Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Functionalized cellulose fibers for dewatering and energy efficiency improvements

a technology of cellulose fibers and functional fibers, applied in the field of functionalization of cellulose fibers, can solve the problems of large proportion of energy required for paper drying, large amount of energy consumed in papermaking process, so as to improve the rate at which fibers slide past each other, influence the dewatering properties of papermaking furnishing and positively, the effect of reducing the friction between the fibers

Inactive Publication Date: 2016-02-04
AUBURN UNIV
View PDF2 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patent text discusses the cost and environmental impact of removing water from the paper making process. The text explains that by removing as much water as possible during the first two stages of the process, the load on the steam heated dryer is reduced and papermaking economics are improved. The text also mentions that improving water drainage even slightly can have a significant impact on both financial and environmental performance. Additionally, the patent text suggests that improving freeness in the paper making process or nano / micro-fibrillated cellulose production process can lead to improved efficiency and performance.

Problems solved by technology

The process of making paper requires a large amount of energy, and nearly 80% of the required energy is consumed by paper drying.
In particular, the sizeable proportion of energy necessary for paper drying is due to the process of drying by vaporization.
The ease with which water is released from furnish during the papermaking process affects both the production rate and energy consumption.
The entire dewatering process for sheet formation is a very complex sequence utilizing various physical phenomena.
All of these process steps require a substantial amount of energy and demand very high capital equipment investments and maintenance costs.
Although several R / D additives have been investigated for their effects on the water removal on the forming process, doing so often causes one or more disadvantages at a subsequent step in the paper making process.
Although positive effects of various R / D additives on water drainage gravity-filtration of fiber suspensions have been suggested, parallel tests carried out with application of vacuum gave contradictory results.
However, excessive treatment of fibers with enzymes have been found to increase the fines content of furnish, thus reducing the dewatering ability.
However, similar tests with application of vacuum have been reported to give different results.
In addition, using CATPAM can improve dewatering in the wire, but lesser water removal at the press section due to the formation of persistent fiber flocs by the chemical treatments.
Once most of the water has been removed by the application vacuum, the same void spaces allow air to rush ineffectively through the wet web, failing to maintain a pressure differential across the thickness of the sheet.
In addition, sheets with highly flocculated fibers were found to require longer application heat in the drying section to remove the remaining water in the sheet by evaporation.
Second, the methods improve the suspension flow of the cellulosic fiber composition during the paper making process, leading to a lower amount of cellulosic fiber flocculation during the process.
Third, the methods improve the bulk of the resultant paper made during the process.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Functionalized cellulose fibers for dewatering and energy efficiency improvements
  • Functionalized cellulose fibers for dewatering and energy efficiency improvements
  • Functionalized cellulose fibers for dewatering and energy efficiency improvements

Examples

Experimental program
Comparison scheme
Effect test

example 2

Functionalization of Cellulose Fibers

[0165]Air dried fiber mats comprising cellulose fibers can be subjected to a process in which all or part of the surface of the cellulose fibers is rendered hydrophobic. For example, the cellulose fibers can be treated using a liquid phase silanization scheme. In this example, cellulose fibers were treated with octadecyltrichlorosilane (OTS) dissolved in one or more hexanes.

[0166]The functionalization process that results in the bonding of the OTS molecule to the cellulose surface can involve two reactions: 1) the hydrolysis of OTS with adventitious dissolved water to produce the reactive intermediate (a trisolanol) and 2) the condensation of the trisilanol with surface hydroxyl groups to form a grafted OTS moiety. The batch process begins with the preparation and conditioning of 2 liters of an OTS-hexane solution. This solution is allowed to condition by uptake of ambient humidity for approximately 10 minutes to cause the hydrolysis step of the ...

example 3

Freeness Measurements of Functionalized Cellulose Fiber Compositions

[0169]Freeness is an industry-standard measure of how quickly water is able to drain from a fiber furnish sample. In many cases, there is a direct correlation between freeness value and either 1) a target level of refining of pulp, or 2) the ease of drainage of white water from the wet web, especially in the early sections of a Fourdrinier former. Freeness of pulp (Canadian standard method) was measured according to T227 OM-09 (Tappi Stadards).

[0170]In this example, Canadian Standard Freeness (CSF) values were obtained for bleached hardwood and softwood pulp mixtures containing various percentage of functionalized fibers. FIG. 2 shows CSF values observed for bleached hardwood pulp mixtures. FIG. 3 shows CSF values observed for bleached softwood pulp mixtures.

[0171]As demonstrated in FIGS. 2 and 3, the addition of functionalized fibers into the furnish mixture where no pre-treatment was applied to the fibers had a li...

example 4

Water Retention Value (WRV) Measurements of Functionalized Cellulose Fiber Compositions

[0175]Water Retention Value (WRV) is a useful tool in evaluating the performance of pulps relative to dewatering behavior on the paper machine. The WRV method was established to provide standard values of centrifugal force, time of centrifuging, and sample preparation so that results can be compared between investigators at standard values. The WRV test can be used to estimate the maximum amount of water that can be removed from a certain furnish before the wet web leaves the press section of a paper machine.

[0176]The basic WRV measurement procedure was the following: the wet specimen weight (W5) is obtained by subtracting the weight of the filtering crucible or specimen holder alone (W1) from the weight of the specimen and holder after centrifuging (W2). The dry specimen weight (W3) is measured by subtracting the weight of the filtering crucible or specimen holder alone (W1) from the weight of th...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
volumesaaaaaaaaaa
volumesaaaaaaaaaa
specific surface areaaaaaaaaaaa
Login to View More

Abstract

The present disclosure provides methods of improving dewatering in the papermaking process by incorporation of functionalized cellulose fibers in the paper furnish. Additionally, the disclosure provides the means to eliminate process problems mainly plugging problems in a nano / micro-fibrillated cellulose production process by incorporation of functionalized cellulose fibers in a cellulose fiber composition and methods of functionalizing cellulose fibers in a paper making process. The methods according to the present disclosure provide several advantages, such as improving the freeness and dewatering of the paper making process during the paper making process, leading to an increased production rate and reduced energy consumption.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims the benefit under 35 USC §119(e) of U.S. Provisional Application Ser. No. 61 / 783,669, filed on Mar. 14, 2013, the entire disclosure of which is incorporated herein by reference.TECHNICAL FIELD[0002]The invention relates to the functionalization of cellulose fibers by a process to render all or part of their surface to be hydrophobic. The invention includes methods for improving the dewatering and drainage practices involved in a paper making process, improving flow properties in papermaking nano / micro-fibrillated cellulose production processes resulting in improvements in energy expenditures associated with the current process and significantly reduced plugging problems during nano / micro-fibrillated cellulose production.BACKGROUND AND SUMMARY OF THE INVENTION[0003]The process of making paper requires a large amount of energy, and nearly 80% of the required energy is consumed by paper drying. In particular, the size...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(United States)
IPC IPC(8): D21H11/20D21H17/13
CPCD21H11/20D21H17/13D21H21/10D21H17/25D21H21/16C07F7/1804
Inventor HAKOVIRTA, MARKOASHURST, WILLIAM R.AKSOY, BURAK
Owner AUBURN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products