Method of manufacturing a 2-layered flexible substrate
a flexible substrate and manufacturing method technology, applied in the direction of cable/conductor manufacturing, metallic pattern materials, foundry moulds, etc., can solve the problems of increased film defects, high labor and time, poor operation efficiency, etc., and achieve excellent adhesion
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example 1
A polyimide film of 50 .mu.m thickness (manufactured by Toray .multidot. Dupon Co.; product name .left brkt-top.Kapton 200 V.right brkt-bot.) was cut into 12 cm.times.12 cm size, a nickel deposition layer was formed to a thickness of 100 .ANG. by vacuum deposition on one surface as a first layer of an underlying metal layer, and a copper deposition layer was formed further thereon as a second layer to a thickness of 1,000 .ANG. by vacuum deposition.
Then, the film was immersed in a weekly alkaline degreasing agent for 1 min, and successively cleaned for 2 min to apply a surface cleaning treatment. Then, a primary electric copper plated deposition layer of 1 .mu.m thickness was formed by using an electric copper plating solution of a composition shown in Table 1. The plating was applied under the conditions of a plating temperature at room temperature, with air stirring and at a current density of 0.5 A / dm.sup.2.
After forming the primary electric copper plated deposition layer, it was...
example 2
When a 2-layered flexible substrate was manufactured in the same procedures as those in Example 1 except for forming the primary electric copper plated deposition layer to a thickness of 0.5 .mu.m and a 2-layered flexible wiring board was manufactured by using the substrate in the same procedures as in Example 1, a 2-layered flexible wiring board free from pinhole-induced defects in the wiring portion was obtained. Further, when the wiring portion of the obtained 2-layered flexible wiring was peeled off vertically and the adhesion strength of the wiring portion was measured, it was found that the strength was not less than 1 kgf / cm and it had an adhesion strength enough to be served for practical use.
example 3
When a 2-layered flexible substrate was manufactured in the same procedures as those in Example 1 except for using potassium hydroxide at a concentration of 3.0 mol / liter for the hydrophilic treatment of the exposed portion of the polyimide film and a 2-layered flexible wiring board was manufactured by using the substrate in the same procedures as those in Example 1, a 2-layered flexible wiring board free from pinhole-induced defects in the wiring portion was obtained. Further, when the wiring portion of the obtained 2-layered flexible wiring was peeled off vertically and the adhesion strength of the wiring portion was measured, it was found that the strength was not less than 1 kgf / cm and it had an adhesion strength enough to be served for practical use.
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