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Method of manufacturing a 2-layered flexible substrate

a flexible substrate and manufacturing method technology, applied in the direction of cable/conductor manufacturing, metallic pattern materials, foundry moulds, etc., can solve the problems of increased film defects, high labor and time, poor operation efficiency, etc., and achieve excellent adhesion

Inactive Publication Date: 2000-04-04
SUMITOMO METAL MINING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

An object o f the present invention is to overcome the foregoing problems in the manufacture of a flexible wiring board by using a dry plating method, an electroless plating method and an electric plating method and provide a method of manufacturing a flexible wiring bo

Problems solved by technology

However, since the copper foil of such a reduced thickness has less rigidity and poor handlability, it has been adopted a method of once appending a reinforcing material such as an aluminum carrier to the copper foil to increase the rigidity, then appending the copper foil and the insulation film and then removing the aluminum carrier.
However, this method involves a problem of taking much labor and time and is poor in the operation efficiency.
Further, such a thin copper foil also involves a problem in view of manufacturing techniques that defects of film are increased due to scattering of the film thickness, pin holes or occurrence of crackings.
Further, as the thickness of the copper foil is decreased, manufacturing thereof becomes more difficult, which increases the manufacturing cost to lose the economical merit of the 3-layered flexible wiring boards because of increase in the manufacturing cost.
Particularly, since it has been an increasing demand recently for a wiring board having a wiring portions with such a narrow width and a narrow pitch that can not be manufactured unless a copper foil having a thickness of less than ten and several micrometers, for example, about of several micrometers, the wiring board using the 3-layered flexible substrate involves problems in view of the manufacturing cost as well as the technical problems described above.
However, although the exposed portion of the insulation film induced by the pinholes can be eliminated to some extent by this method, a plating solution used for the electroless copper plating or a pretreatment solution theref or penetrates through already formed pinholes of various sizes to a position between the insulation film and the underlying metal film, which brings about hindrance for the adhesion of the underlying metal layer and, thus, the adhesion of the conductor layer by electric plating to be formed subsequently, and this method cannot provide a satisfactory countermeasure.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

A polyimide film of 50 .mu.m thickness (manufactured by Toray .multidot. Dupon Co.; product name .left brkt-top.Kapton 200 V.right brkt-bot.) was cut into 12 cm.times.12 cm size, a nickel deposition layer was formed to a thickness of 100 .ANG. by vacuum deposition on one surface as a first layer of an underlying metal layer, and a copper deposition layer was formed further thereon as a second layer to a thickness of 1,000 .ANG. by vacuum deposition.

Then, the film was immersed in a weekly alkaline degreasing agent for 1 min, and successively cleaned for 2 min to apply a surface cleaning treatment. Then, a primary electric copper plated deposition layer of 1 .mu.m thickness was formed by using an electric copper plating solution of a composition shown in Table 1. The plating was applied under the conditions of a plating temperature at room temperature, with air stirring and at a current density of 0.5 A / dm.sup.2.

After forming the primary electric copper plated deposition layer, it was...

example 2

When a 2-layered flexible substrate was manufactured in the same procedures as those in Example 1 except for forming the primary electric copper plated deposition layer to a thickness of 0.5 .mu.m and a 2-layered flexible wiring board was manufactured by using the substrate in the same procedures as in Example 1, a 2-layered flexible wiring board free from pinhole-induced defects in the wiring portion was obtained. Further, when the wiring portion of the obtained 2-layered flexible wiring was peeled off vertically and the adhesion strength of the wiring portion was measured, it was found that the strength was not less than 1 kgf / cm and it had an adhesion strength enough to be served for practical use.

example 3

When a 2-layered flexible substrate was manufactured in the same procedures as those in Example 1 except for using potassium hydroxide at a concentration of 3.0 mol / liter for the hydrophilic treatment of the exposed portion of the polyimide film and a 2-layered flexible wiring board was manufactured by using the substrate in the same procedures as those in Example 1, a 2-layered flexible wiring board free from pinhole-induced defects in the wiring portion was obtained. Further, when the wiring portion of the obtained 2-layered flexible wiring was peeled off vertically and the adhesion strength of the wiring portion was measured, it was found that the strength was not less than 1 kgf / cm and it had an adhesion strength enough to be served for practical use.

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Abstract

A method of manufacturing a 2-layered flexible substrate includes forming an underlying metal layer on an insulation film with a deposition layer formed by a dry plating method using at least one of nickel, copper-nickel alloy, chromium and chromium oxide and a copper deposition layer formed by a dry plating method on the noted deposition layer, then forming a primary electric copper plated deposition layer on the underlying metal layer, then applying a treatment using at least one alkaline solution selected from inorganic alkaline solutions and organic alkaline solutions, then forming an electroless copper plated deposition layer as an intermediate metal layer on the primary electric copper plated deposition layer and, finally, forming a secondary electric copper plated deposition layer on the intermediate metal layer, thereby finally forming a copper conductor layer of 1 to 35 mu m thickness on the insulation film.

Description

1. Field of the InventionThe present invention concerns a method of manufacturing a 2-layered flexible substrate and, more specifically, it relates to a method of manufacturing a 2-layered flexible substrate capable of easily forming a copper conductor layer of more intact and adhesive property upon forming a copper conductor layer on an insulation film by adopting a dry plating method, an electroless plating method and an electric copper plating method.2. Statement of the Prior ArtSubstrates used for manufacturing flexible wiring boards are generally classified into a 3-layered flexible substrate in which a copper foil as a conductor layer is appended on an insulation film by using an adhesive and a 2-layered flexible substrate in which a copper conductor layer is formed directly on an insulation film without using an adhesive by a dry plating method or a wet plating method.In a case of using the 3-layered flexible substrate, a 3-layered flexible wiring board can be manufactured by...

Claims

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Application Information

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IPC IPC(8): C23C28/02H05K3/10H05K3/38H05K1/09B32B15/08B32B15/20C23C14/20H05K1/00H05K3/00H05K3/24
CPCC23C28/02C23C28/023H05K3/24H05K1/0393H05K2203/1476H05K3/388H05K2203/0793
Inventor TAMIYA, YUKIHIROSAKURADA, TAKEHIKOTAKABATAKE, TOSHINOBUSUGIURA, TAKASHI
Owner SUMITOMO METAL MINING CO LTD
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