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Liquid crystal orientating agent and liquid crystal display element

A technology of liquid crystal orientation and vertical orientation, which is applied in the direction of liquid crystal materials, chemical instruments and methods, instruments, etc., can solve the problems of uneven orientation and moisture absorption, and achieve the effect of excellent voltage retention rate

Active Publication Date: 2009-12-16
JSR CORPORATIOON
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Especially for low-voltage drive type liquid crystal display elements for the purpose of low power consumption, the requirements for voltage retention and reliability tests for long-term voltage at high temperatures are becoming more and more stringent. In addition, there are still manufacturing processes The problem of uneven orientation due to the absorption of moisture in the air by the oriented film, this problem needs to be solved urgently
However, as a liquid crystal alignment film suitable for the MVA method and the PVA method so far, for example, in Patent Document 1 and Patent Document 2, there are epoxy groups in the alignment agent structure, which can show excellent vertical alignment and electrical properties, but there is no solution. moisture problem

Method used

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  • Liquid crystal orientating agent and liquid crystal display element
  • Liquid crystal orientating agent and liquid crystal display element
  • Liquid crystal orientating agent and liquid crystal display element

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0078] Hereinafter, the present invention will be explained more specifically through examples, but the present invention is not limited by these examples. The evaluation items and evaluation methods of the liquid crystal aligning agents prepared in the following examples and comparative examples are as follows.

[0079] (Vertical orientation of liquid crystal molecules)

[0080] Regarding the vertical orientation of the vertical orientation type liquid crystal display element, when the voltage is OFF and the liquid crystal display element under AC 12V (peak-to-peak) is observed, it is judged as "good" without abnormal magnetic regions.

[0081] (Moisture resistance test of liquid crystal display element)

[0082] Regarding the humidity resistance of the vertical alignment type liquid crystal display element, it was placed in a room temperature and high humidity environment (90% RH), and when the voltage was turned on and off, no abnormal magnetic area occurred in the liquid cryst...

Synthetic example 1

[0088]2.3g of 2,3,5-tricarboxycyclopentaacetic acid dianhydride, 0.88g of p-phenylenediamine and 1.1g of the diamine compound represented by the above formula (9) were dissolved in 16.8g of N-methyl-2 -In pyrrolidone, react at 60°C for 5 hours. Then, the reaction mixture was poured into a large excess of methanol, and the reaction product was precipitated. Then it was washed with methanol and dried at 40°C under reduced pressure for 15 hours to obtain 55.6 g of specific polymer Ia.

[0089] The specific polymer Ia obtained in Synthesis Example 1 was dissolved in 39.0 g of N-methyl-2-pyrrolidone, 0.88 g of pyridine and 1.13 g of acetic anhydride were added, and imidization was performed at 110°C for 4 hours. Then, the reaction product liquid was precipitated in the same manner as in Synthesis Example 1, and 53.0 g of a specific polymer IIa having an intrinsic viscosity of 0.63 dL / g was obtained. The imidization rate of the obtained specific polymer IIa is shown in Table 1.

Synthetic example 2

[0091] Except that 1.89g of 2,3,5-tricarboxycyclopentaacetic acid dianhydride, 0.55g of p-phenylenediamine and 1.76g of the diamine compound represented by the above formula (9) are dissolved in 16.8g of N-methyl Except for the -2-pyrrolidone, 55.7 g of the specific polymer Ib was obtained in the same manner as in Synthesis Example 1.

[0092] The specific polymer Ib obtained in Synthesis Example 2 was dissolved in 39.0 g of N-methyl-2-pyrrolidone, 0.73 g of pyridine and 0.95 g of acetic anhydride were added, and imidization was performed at 110°C for 4 hours. Then, the reaction product liquid was precipitated in the same manner as in Synthesis Example 1, and 52.1 g of a specific polymer IIb having an intrinsic viscosity of 0.5 dL / g was obtained.

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Abstract

The present invention provides a vertical alignment type liquid crystal display element capable of achieving vertical alignment, excellent in voltage retention, and free of contrast unevenness and display defects even when placed in a high-humidity environment, and having high reliability, and a liquid crystal used therein Orienting agent. The vertical alignment type liquid crystal aligning agent contains 100 parts by weight of polyamic acid obtained by reacting tetracarboxylic dianhydride and diamine compound and / or its imidized polymer and 0.01 to 100 parts by weight of 2 Or a compound with two or more epoxy groups.

Description

Technical field [0001] The present invention relates to a liquid crystal aligning agent and a liquid crystal display element. In more detail, it relates to a liquid crystal aligning agent capable of realizing a liquid crystal alignment film excellent in vertical alignment, voltage retention, and moisture resistance, and a liquid crystal display element having the liquid crystal alignment film and high reliability. Background technique [0002] At present, as a liquid crystal display element, it is known that a liquid crystal alignment film composed of polyamic acid, polyimide, etc., is formed on the surface of a substrate provided with a transparent conductive film, and used as a substrate for liquid crystal display elements. The sheets are arranged in opposite directions, and a layer of nematic liquid crystal with positive dielectric anisotropy is formed in the gap to form a liquid crystal cell with a sandwich structure. The long axis of the liquid crystal molecule is continuous...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K19/38G02F1/1337
CPCC08G73/10C08L79/08C09K19/38C09K19/56G02F1/133723
Inventor 木村礼子六鹿泰显
Owner JSR CORPORATIOON
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