Silvering graphite and preparation method thereof

A technology of graphite and nano-graphite microchips, applied in chemical instruments and methods, liquid chemical plating, fibrous fillers, etc., can solve the problems of low contact resistivity and limit the improvement of the conductivity of composite conductive polymers, and achieve Effects of low resistivity, low density, and high utilization

Active Publication Date: 2007-10-17
HUAQIAO UNIVERSITY +1
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AI Technical Summary

Problems solved by technology

[0004] However, the limited conductivity of graphite limits the improvement of the conductivity of composite conductive polymers. In order to further improve the conductivity of composite materials, silver has the best electrical and thermal conductivity an...

Method used

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Embodiment Construction

[0026] The invention discloses a silver-plated graphite, the surface of which is covered by silver, and the graphite is a nano-graphite with a thickness of 20-80 nm and a diameter of 5-30 μm.

[0027] A kind of preparation method of silver-plated graphite of the present invention, embodiment 1 realizes by following steps:

[0028] Put 0.1g of nanographite microflakes with a thickness of 20-80nm and a diameter of 5-30μm in 5mL of ethanol for ultrasonic dispersion, then put them into 50mL of 20g / L stannous chloride and 10mL / L hydrochloric acid solution, heat and boil for 5min, then pump After filtering and washing, redisperse the nano-graphite flakes in 10mL ethanol aqueous solution (the volume ratio of ethanol and water is 1:1) and put them into 50mL of 1% AgNO3 solution and stir continuously for 5min, then redisperse them in 10mL ethanol after washing with suction Aqueous solution (the volume ratio of ethanol and water is 1:1) and put into 50mL of 40g / L sodium hypophosphite so...

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Abstract

The invention discloses a silvered graphite and its producing method which is coated by outside plated nano graphite microchip. The method includes: making the nano graphite microchip orderly sensitize, activate, degelation pretreat, and re-disperse in the ethanol water solution, adding a certain amount of aminosilane as mother liquid; adding the silver nitrate into deionized water for dissolving, adding ammonia and/or sodium hydroxide to get [Ag(NH3)2]OH] solution, then feeding the reducing agent and [Ag(NH3)2]OH] solution into the mother liquid that finishing the nano graphite microchip silvering, filtering and washing, drying in vacuum to obtain silvered nano graphite microchip. The inventive silvered graphite has a high conductivity, a low density, a low cost, a low resistivity in which the pulverous volume resistivity is 8*10-5omegacm. The method has a simple craft, a low demanded device. The produced nano graphite microchip is silvered an even and continuous silver layer on surface with a high availability of silver nitrate.

Description

technical field [0001] The invention relates to a silver-plated graphite and a preparation method thereof, belonging to the technical field of chemical silver plating. The prepared silver-plated nano-graphite microchips can be used as conductive fillers in composite conductive polymers, electromagnetic shielding materials, and the like. Background technique [0002] With the development of modern science and technology, especially the rapid development of electronic industry and information technology, the demand for polymer materials with conductive properties is increasing day by day, and composite conductive polymers refer to high molecular polymers as the matrix, adding a considerable amount of Conductive material (such as carbon black, graphite, carbon fiber, metal powder, metal fiber, metal oxide, etc.) electrical and mechanical properties. [0003] Graphite / metal composite materials not only have the anisotropy of graphite, good lubricity and wear resistance, but als...

Claims

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Application Information

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IPC IPC(8): C09C3/06C09C1/46C23C18/44C23C18/28C08L101/12
Inventor 陈国华赵立平孙伟福郑丽龙
Owner HUAQIAO UNIVERSITY
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