with layers of 30 mL (bottom) and 30 mL (top) of glass beads. Reactor 2 was packed with a layer of 10 mL (bottom) and 11 mL (top) of glass beads. Reactor 3 was packed with a layer of 7 mL (bottom) and 3 mL (top) of glass beads.

[0065]Fresh LCO feed was pumped to Reactor 1 using a reciprocating pump at a flow rate ranging from 1 mL / minute to 3 mL / minute. Total hydrogen fed to the reactors ranged between 310 N l / l to 350 N l / l (1730 scf / bbl-2180 ...

example 2

[0067]Demonstrated in this example is the second stage of the present invention wherein the stage 1 product from Example 1 is used as the feed.

[0068]Reactors 4 and 5 were filled with hydrocracking catalyst, KC2610 (NiW on a zeolite support) from Albemarle in the form of cylindrical extrudates about 1.5 mm in diameter and 10 mm long. Each reactor was filled with 60 mL of catalyst and contained a layer of 12 mL (bottom) and 24 mL (top) of glass beads. Hydrogen was injected only into the feed to reactor 4; effluent from reactor 4 flowed directly into reactor 5. The effluent from reactor 5 was split into a recycle stream and a product effluent. The liquid recycle stream flowed through a piston metering pump, to join the feed at the inlet of reactor 4.

[0069]The feed (stage 1 product from Example 1) was pumped to reactor 4 using a reciprocating pump at a flow rate of 1.5 mL / min for a LHSV of 0.75 hr−1. Hydrogen was fed at 125 N l / l (710 scf / bbl). Pressure was 13.8 MPa (138 bar). The recyc...

example 3

[0070]Demonstrated in this example is the second stage of the present invention wherein the stage 1 product from Example 1 is fractionated prior to use as the feed. The reaction conditions are otherwise similar to Example 2

[0071]A portion of the stage 1 product from example 1 was charged into 3 L batch distillation column. The column contained 5 trays, a total condenser, and reflux splitter. The column was operated under a vacuum. An electric heating mantle was used to heat the column. The column operated at a 2:1 reflux ratio. The distillation was continued until the distillate had an average density of 850 kg / m3. The bottoms from the batch distillation was used as the feed for the second stage of Example 3.

[0072]The feed (bottoms from the distillation) was pumped to reactor 4 using a reciprocating pump at a flow rate of 1.5 mL / min for a LHSV of 0.75 hr−1. Hydrogen was fed at 125 N l / l (710 scf / bbl). Pressure was 13.8 MPa (138 bar). The recycle ratio was 6. Runs were again made at ...

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Abstract

A process for the hydroprocessing of a low value light cycle oil (LCO) hydrocarbon feed to provide a high-value diesel-range product. The process comprises a hydrotreatment stage followed by a hydrocracking stage, each of which is conducted under liquid-full reaction conditions wherein substantially all the hydrogen supplied to the hydrotreating and hydrocracking reactions is dissolved in the liquid-phase hydrocarbon feed. Ammonia and other gases formed during hydrotreatment are removed in a separation step prior to hydrocracking. The LCO feed is advantageously converted to diesel in high yield with little loss of hydrocarbon to naphtha.

Description

FIELD OF THE INVENTION[0001]The present invention pertains to a process for hydroprocessing a hydrocarbon feed and more particularly to a process for hydroprocessing light cycle oil hydrocarbon feed in liquid-full reactors to selectively convert the light cycle oil to a diesel-range product.BACKGROUND OF THE INVENTION[0002]Global demand for diesel has risen quickly with increased growth of transportation fuels. At the same time, regulations on the properties of the transportation diesel have become more rigorous in order to mitigate environmental impact. European standards, for example, call for a density less than 860 kilograms per cubic meter (kg / m3), a polycyclic aromatics content of less than 11 wt. % and a sulfur content of less than 10 part per million by weight (wppm) which is often referred to as ultra-low-sulfur-diesel, or ULSD. Future standards call for a density less than 845 kg / m3.[0003]There is a need for a broader range of hydrocarbon feeds to use as feedstocks for pro...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10G65/12
CPCC10G65/12C10G65/043C10G65/02C10G65/04C10G2300/307C10G2300/308
Inventor DINDI, HASANPULLEY, ALAN HOWARDKUPERAVAGE, JR., VINCENT ADAMTA, THANH GIA
Owner REFINING TECH SOLUTIONS LLC
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