Functionalized cellulose fibers for dewatering and energy efficiency improvements
a technology of cellulose fibers and functional fibers, applied in the field of functionalization of cellulose fibers, can solve the problems of large proportion of energy required for paper drying, large amount of energy consumed in papermaking process, so as to improve the rate at which fibers slide past each other, influence the dewatering properties of papermaking furnishing and positively, the effect of reducing the friction between the fibers
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example 2
Functionalization of Cellulose Fibers
[0165]Air dried fiber mats comprising cellulose fibers can be subjected to a process in which all or part of the surface of the cellulose fibers is rendered hydrophobic. For example, the cellulose fibers can be treated using a liquid phase silanization scheme. In this example, cellulose fibers were treated with octadecyltrichlorosilane (OTS) dissolved in one or more hexanes.
[0166]The functionalization process that results in the bonding of the OTS molecule to the cellulose surface can involve two reactions: 1) the hydrolysis of OTS with adventitious dissolved water to produce the reactive intermediate (a trisolanol) and 2) the condensation of the trisilanol with surface hydroxyl groups to form a grafted OTS moiety. The batch process begins with the preparation and conditioning of 2 liters of an OTS-hexane solution. This solution is allowed to condition by uptake of ambient humidity for approximately 10 minutes to cause the hydrolysis step of the ...
example 3
Freeness Measurements of Functionalized Cellulose Fiber Compositions
[0169]Freeness is an industry-standard measure of how quickly water is able to drain from a fiber furnish sample. In many cases, there is a direct correlation between freeness value and either 1) a target level of refining of pulp, or 2) the ease of drainage of white water from the wet web, especially in the early sections of a Fourdrinier former. Freeness of pulp (Canadian standard method) was measured according to T227 OM-09 (Tappi Stadards).
[0170]In this example, Canadian Standard Freeness (CSF) values were obtained for bleached hardwood and softwood pulp mixtures containing various percentage of functionalized fibers. FIG. 2 shows CSF values observed for bleached hardwood pulp mixtures. FIG. 3 shows CSF values observed for bleached softwood pulp mixtures.
[0171]As demonstrated in FIGS. 2 and 3, the addition of functionalized fibers into the furnish mixture where no pre-treatment was applied to the fibers had a li...
example 4
Water Retention Value (WRV) Measurements of Functionalized Cellulose Fiber Compositions
[0175]Water Retention Value (WRV) is a useful tool in evaluating the performance of pulps relative to dewatering behavior on the paper machine. The WRV method was established to provide standard values of centrifugal force, time of centrifuging, and sample preparation so that results can be compared between investigators at standard values. The WRV test can be used to estimate the maximum amount of water that can be removed from a certain furnish before the wet web leaves the press section of a paper machine.
[0176]The basic WRV measurement procedure was the following: the wet specimen weight (W5) is obtained by subtracting the weight of the filtering crucible or specimen holder alone (W1) from the weight of the specimen and holder after centrifuging (W2). The dry specimen weight (W3) is measured by subtracting the weight of the filtering crucible or specimen holder alone (W1) from the weight of th...
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