Preparing dye sensitized nanocrystalline semiconductor solar cell optical anode using electrical spinning method

A technology of solar cells and semiconductors, applied in semiconductor devices, circuits, photovoltaic power generation, etc., can solve the problems of dye-sensitized porous nanocrystalline semiconductor solar cell photoanodes that have not been reported, and achieve easy operation and control, large specific surface area, and broad space. The effect of applying the foreground

Inactive Publication Date: 2007-12-26
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The U.S. Patent No. 6743273 discloses the preparation of polymer fibers by electrospinning, but the preparation of dye-sensitized porous nanocrystalline semiconductor solar cell photoanodes by electrospinning has not been reported so far.

Method used

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  • Preparing dye sensitized nanocrystalline semiconductor solar cell optical anode using electrical spinning method
  • Preparing dye sensitized nanocrystalline semiconductor solar cell optical anode using electrical spinning method
  • Preparing dye sensitized nanocrystalline semiconductor solar cell optical anode using electrical spinning method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] (1) 10 milliliters of the precursor isopropyl titanate of titanium dioxide are dropped into 60 milliliters of water, obtain titanium dioxide sol, then add PVA 0.1 gram and sodium dodecylbenzene sulfonate 0.1 milliliter in 10 grams of titanium dioxide sols, simultaneously Add 0.2 g of acetylacetone and stir for 2 hours to form a uniformly dispersed and stable titanium dioxide sol.

[0035] (2) The conductive glass is cleaned with tap water, secondary deionized water, acetone and ethanol successively, and dried;

[0036] (3) Install the device for electrospinning, install the batching port on the liquid container, put the nanocrystalline semiconductor sol described in step (1) into the liquid container, then connect the high voltage generator to the material spray port, and connect the conductive The glass (i.e. receiver) is placed under the nozzle and grounded.

[0037] (4) Turn on the high-voltage generator described in step (3), under the action of electric field forc...

Embodiment 2

[0040](1) Drop 10 milliliters of isopropyl titanate, a precursor of titanium dioxide, into 100 milliliters of water to form a titanium dioxide sol, then add 0.2 grams of PVA and 0.1 milliliters of dodecylbenzenesulfonic acid to 10 grams of titanium dioxide sol, and simultaneously add acetyl 0.1 g of acetone was stirred for 2 hours to form a uniformly dispersed and stable titanium dioxide sol.

[0041] (2) The conductive glass is cleaned with tap water, secondary deionized water, acetone and ethanol successively, and dried;

[0042] (3) Install the device for electrospinning, install the batching port on the liquid container, put the nanocrystalline semiconductor sol described in step (1) into the liquid container, then connect the high voltage generator to the material spray port, and connect the conductive The glass (i.e. receiver) is placed under the nozzle and grounded.

[0043] (4) Turn on the high-voltage generator described in step (3), under the action of electric fiel...

Embodiment 3

[0046] (1) Drop 10 milliliters of isopropyl titanate, a precursor of titanium dioxide, into 30 milliliters of water to form a titanium dioxide sol, then add 0.3 grams of PVA and 0.05 milliliters of dodecylbenzenecyclonic acid to 10 grams of titanium dioxide sol, and stir for 2 hours A uniformly dispersed and stable titanium dioxide sol is formed.

[0047] (2) The conductive glass is cleaned with tap water, secondary deionized water, acetone and ethanol successively, and dried;

[0048] (3) Install the device for electrospinning, install the batching port on the liquid container, put the nanocrystalline semiconductor sol described in step (1) into the liquid container, then connect the high voltage generator to the material spray port, and connect the conductive The glass (i.e. receiver) is placed under the nozzle and grounded.

[0049] (4) Turn on the high-voltage generator described in step (3), under the action of electric field force, the nanocrystalline semiconductor sol ...

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Abstract

The invention relates to prepare dye sensitization nano-crystal semiconductor solar cell light anode with electric spinning, which comprises: spraying the solution contained nano-crystal semiconductor conductive substrate by electric field force to form film with porous nano structure to generate current and photo voltage. This invention needs simple devices with low cost and easy control. The product has high specific surface area and porosity. The prepared objective cell has same efficiency as cell by traditional method.

Description

technical field [0001] The invention belongs to the field of preparation of dye-sensitized solar cell materials, in particular to a method for preparing dye-sensitized nanocrystalline semiconductor solar cell photoanode by electrospinning. Background technique [0002] Since Swiss scientist Grtzel reported the research work of dye-sensitized nanocrystalline semiconductor solar cells in 1991, it has become the most promising new type of solar cells due to its high efficiency and low cost. Its highest efficiency can reach more than 10%. Such a high efficiency is attributed to the dye sensitization effect on the one hand, and the application of the porous nanocrystalline semiconductor film as a photoanode in the battery on the other hand. This photoanode is one of the main components of dye-sensitized nanocrystalline semiconductor solar cells, and its nanocrystalline porous structure has a large specific surface area (about 100m 2 / g), the porosity is high, which greatly impr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/0224H01L31/18H01L31/04H01G9/20H01M14/00
CPCY02E10/542Y02P70/50
Inventor 谭庶欣赵勇王立芳翟锦江雷
Owner INST OF CHEM CHINESE ACAD OF SCI
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