The application discloses a preparation method of
germanium diselenide and belongs to the technical field of compound preparation. The preparation method of
germanium diselenide provided by the application comprises the following steps: mixing
germanium powder screened and
selenium powder screened and ball milling, then heating and reacting in an
inert gas environment, crushing after removing the surface attachments of the heating and
reaction product, and heat-insulating and reacting in the
inert gas environment, so that golden yellow crystalline germanium
diselenide can be obtained. The obtained germanium diselenide is high in purity, free of segregation, and low in loss, namely, high in yield. Moreover, the preparation method provided by the application is simple in operation, does not need special equipment, and is beneficial to practical production and application.