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High intensity, corrosion resistant and high ductility steel for mooring chain and production process thereof

A production process and corrosion-resistant technology, which is applied in the field of alloy steel, can solve problems such as high content of Ni in the composition, internal cracks in the material, and increased costs, and achieve the effects of good welding performance, high and low temperature toughness, and energy saving

Inactive Publication Date: 2009-07-22
JIANGSU SHAGANG GROUP HUAIGANG SPECIAL STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the overall high setting of the alloy composition, the structure of the material is semi-martensitic, and the material must be annealed before delivery, otherwise the material will undergo martensitic transformation during placement, resulting in structural stress, resulting in material Internal cracks appear, once internal cracks occur, the material will be scrapped as a whole, and the Ni content in the composition is high, which not only increases the cost, but also causes a waste of resources

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Embodiment 1: adopt following production technology to prepare:

[0037] (1) Smelting: Add molten iron and steel scrap to a top-bottom double-blowing converter of more than 60 tons to realize pre-removal of P and initial adjustment of components;

[0038] (2) LF refining: Desulphurization, deoxygenation and composition fine-tuning in LF furnaces of more than 60 tons;

[0039] (3) RH / VD refining: use more than 60 tons of RH / VD refining to realize vacuum degassing, ensure [H]≤0.00015% and remove inclusions;

[0040] (4) Continuous casting: the R14m 6-machine 6-strand continuous casting machine produced by Italian Danieli Company is used to cast a round billet of φ380mm-500mm;

[0041] (5) Continuous rolling: use one billet stand and 6 continuous rolling units to roll into steel bars for mooring chains;

[0042] (6) Non-destructive flaw detection, using ultrasonic and eddy current flaw detection units to inspect the surface and internal quality of the bar.

[0043] The ...

Embodiment 2

[0048] C 0.24%, Si 0.20%, Mn 1.52%, Cr 1.10%, Ni 1.00%, Mo 0.58%, Nb 0.040%, Al 0.022%, S 0.0030%, P 0.010%, B 0.0003%, Cu 0.01%, Sb 0.002%, Sn 0.0015%, As 0.006%, [O] 0.0010%, [N] 0.0048%, the rest is Fe.

[0049] The φ150mm bar is sampled after overall quenching and tempering (900°C water quenching, 620°C water tempering), and the obtained mechanical properties are as follows:

[0050] Tensile strength R m =930MPa, yield strength R el =840MPa, Elongation A 5 =19%, reduction of area Z=66%, -20°C, V-notch impact energy AKv=145J.

[0051] All the other implementations are as in Example 1.

Embodiment 3

[0053] C 0.22%, Si 0.23%, Mn 1.50%, Cr 1.28%, Ni 0.80%, Mo 0.50%, Nb 0.030%, Al 0.026%, S 0.0040%, P 0.012%, B 0.0005%, Cu 0.01%, Sb 0.006%, Sn≤0.02%, As 0.005%, [O]≤0.0014%, [N]≤0.0046%, the rest is Fe.

[0054] The φ95mm bar is sampled after overall quenching and tempering (900°C water quenching, 620°C water tempering), and the obtained mechanical properties are as follows:

[0055] Tensile strength R m =910MPa, yield strength R el =745MPa, Elongation A 5 =25%, reduction of area Z=71%, -20°C, V-notch impact energy AKv=148J.

[0056] All the other implementations are as in Example 1.

[0057] After the mooring chain steel of the present invention is used by Zhengmao Group, the properties of the mooring chain products are as follows:

[0058] The chain-making process of the mooring chain is: use the flash preheating butt-welding special unit to weave and butt-weld the bar. After the chain is made, it needs to be tempered in a vertical continuous tempering furnace: quenchi...

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Abstract

The invention discloses a high-strength corrosion resistant high-tenacity steel which is used for mooring chain and a production process hereof; the chemical components (wt percent) are: 0.18 percent to 0.25 percent of C, 0.10 percent to 0.35 percent of Si, 1.40 percent to 1.80 percent of Mn, 0.80 percent to 1.40 percent of Cr, 0.60 percent to 1.20 percent of Ni, 0.40 percent to 0.70 percent of Mo, 0.02 percent to 0.06 percent of Nb, 0.02 percent to 0.06 percent of Al, S which is less than or equal to 0.010 percent, P which is less than or equal to 0.020 percent, B which is less than or equal to 0.005 percent, Cu which is less than or equal to 0.20 percent, Sb which is less than or equal to 0.010 percent, Sn which is less than or equal to 0.03 percent, As is less than or equal to 0.04 percent, [O] which is less than or equal to 0.0018 percent, [N] which is less than or equal to 0.0060 percent and the rest is Fe. The invention avoid producing martensite tissue with optimized design of components and in this way the material tissue can not be converted to produce central crack in a long-term placement under the situation that the parent metal does not adopt annealing process; at the same time the precious metal Ni is saved. The invention adopts RH / VD for desaeration and removing impurities and in this way, the purity of the steel can be obviously increased; the invention adopts converter for melting which reduces the energy consumption and saves cost.

Description

Technical field: [0001] The invention relates to alloy steel in the iron and steel industry, in particular to the design and production process of high-strength, corrosion-resistant and high-toughness steel for mooring chains. Background technique: [0002] With the development of modern industry, the development of marine resources is getting deeper and deeper. In particular, marine facilities such as deep-sea oil production, marine exploration, and national defense construction require the use of a large number of mooring chains. load, all put forward strict requirements on the overall performance of the mooring chain, not only require high strength and good toughness of the material, but also require the material to have good seawater corrosion resistance, fatigue resistance, wear resistance, good welding performance and low temperature of the weld joint Impact toughness. The diameter of the bars used to manufacture mooring chains is generally φ70mm-φ160mm, of which mor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C38/48C22C38/58C22C33/04C21C7/00B22D11/16B21B37/16B21B1/46C21D8/06
Inventor 何达平王忠英尹修刚张小华王刚
Owner JIANGSU SHAGANG GROUP HUAIGANG SPECIAL STEEL CO LTD
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